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Journal of Materials Engineering and Performance

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29-04-2019

Effect of MgCl₂ on the Corrosion Behavior of Copper Under Periodic Wet/Dry Cycle Condition

Authors: Chen Pan, Mingxiao Guo, Zhenyao Wang

Published in: Journal of Materials Engineering and Performance | Issue 5/2019

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Abstract

The corrosion behaviors of copper under periodic wet/dry cycle conditions were investigated. The characteristics of the corrosion product formed on copper were analyzed by x-ray diffraction, scanning electron microscopy, energy-dispersive spectroscopy, and in situ electrochemical impedance spectroscopy. Weight loss results showed that the corrosion of copper under an MgCl₂ deposition condition was more severe than that under NaCl. The main corrosion products formed on the tested sample under NaCl deposition condition consisted of Cu₂Cl(OH)₃ and Cu₂O, while those under the MgCl₂ deposition condition consisted of Cu₂Cl(OH)₃ and Mg₂(OH)₃Cl·4H₂O. In the case of the NaCl deposition condition, a two-layered structure formed during the corrosion process. However, the corrosion product layer formed on copper under the MgCl₂ deposition condition had an extremely loose structure. The effect of MgCl₂ on the corrosion mechanism of copper is discussed.

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Y.J. Liu, Study on Influence of Native Oxide and Corrosion Products on Atmospheric Corrosion of Pure Al, Corros. Sci., 2014, 80, p 169–176CrossRef

W. Han, C. Pan, and Z.Y. Wang, A Study on the Initial Corrosion Behavior of Carbon Steel Exposed to Outdoor Wet/Dry Cyclic Condition, Corros. Sci., 2014, 88, p 89–100CrossRef

Y.T. Ma, Y. Li, and F.H. Wang, The Atmospheric Corrosion Kinetics of Low Carbon Steel in a Tropical Marine Environment, Corros. Sci., 2010, 52, p 1796–1800CrossRef

M.P. Zheng, Research and Prospection of the Whole World Salt Lake Geology, Foreign Depos. Geol., 1989, 3, p 1–34

Q.X. Li, Z.Y. Wang, W. Han, and E.H. Han, Characterization of the Rust Formed on Weathering Steel Exposed to Qinghai Salt Lake Atmosphere, Corros. Sci., 2008, 50, p 365–371CrossRef

J. Wang, Z.Y. Wang, and W. Ke, Corrosion Behavior of Weathering Steel in Diluted Qinghai Salt Lake Water in a Laboratory Accelerated Test that Involved Cyclic Wet/Dry Conditions, Mater. Chem. Phys., 2010, 124, p 952–958CrossRef

J. Wang, Z.Y. Wang, and W. Ke, Characterisation of Rust Formed on Carbon Steel after Exposure to Open Atmosphere in Qinghai Salt Lake Region, Corros. Eng. Sci. Technol., 2012, 47, p 125–130CrossRef

B.B. Wang, Z.Y. Wang, W. Han, and W. Ke, Atmospheric Corrosion of Aluminium Alloy 2024–T3 Exposed to Salt Lake Environment in Western China, Corros. Sci., 2012, 59, p 63–70CrossRef

A.R. Mendoza, F. Corvo, A. Gomez, and J. Gomez, Influence of the Corrosion Products of Copper on Its Atmospheric Corrosion Kinetics in Tropical Climate, Corros. Sci., 2004, 46, p 1189–1200CrossRef

10.

J. Wu, X.G. Li, C.F. Dong, S.P. Zhang, and J.L. Zhou, Initial Corrosion Behavior of Copper and Brass in Tropical Maritime Atmospheric Environment, J. Chin. Soc. Corros. Prot., 2012, 32, p 70–79

11.

I.T.E. Fonseca, R. Picciochi, M.H. Medonca, and A.C. Ramos, The Atmospheric Corrosion of Copper at Two Sites in Portugal: A Comparative Study, Corros. Sci., 2004, 46, p 547–561CrossRef

12.

H.L. Huang, Z.Q. Pan, X.P. Guo, and Y.B. Qiu, Effect of an Alternating Electric Field on the Atmospheric Corrosion Behavior of Copper Under a Thin Electrolyte Layer, Corros. Sci., 2013, 75, p 100–105CrossRef

13.

Ch Kleber, U. Hilfrich, and M. Schreiner, In Situ QCM and TM–AFM Investigations of the Early Stages of Degradation of Silver and Copper Surfaces, Appl. Surf. Sci., 2007, 253, p 3712–3721CrossRef

14.

