Skip to main content
Top
Published in: Journal of Materials Engineering and Performance 8/2015

01-08-2015

Effect of Annealing Temperature on the Corrosion Resistance of Electroless Ni-B-Mo Coatings

Authors: Ihsan Gökhan Serin, Ali Göksenli, Behiye Yüksel, Rasid Ahmed Yildiz

Published in: Journal of Materials Engineering and Performance | Issue 8/2015

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The Ni-B-Mo coating on steel by electroless plating and the evaluation of the morphology and corrosion performance after applying heat treatments at different temperatures for 1 h were investigated in this study. The 25-μm-thick coating was uniform and adhesion between the substrate and the coating was good. The coating consisted of an amorphous-like structure in their as-plated condition, and after annealing at 400 °C for 1 h, crystallized nickel, nickel borides, and molybdenum carbide were formed. Immersion tests in 10% HCl solution and potentiodynamic polarization measurements in 3.5% NaCl aqueous solution were applied to investigate corrosion resistance. The corrosion performance of heat-treated coatings was compared with steel and the as-plated coating. By increasing the annealing temperature, corrosion potential shifted toward a noble direction, corrosion current density decreased and the weight loss of specimens decreased, demonstrating an increase in corrosion resistance. Best corrosion performance was achieved by the coating heat treated at 550 °C .

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference P. Sahoo and S.K. Das, Tribology of Electroless Nickel Coatings a Review, Mater. Des., 2011, 32, p 1760–1775CrossRef P. Sahoo and S.K. Das, Tribology of Electroless Nickel Coatings a Review, Mater. Des., 2011, 32, p 1760–1775CrossRef
2.
go back to reference C. Zhao and Y. Yao, Preparation and Mechanical Properties of Electroless Nickel-Phosphorus-Tungsten Carbide Nanocomposite Coatings, J. Mater. Eng. & Perf., 2014, 23(1), p 193–197CrossRef C. Zhao and Y. Yao, Preparation and Mechanical Properties of Electroless Nickel-Phosphorus-Tungsten Carbide Nanocomposite Coatings, J. Mater. Eng. & Perf., 2014, 23(1), p 193–197CrossRef
3.
go back to reference B. Oraon, G. Majundar, and B. Ghjosh, Improving Hardness of Electroless Ni-B Coatings Using Optimized Deposition Conditions and Annealing, Mater. Des., 2008, 29, p 1412–1418CrossRef B. Oraon, G. Majundar, and B. Ghjosh, Improving Hardness of Electroless Ni-B Coatings Using Optimized Deposition Conditions and Annealing, Mater. Des., 2008, 29, p 1412–1418CrossRef
4.
go back to reference A. Sharma and A.K. Singh, Electroless Ni-P and Ni-P-Al2O3 Nanocomposite Coatings and their Corrosion and Wear Resistance, J. Mater. Eng. Perform., 2013, 22(1), p 176–183CrossRef A. Sharma and A.K. Singh, Electroless Ni-P and Ni-P-Al2O3 Nanocomposite Coatings and their Corrosion and Wear Resistance, J. Mater. Eng. Perform., 2013, 22(1), p 176–183CrossRef
5.
go back to reference D. Nava, A.M. Hernandez, F. Manriquez, Y. Meas, R.O. Borges, J.J. Perez, and G. Trejo, Effects of Heat Treatment on the Tribological and Corrosion Properties of Electrodeposited Ni-P Alloys, Int. J. Electrochem. Sci., 2013, 8, p 2670–2681 D. Nava, A.M. Hernandez, F. Manriquez, Y. Meas, R.O. Borges, J.J. Perez, and G. Trejo, Effects of Heat Treatment on the Tribological and Corrosion Properties of Electrodeposited Ni-P Alloys, Int. J. Electrochem. Sci., 2013, 8, p 2670–2681
6.
