Skip to main content
Top
Published in: Journal of Materials Science: Materials in Electronics 24/2019

14-11-2019

Effect of NaCl on the microstructure and electrical properties of K0.5Na0.5NbO3 ceramics prepared by cold sintering process

Authors: Mengshuang Chi, Weibing Ma, Jingdong Guo, Jinquan Wu, Tingting Li, Shenghui Wang, Pengfei Zhang

Published in: Journal of Materials Science: Materials in Electronics | Issue 24/2019

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

K0.5Na0.5NbO3 ceramics are considered as a potential candidate for PZT due to its excellent electrical properties and high Curie temperature. In this work, Cold sintering process (CSP) has been used in preparing the K0.5Na0.5NbO3-NaCl ceramics. Based on the experimental characterization, utilizing NaCl aqueous solutions as a transient solvent can change the grain microstructure of KNN ceramics, inhibit the volatilization of alkali metal elements, and lower the sintering temperature. As sintering at 900 °C, the electrical properties of the ceramic were Tc= 448 °C, d33= 115 pC/N, kp= 32%, and the obtained sample had an average grain size of 0.5 μm. The results indicate that CSP with NaCl aqueous solutions is an efficient method for low-temperature sintering of KNN ceramics with uniform grain size as well as good performance in electrical properties.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference J. Rodel, K.G. Webber, R. Dittmer, W. Jo, M. Kimura, D. Damjanovic, Transferring lead-free piezoelectric ceramics into application. J. Eur. Ceram. Soc. 35, 1659–1681 (2015)CrossRef J. Rodel, K.G. Webber, R. Dittmer, W. Jo, M. Kimura, D. Damjanovic, Transferring lead-free piezoelectric ceramics into application. J. Eur. Ceram. Soc. 35, 1659–1681 (2015)CrossRef
2.
go back to reference E. Aksel, J.L. Jones, Advances in lead-free piezoelectric materials for sensors and actuators. Sensors 10, 1935–1954 (2010)CrossRef E. Aksel, J.L. Jones, Advances in lead-free piezoelectric materials for sensors and actuators. Sensors 10, 1935–1954 (2010)CrossRef
3.
go back to reference C. Bantignies, E. Filoux, P. Mauchamp, R. Dufait, M.P. Thi, R. Rouffaud, J.M. Gregoire, F. Levassort, Lead-free high-frequency linear-array transducer (30 MHz) for in vivo skin imaging. IEEE Int. Ultra. Sym 3, 777–780 (2013) C. Bantignies, E. Filoux, P. Mauchamp, R. Dufait, M.P. Thi, R. Rouffaud, J.M. Gregoire, F. Levassort, Lead-free high-frequency linear-array transducer (30 MHz) for in vivo skin imaging. IEEE Int. Ultra. Sym 3, 777–780 (2013)
4.
go back to reference Y. Saito, H. Takao, T. Tani, T. Nonoyama, K. Takatori, T. Homma, T. Nagaya, M. Nakamura, Lead-free piezoceramics. Nature 432, 84–87 (2004)CrossRef Y. Saito, H. Takao, T. Tani, T. Nonoyama, K. Takatori, T. Homma, T. Nagaya, M. Nakamura, Lead-free piezoceramics. Nature 432, 84–87 (2004)CrossRef
5.
go back to reference R.X. Huang, Y.J. Zhao, D. Yan, (K0.5Na0.5)NbO3 lead-free ceramics with improved piezoelectricity and field-induced strain. Ceram. Int. 45, 1450–1454 (2019)CrossRef R.X. Huang, Y.J. Zhao, D. Yan, (K0.5Na0.5)NbO3 lead-free ceramics with improved piezoelectricity and field-induced strain. Ceram. Int. 45, 1450–1454 (2019)CrossRef
6.
go back to reference K. Xu, J. Li, X. Lv, J.G. Wu, X.X. Zhang, D.Q. Xiao, J.G. Zhu, Superior piezoelectric properties in potassium-sodium niobate lead-free ceramics. Adv. Mater. 28, 8519–8523 (2016)CrossRef K. Xu, J. Li, X. Lv, J.G. Wu, X.X. Zhang, D.Q. Xiao, J.G. Zhu, Superior piezoelectric properties in potassium-sodium niobate lead-free ceramics. Adv. Mater. 28, 8519–8523 (2016)CrossRef
7.
go back to reference R.X. Huang, Y.Z. Zhao, Y.J. Zhao, R.Z. Liu, H.P. Zhou, Effects of sintering temperature and alkaline elements excess on the structure and electrical properties of (K0.462Na0.48Li0.058)(1+x)NbO3 lead-free piezoelectric ceramics. Curr. Appl. Phys. 11, 1205–1209 (2011)CrossRef R.X. Huang, Y.Z. Zhao, Y.J. Zhao, R.Z. Liu, H.P. Zhou, Effects of sintering temperature and alkaline elements excess on the structure and electrical properties of (K0.462Na0.48Li0.058)(1+x)NbO3 lead-free piezoelectric ceramics. Curr. Appl. Phys. 11, 1205–1209 (2011)CrossRef
8.