X.Y. Zhang, W.L. He, I.O. Wallinder, J.S. Pan, and C. Leygraf, Determination of Instantaneous Corrosion Rates and Runoff Rates of Copper from Naturally Patinated Copper During Continuous Rain Events, Corros. Sci., 2002, 44, p 2131–2151CrossRef

15.

C. Pan, W.Y. Lv, Z.Y. Wang, W. Su, C. Wang, and S.N. Liu, Atmospheric Corrosion of Copper Exposed in a Simulated Coastal–Industrial Atmosphere, J. Mater. Sci. Tech., 2017, 33, p 587–595CrossRef

16.

ISO 8407, Corrosion of Metal and Alloys–Removal of Corrosion Products from Corrosion Test Specimens, The International Organization for Standardization (ISO), Geneva, 2009

17.

W.J. Lorenz and F. Mansfeld, Determination of Corrosion Rates by Electrochemical DC and AC Methods, Corros. Sci., 1981, 21, p 647–672CrossRef

18.

C.L. Li, Y.T. Ma, Y. Li, and F.H. Wang, EIS Monitoring Study of Atmospheric Corrosion Under Variable Relative Humidity, Corros. Sci., 2010, 52, p 3677–3686CrossRef

19.

C. Thee, L. Hao, J.H. Dong, X. Mu, X. Wei, X.F. Li, and W. Ke, Atmospheric Corrosion Monitoring of a Weathering Steel Under an Electrolyte Film in Cyclic Wet/Dry Condition, Corros. Sci., 2014, 78, p 130–137CrossRef

20.

S.X. Li, J.H. Dong, E.H. Han, and W. Ke, Evolvement of Electrochemical Impedance Spectra of a Bi–electrode Cell for Carbon Steel in the Initial Stage of Wet/Dry Process, Corros. Sci. Prot. Technol., 2007, 19, p 167–170

21.

Y. Van Ingelgem, E. Tourwé, J. Vereecken, and A. Hubin, Application of Multisine Impedance Spectroscopy, FE–AES and FE–SEM to Study the Early Stages of Copper Corrosion, Electrochim. Acta, 2008, 53, p 7523–7530CrossRef

22.

G. Žerjav and I. Milošev, Protection of Copper Against Corrosion in Simulated Urban Rain by the Combined Action of Benzotriazole, 2–Mercaptobenzimidazole and Stearic Acid, Corros. Sci., 2015, 98, p 180–191CrossRef

23.

Y.L. Cheng, Z. Zhang, F.H. Cao, J.F. Li, J.Q. Zhang, J.M. Wang, and C.N. Cao, A Study of the Corrosion of Aluminum Alloy 2024–T3 Under Thin Electrolyte Layers, Corros. Sci., 2004, 46, p 1649–1667CrossRef

24.

M. Yamashita, H. Konishi, and T. Kozakura, In Situ Observation of Initial Rust Formation Process on Carbon STEEL under Na₂SO₄ and NaCl Solution Film with Wet/Dry Cycles Using Synchrotron Radiation x–rays, Corros. Sci., 2005, 47, p 2492–2498CrossRef

25.

G. Faita, G. Fiori, and D. Salvadore, Copper Behavior in Acid and Alkaline Brines–I, Kinetics of Anodic Dissolution in 0.5 M NaCl and Free–Corrosion Rates in the Presence of Oxygen, Corros. Sci., 1975, 15, p 383–392CrossRef

26.

X.N. Liao, F.H. Cao, L.Y. Zheng, W.J. Liu, A.N. Chen, J.Q. Zhang, and C.N. Cao, Corrosion Behavior of Copper Under Chloride–Containing Thin Electrolyte Layer, Corros. Sci., 2011, 53, p 3289–3298CrossRef

27.

P. Druska, H.H. Strehblow, and S. Golledge, A Surface Analytical Examination of Passive Layers on CuNi Alloys: PartI. Alkaline solution, Corros. Sci., 1996, 38, p 835–851CrossRef

Title: Effect of MgCl2 on the Corrosion Behavior of Copper Under Periodic Wet/Dry Cycle Condition
Authors: Chen Pan
Mingxiao Guo
Zhenyao Wang
Publication date: 29-04-2019
Publisher: Springer US
Published in: Journal of Materials Engineering and Performance / Issue 5/2019
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-019-04058-3

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