go back to reference M. He, W. Hu, C. Zhang, J. Weng, B. Shen, and Y. Wu, Effect of Wear Conditions on Tribological Properties of Ni-P Coatings, Trans. Nonferrous Met. Soc. China, 2012, 22, p 2586–2592CrossRef M. He, W. Hu, C. Zhang, J. Weng, B. Shen, and Y. Wu, Effect of Wear Conditions on Tribological Properties of Ni-P Coatings, Trans. Nonferrous Met. Soc. China, 2012, 22, p 2586–2592CrossRef
7.
go back to reference M. Novak, D. Vojtech, P. Novak, and T. Vitu, Tribological Properties of Heat-Treated Ni-P Coatings on AZ91 Alloy, Appl. Surf. Sci., 2011, 257, p 9982–9985CrossRef M. Novak, D. Vojtech, P. Novak, and T. Vitu, Tribological Properties of Heat-Treated Ni-P Coatings on AZ91 Alloy, Appl. Surf. Sci., 2011, 257, p 9982–9985CrossRef
8.
go back to reference K. Gilley, J. Nino, Y. Riddle, D. Hahn, and S.S. Perry, Treatments Modify the Tribological Properties of Nickel Boron Coatings, Appl. Mater. Interfaces, 2012, 4, p 3069–3076CrossRef K. Gilley, J. Nino, Y. Riddle, D. Hahn, and S.S. Perry, Treatments Modify the Tribological Properties of Nickel Boron Coatings, Appl. Mater. Interfaces, 2012, 4, p 3069–3076CrossRef
9.
go back to reference Z.A. Hamid, H.B. Hassan, and A.M. Attyia, Influence of Deposition Temperature and Heat Treatment on the Performance of Electroless Ni–B Films, Surf. Coat. Technol., 2010, 205, p 2348–2354CrossRef Z.A. Hamid, H.B. Hassan, and A.M. Attyia, Influence of Deposition Temperature and Heat Treatment on the Performance of Electroless Ni–B Films, Surf. Coat. Technol., 2010, 205, p 2348–2354CrossRef
10.
go back to reference C.P. Steffani, J.W. Dini, J.R. Groza, and A. Palazoglu, Electrodeposition and Corrosion Resistance of Ni-B-W Coatings, J. Mater. Eng. Perform., 1997, 6(4), p 413–416CrossRef C.P. Steffani, J.W. Dini, J.R. Groza, and A. Palazoglu, Electrodeposition and Corrosion Resistance of Ni-B-W Coatings, J. Mater. Eng. Perform., 1997, 6(4), p 413–416CrossRef
11.
go back to reference A. Drovosekov, M. Ivanov, V. Krutskikh, E. Lubnin, and Y. Polukarov, Chemically Deposited Ni-W-B Coatings: Composition, Structure, and Properties, Prot. Metals, 2005, 41, p 55–62CrossRef A. Drovosekov, M. Ivanov, V. Krutskikh, E. Lubnin, and Y. Polukarov, Chemically Deposited Ni-W-B Coatings: Composition, Structure, and Properties, Prot. Metals, 2005, 41, p 55–62CrossRef
12.
go back to reference T. Osaka, K. Arai, N. Masubuchi, Y. Yanazaki, and T. Namikawa, Transmission Electron Microscopic Study of Electroless Nickel-Molybdenum-Boron Alloy Films, Jap. J. Appl. Phys., 1989, 28, p 866–871CrossRef T. Osaka, K. Arai, N. Masubuchi, Y. Yanazaki, and T. Namikawa, Transmission Electron Microscopic Study of Electroless Nickel-Molybdenum-Boron Alloy Films, Jap. J. Appl. Phys., 1989, 28, p 866–871CrossRef
13.
go back to reference S. Karthikeyan, K.N. Srinivasan, T. Vasudevan, S. John, A. Gopalan, and G. Paruthimal Kalaignan, Characterisation of Nickel Phosphorus Silicon Carbide Composite Coatings, Bull. Electrochemie., 2001, 17, p 127–130 S. Karthikeyan, K.N. Srinivasan, T. Vasudevan, S. John, A. Gopalan, and G. Paruthimal Kalaignan, Characterisation of Nickel Phosphorus Silicon Carbide Composite Coatings, Bull. Electrochemie., 2001, 17, p 127–130
14.
