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Polymer Bulletin
Published in: Polymer Bulletin 7/2021

02-07-2020 | Original Paper

Design of pH sensitive low-cost adsorbent from the exudate of Lannea coromandelica (Houtt) for remediation of Malachite Green dye from aqueous solution

Authors: Ch. Jamkhokai Mate, Sumit Mishra, P. K. Srivastava

Published in: Polymer Bulletin | Issue 7/2021

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Abstract

In this paper, pH sensitive superabsorbent hydrogel (Jh-g-AM-cl-NN′MBA) was designed from unexplored natural exudate of Lannea coromandelica (Houtt.) known as Jhingan gum or Odina gum or Jeol gum. The synthesized adsorbent was characterized by analytical techniques. Swelling studies carried out at different pH and temperature indicted that the hydrogel swelled maximum in alkaline and at high temperature. Batch adsorption was carried out to investigate the effect of initial dye concentration, adsorbent dosage, pH, agitation time and temperature. Adsorption data were fitted to various adsorption isotherms which were best explained by Langmuir isotherm (R2 = 0.997–0.999) with maximum adsorption capacity of 83 mg/g. The kinetic studies suggested that pseudo-second order (R2 = 0.996) well fitted the results. The feasibility of adsorption process determined thermodynamically suggested that adsorption process was endothermic and spontaneous. Moreover, the adsorbent displayed excellent regeneration capability and could be employed for dye removal upto five cycles of desorption–adsorption. The biodegradability of the adsorbent studied by soil burial method indicated that the material degraded completely in 180 days with a calculated half-life of 56 days. In sum, the synthesized adsorbent met all the desirable characters to be an excellent adsorbent.

Graphic abstract

previous article Synthesis of montmorillonite/modified graphene oxide filler and its effect on the properties of PP composites
next article The effect of acid aging on the mechanical and tribological properties of coir–coconut husk-reinforced low-density polyethylene composites

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Appendix
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Metadata
Title
Design of pH sensitive low-cost adsorbent from the exudate of Lannea coromandelica (Houtt) for remediation of Malachite Green dye from aqueous solution
Authors
Ch. Jamkhokai Mate
Sumit Mishra
P. K. Srivastava
Publication date
02-07-2020
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 7/2021
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-020-03263-8

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