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Published in: Journal of Materials Engineering and Performance 12/2017

30-10-2017

Effect of Cerium Oxide on Morphologies and Electrochemical Properties of Ni-W-P Coating on AZ91D Magnesium

Authors: Wan-chang Sun, Jia-Min Xu, Yuan Wang, Fang Guo, Zong-Wei Jia

Published in: Journal of Materials Engineering and Performance | Issue 12/2017

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Abstract

AZ91D magnesium alloy substrate was first pretreated in a phosphoric acid to obtain a phosphate coating, and then, the electroless ternary Ni-W-P coating was deposited using a sulfate nickel bath. The morphologies of the Ni-W-P coating were observed by using scanning electron microscope, the deposition rate of the coating was examined with the method of gravimetric analysis, and the phase analysis was identified by x-ray diffractometer. Electrochemical property was tested by means of an electrochemical analyzer. The results indicated that the addition of an optimum concentration of CeO2 (cerium oxide) particles could evidently improve the deposition rate and the stability of the plating bath. However, it acted as an inhibiting effect as the concentration of CeO2 particles exceeded to 8 mg/L in the sulfate nickel bath. The results also revealed that the morphology of Ni-W-P coating became more smooth, compact and uniform with the increase in the concentrations of CeO2 particles in the bath, but the corrosion resistance decreased due to the precipitation of crystal phases (Ni3P, Ni4W, etc.) after heat treatment.

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Metadata
Title
Effect of Cerium Oxide on Morphologies and Electrochemical Properties of Ni-W-P Coating on AZ91D Magnesium
Authors
Wan-chang Sun
Jia-Min Xu
Yuan Wang
Fang Guo
Zong-Wei Jia
Publication date
30-10-2017
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 12/2017
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-017-3038-3

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