go back to reference K.H. Hou, M.C. Jeng, and M.D. Ger, The Heat Treatment Effects on the Structure and Wear Behavior of Pulse Electroforming Ni-P Alloy Coatings, J. Alloys Compd., 2007, 437, p 289–297CrossRef K.H. Hou, M.C. Jeng, and M.D. Ger, The Heat Treatment Effects on the Structure and Wear Behavior of Pulse Electroforming Ni-P Alloy Coatings, J. Alloys Compd., 2007, 437, p 289–297CrossRef
15.
go back to reference Z.Y. Jin, P.P. Li, B.Z. Zheng, and D. Xiao, The Structure and Properties of Electroless Ni-Mo-Cr-P Coatings on Copper Alloy, Mater. Corr., 2013, 64, p 341–346 Z.Y. Jin, P.P. Li, B.Z. Zheng, and D. Xiao, The Structure and Properties of Electroless Ni-Mo-Cr-P Coatings on Copper Alloy, Mater. Corr., 2013, 64, p 341–346
16.
go back to reference V. Krutskikh, M. Ivanov, A. Drovosekov, E. Lubnin, B.F. Lyakhov, and Y. Polukarov, Structural Characteristics and Catalytic Activities of Nanocrystalline Ni-B-Mo Coating Obtained by Catalytic Elecroless Reduction, Prot. Metals, 2007, 43, p 560–566CrossRef V. Krutskikh, M. Ivanov, A. Drovosekov, E. Lubnin, B.F. Lyakhov, and Y. Polukarov, Structural Characteristics and Catalytic Activities of Nanocrystalline Ni-B-Mo Coating Obtained by Catalytic Elecroless Reduction, Prot. Metals, 2007, 43, p 560–566CrossRef
17.
go back to reference C.Y. Bai, Y.H. Chou, C.L. Chao, S.J. Lee, and M.D. Ger, Evaluation of Corrosion Resistance of Electroless Ni-P/Ni-W-P Double Layer Coatings on 6061 Aluminium Alloy, J. Power Source, 2008, 183, p 174–181CrossRef C.Y. Bai, Y.H. Chou, C.L. Chao, S.J. Lee, and M.D. Ger, Evaluation of Corrosion Resistance of Electroless Ni-P/Ni-W-P Double Layer Coatings on 6061 Aluminium Alloy, J. Power Source, 2008, 183, p 174–181CrossRef
18.
go back to reference J.F. Li and C.X. Ding, Improvement in Tribological Properties of Plasma-Sprayed Cr C-NiCr32 Coating Followed by Electroless Ni-Based Alloy Plating, Wear, 2000, 240, p 180–185 CrossRef J.F. Li and C.X. Ding, Improvement in Tribological Properties of Plasma-Sprayed Cr C-NiCr32 Coating Followed by Electroless Ni-Based Alloy Plating, Wear, 2000, 240, p 180–185 CrossRef
19.
go back to reference L. Melo, N.S. Casciano, N. Correia, and P. Lima-Meto, Characterisation of Electrodeposited and Heat-Treated Ni-Mo-P Coatings, J. Braz. Chem. Soc., 2012, 23, p 328–334CrossRef L. Melo, N.S. Casciano, N. Correia, and P. Lima-Meto, Characterisation of Electrodeposited and Heat-Treated Ni-Mo-P Coatings, J. Braz. Chem. Soc., 2012, 23, p 328–334CrossRef
20.
go back to reference Y.H. Chou, C.Y. Bai, M.D. Ger, S.J. Lee, C.Y. Lee, and C.L. Chao, Studies on Ni-Mo-P Coatings by Electroless Deposition, Key Eng. Mater., 2008, 364–366, p 333–339 CrossRef Y.H. Chou, C.Y. Bai, M.D. Ger, S.J. Lee, C.Y. Lee, and C.L. Chao, Studies on Ni-Mo-P Coatings by Electroless Deposition, Key Eng. Mater., 2008, 364–366, p 333–339 CrossRef
21.
go back to reference Ichiro Koiwa, Masahiko Usuda, Keizo Yamada, and Tetsuya Osaka, Effect of Heat-Treatment on Properties of Electroless-Deposited Nickel-Molybdenum-Phosphorus Alloy Films, J. Electrochem Soc., 1988, 135, p 718–726 CrossRef Ichiro Koiwa, Masahiko Usuda, Keizo Yamada, and Tetsuya Osaka, Effect of Heat-Treatment on Properties of Electroless-Deposited Nickel-Molybdenum-Phosphorus Alloy Films, J. Electrochem Soc., 1988, 135, p 718–726 CrossRef
22.
go back to reference T. Osaka, K. Arai, and T. Masubuchi, The Formation and Structure of Electroless Ni-Mo-B Alloy Films, J. Metal Finish. Soc. Jpn., 1988, 39, p 782–787 T. Osaka, K. Arai, and T. Masubuchi, The Formation and Structure of Electroless Ni-Mo-B Alloy Films, J. Metal Finish. Soc. Jpn., 1988, 39, p 782–787
23.
go back to reference B. Kaya, T. Gulmez, and M. Demirkol, Preparation and Properties of Electroless Ni-B and Ni-B nanocomposite Coatings, Proceedings of the World Congress on Engineering and Computer Science, October 22-24, 2008, (San Francisco, USA), B. Kaya, T. Gulmez, and M. Demirkol, Preparation and Properties of Electroless Ni-B and Ni-B nanocomposite Coatings, Proceedings of the World Congress on Engineering and Computer Science, October 22-24, 2008, (San Francisco, USA),
24.
go back to reference C. Rios, A. Macias, R.T. Sanchez, M.A. Ramos, and J.G. Hermandez, Measurement of Mechanical Properties of an Electroless Ni-B Coating Using Nanoindentation, Ind. Eng. Chem. Res., 2012, 51, p 7762–7768 CrossRef C. Rios, A. Macias, R.T. Sanchez, M.A. Ramos, and J.G. Hermandez, Measurement of Mechanical Properties of an Electroless Ni-B Coating Using Nanoindentation, Ind. Eng. Chem. Res., 2012, 51, p 7762–7768 CrossRef
25.
go back to reference S. Ziywan, W. Deping, and D. Zhimin, Nanocrystalline Ni-B Coating Surface Strengthening Pure Copper, Appl. Surf. Sci., 2006, 253, p 1051–1054CrossRef S. Ziywan, W. Deping, and D. Zhimin, Nanocrystalline Ni-B Coating Surface Strengthening Pure Copper, Appl. Surf. Sci., 2006, 253, p 1051–1054CrossRef
26.
go back to reference V. Vitry, A.F. Kanta, J. Dille, and F. Delaunois, Structural State of Electroless Nickel-Boron Deposits (5 wt.% B): Characterization by XRD and TEM, Surf. Coat. Technol., 2012, 206, p 3444–3449CrossRef V. Vitry, A.F. Kanta, J. Dille, and F. Delaunois, Structural State of Electroless Nickel-Boron Deposits (5 wt.% B): Characterization by XRD and TEM, Surf. Coat. Technol., 2012, 206, p 3444–3449CrossRef
27.
go back to reference F. Delaunois and P. Lienard, Heat Treatments for Electroless Nickel-Boron Plating on Aluminium Alloys, Surf. Coat. Technol., 2002, 160, p 239–248 CrossRef F. Delaunois and P. Lienard, Heat Treatments for Electroless Nickel-Boron Plating on Aluminium Alloys, Surf. Coat. Technol., 2002, 160, p 239–248 CrossRef
28.
go back to reference C.T. Dervos, J. Novakovic, and P. Vassiliou, Vacuum Heat Treatment of Electroless Ni-B Coatings, Mater. Lett., 2004, 58, p 619–623CrossRef C.T. Dervos, J. Novakovic, and P. Vassiliou, Vacuum Heat Treatment of Electroless Ni-B Coatings, Mater. Lett., 2004, 58, p 619–623CrossRef
29.
go back to reference T. Narayanan, A. Stephan, and S. Guruskanthan, Electroless Ni-Co-B Ternary Alloy Deposits: Preparation and Characteristics, Surf. Coat. Technol., 2004, 179, p 56–62 CrossRef T. Narayanan, A. Stephan, and S. Guruskanthan, Electroless Ni-Co-B Ternary Alloy Deposits: Preparation and Characteristics, Surf. Coat. Technol., 2004, 179, p 56–62 CrossRef
30.
go back to reference Y.N. Bekish, S.K. Poznyak, L.S. Tsybulskaya, and T.V. Gaevskaya, Electrodeposited Ni-B alloy coatings: Structure, corrosion resistance and mechanical properties, Electroch. Acta., 2010, 55, p 2223–2231 CrossRef Y.N. Bekish, S.K. Poznyak, L.S. Tsybulskaya, and T.V. Gaevskaya, Electrodeposited Ni-B alloy coatings: Structure, corrosion resistance and mechanical properties, Electroch. Acta., 2010, 55, p 2223–2231 CrossRef
31.
go back to reference A. Kanta, V. Vitry, and F. Delaunois, Wear and Corrosion Resistance of Electroless Nickel-Boron Coated Mild Steel, Mater. Sci. For., 2010, 638, p 846–851 A. Kanta, V. Vitry, and F. Delaunois, Wear and Corrosion Resistance of Electroless Nickel-Boron Coated Mild Steel, Mater. Sci. For., 2010, 638, p 846–851
32.
go back to reference V. Vitry, A.F. Kanta, and F. Delaunois, Synthesis of Nanocrystalline Ni-B Alloy by Electroless Deposition and Effect of Heat Treatments on Their Structural State, Euromat 2011, 2011, (Montpellier), France, V. Vitry, A.F. Kanta, and F. Delaunois, Synthesis of Nanocrystalline Ni-B Alloy by Electroless Deposition and Effect of Heat Treatments on Their Structural State, Euromat 2011, 2011, (Montpellier), France,
33.
go back to reference K. Krishnaveni, T. Narayanan, and S. Seshadri, Electroless Ni-B Coatings: Preparation and Evaluation of Hardness and Wear Resistance Original, Surf. Coat. Technol., 2005, 190, p 115–121CrossRef K. Krishnaveni, T. Narayanan, and S. Seshadri, Electroless Ni-B Coatings: Preparation and Evaluation of Hardness and Wear Resistance Original, Surf. Coat. Technol., 2005, 190, p 115–121CrossRef
34.
go back to reference M. Anik, E. Körpe, and E. Sen, Effect of Coating Bath Composition on the Properties of Electroless Nickel-Boron Films, Surf. Coat. Technol., 2008, 202, p 1718–1727 CrossRef M. Anik, E. Körpe, and E. Sen, Effect of Coating Bath Composition on the Properties of Electroless Nickel-Boron Films, Surf. Coat. Technol., 2008, 202, p 1718–1727 CrossRef
35.
go back to reference V. Vitry, A.F. Kanta, and F. Delaunois, Mechanical and Wear Characterization of Electroless Nickel-Boron Coatings, Surf. Coat. Technol., 2011, 206, p 1879–1885 CrossRef V. Vitry, A.F. Kanta, and F. Delaunois, Mechanical and Wear Characterization of Electroless Nickel-Boron Coatings, Surf. Coat. Technol., 2011, 206, p 1879–1885 CrossRef
36.
go back to reference Y.W. Riddle and T.O. Bailer, Friction and Wear Reduction via a Ni-B Electroless Bath Coating for Metal Alloys, J. Min. Met. Mater. Soc., 2005, 4, p 40–45 CrossRef Y.W. Riddle and T.O. Bailer, Friction and Wear Reduction via a Ni-B Electroless Bath Coating for Metal Alloys, J. Min. Met. Mater. Soc., 2005, 4, p 40–45 CrossRef
37.
go back to reference E. Correa, A. Zuleta, L. Guerra, M.A. Gomez, and G. Castano, Coating Development During Electroless Ni-B Plating on Magnesium and AZ91D Alloy, Surf. Coat. Technol., 2013, 232, p 784–794CrossRef E. Correa, A. Zuleta, L. Guerra, M.A. Gomez, and G. Castano, Coating Development During Electroless Ni-B Plating on Magnesium and AZ91D Alloy, Surf. Coat. Technol., 2013, 232, p 784–794CrossRef
38.
go back to reference A. Contreras, C. Leon, O. Jimenez, E. Sosa, and R. Perez, Electrochemical Behavior and Microstructural Characterization of 1026 Ni-B Coated Steel, Appl. Surf. Sci., 2006, 253, p 592–599CrossRef A. Contreras, C. Leon, O. Jimenez, E. Sosa, and R. Perez, Electrochemical Behavior and Microstructural Characterization of 1026 Ni-B Coated Steel, Appl. Surf. Sci., 2006, 253, p 592–599CrossRef
39.
go back to reference C. León, E. García-Ochoa, J. García-Guerra, and J. González-Sánchez, Annealing Temperature Effect on the Corrosion Parameters of Autocatalytically Produced Ni-P and Ni-P-Al2O3 Coatings in Artificial Seawater, Surf. Coat. Technol., 2010, 205, p 2425–2431CrossRef C. León, E. García-Ochoa, J. García-Guerra, and J. González-Sánchez, Annealing Temperature Effect on the Corrosion Parameters of Autocatalytically Produced Ni-P and Ni-P-Al2O3 Coatings in Artificial Seawater, Surf. Coat. Technol., 2010, 205, p 2425–2431CrossRef
40.
go back to reference A. Farzaneh, M. Ehteshamzadeh, and M. Mohammadi, Corrosion Performance of the Electroless Ni-P Coatings Prepared in Different Conditions and Optimized by the Taguchi Method, J. Appl. Electrochem., 2011, 41, p 19–27CrossRef A. Farzaneh, M. Ehteshamzadeh, and M. Mohammadi, Corrosion Performance of the Electroless Ni-P Coatings Prepared in Different Conditions and Optimized by the Taguchi Method, J. Appl. Electrochem., 2011, 41, p 19–27CrossRef
41.
go back to reference A. Göksenli, B. Yüksel, A. Yildiz, F. Muhaffel, A. Aydeniz, and G. Dil, Effect of Annealing Temperature on the Corrosion Resistance of Electroless Ni-B Coatings, The 1st International Conference on Surface Engineering, 2013 Busan, Korea A. Göksenli, B. Yüksel, A. Yildiz, F. Muhaffel, A. Aydeniz, and G. Dil, Effect of Annealing Temperature on the Corrosion Resistance of Electroless Ni-B Coatings, The 1st International Conference on Surface Engineering, 2013 Busan, Korea
42.
go back to reference I. Serin and A. Göksenli, Effect of Annealing Temperature on Hardness and Wear Resistance of Electroless Ni-B-Mo Coatings, The 1st International Conference on Surface Engineering, 2013 Busan, Korea I. Serin and A. Göksenli, Effect of Annealing Temperature on Hardness and Wear Resistance of Electroless Ni-B-Mo Coatings, The 1st International Conference on Surface Engineering, 2013 Busan, Korea
Metadata
Title
Effect of Annealing Temperature on the Corrosion Resistance of Electroless Ni-B-Mo Coatings
Authors
Ihsan Gökhan Serin
Ali Göksenli
Behiye Yüksel
Rasid Ahmed Yildiz
Publication date
01-08-2015
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 8/2015
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-015-1568-0

Other articles of this Issue 8/2015

Journal of Materials Engineering and Performance 8/2015 Go to the issue

Premium Partners