go back to reference S.J. Park, H.Y. Park, K.H. Cho, S. Nahm, H.G. Lee, D.H. Kim, B.H. Choi, Effect of CuO on the sintering temperature and piezoelectric properties of lead-free 0.95(Na0.5K0.5)NbO3-0.05CaTiO(3) ceramics. Mater. Res. Bull. 43, 3580–3586 (2008)CrossRef S.J. Park, H.Y. Park, K.H. Cho, S. Nahm, H.G. Lee, D.H. Kim, B.H. Choi, Effect of CuO on the sintering temperature and piezoelectric properties of lead-free 0.95(Na0.5K0.5)NbO3-0.05CaTiO(3) ceramics. Mater. Res. Bull. 43, 3580–3586 (2008)CrossRef
9.
go back to reference M.R. Bafandeh, R. Gharahkhani, M.H. Abbasi, A. Saidi, J.S. Lee, H.S. Han, Improvement of piezoelectric and ferroelectric properties in (K, Na)NbO3- based ceramics via microwave sintering. J. Electroceram. 33, 128–133 (2014)CrossRef M.R. Bafandeh, R. Gharahkhani, M.H. Abbasi, A. Saidi, J.S. Lee, H.S. Han, Improvement of piezoelectric and ferroelectric properties in (K, Na)NbO3- based ceramics via microwave sintering. J. Electroceram. 33, 128–133 (2014)CrossRef
10.
go back to reference R. Chaim, A. Shlayer, C. Estournes, Densification of nanocrystalline Y2O3 ceramic powder by spark plasma sintering. J. Eur. Ceram. Soc. 29, 91–98 (2009)CrossRef R. Chaim, A. Shlayer, C. Estournes, Densification of nanocrystalline Y2O3 ceramic powder by spark plasma sintering. J. Eur. Ceram. Soc. 29, 91–98 (2009)CrossRef
11.
go back to reference M. Cologna, B. Rashkova, R. Raj, Flash sintering of nanograin zirconia in < 5s at 850 °C. J. Am. Ceram. Soc. 93, 3556–3559 (2010)CrossRef M. Cologna, B. Rashkova, R. Raj, Flash sintering of nanograin zirconia in < 5s at 850 °C. J. Am. Ceram. Soc. 93, 3556–3559 (2010)CrossRef
12.
go back to reference I.W. Chen, X.H. Wang, Sintering dense nanocrystalline ceramics without final-stage grain growth. Nature 404, 168–171 (2000)CrossRef I.W. Chen, X.H. Wang, Sintering dense nanocrystalline ceramics without final-stage grain growth. Nature 404, 168–171 (2000)CrossRef
13.
go back to reference H.Z. Guo, J. Guo, A. Baker, C.A. Randall, Hydrothermal-assisted cold sintering process: a new guidance for low-temperature ceramic sintering. ACS Appl. Mater. Interface 8, 20909–20915 (2016)CrossRef H.Z. Guo, J. Guo, A. Baker, C.A. Randall, Hydrothermal-assisted cold sintering process: a new guidance for low-temperature ceramic sintering. ACS Appl. Mater. Interface 8, 20909–20915 (2016)CrossRef
14.
go back to reference H.Z. Guo, A. Baker, J. Guo, C.A. Randall, Protocol for ultralow-temperature ceramic sintering: an integration of nanotechnology and the cold sintering process. ACS Nano 10, 10606–10614 (2016)CrossRef H.Z. Guo, A. Baker, J. Guo, C.A. Randall, Protocol for ultralow-temperature ceramic sintering: an integration of nanotechnology and the cold sintering process. ACS Nano 10, 10606–10614 (2016)CrossRef
15.
go back to reference J. Guo, S.S. Berbano, H.Z. Guo, A.L. Baker, M.T. Lanagan, C.A. Randall, Cold sintering process of composites: bridging the processing temperature gap of ceramic and polymer materials. Adv. Funct. Mater. 26, 7115–7121 (2016)CrossRef J. Guo, S.S. Berbano, H.Z. Guo, A.L. Baker, M.T. Lanagan, C.A. Randall, Cold sintering process of composites: bridging the processing temperature gap of ceramic and polymer materials. Adv. Funct. Mater. 26, 7115–7121 (2016)CrossRef
16.
go back to reference H. Kahari, M. Teirikangas, J. Juuti, H. Jantunen, Improvements and modifications to room-temperature fabrication method for dielectric Li2MoO4 ceramics. J. Am. Ceram. Soc. 98, 687–689 (2015)CrossRef H. Kahari, M. Teirikangas, J. Juuti, H. Jantunen, Improvements and modifications to room-temperature fabrication method for dielectric Li2MoO4 ceramics. J. Am. Ceram. Soc. 98, 687–689 (2015)CrossRef
17.
go back to reference H.Z. Guo, A. Baker, J. Guo, C.A. Randall, Cold sintering process: a novel technique for low-temperature ceramic processing of ferroelectrics. J. Am. Ceram. Soc. 99, 3489–3507 (2016)CrossRef H.Z. Guo, A. Baker, J. Guo, C.A. Randall, Cold sintering process: a novel technique for low-temperature ceramic processing of ferroelectrics. J. Am. Ceram. Soc. 99, 3489–3507 (2016)CrossRef
18.
go back to reference L. Li, W.B. Hong, S. Yang, H. Yan, X.M. Chen, Effects of water content during cold sintering process of NaCl ceramics. J. Alloys Compd. 787, 352–357 (2019)CrossRef L. Li, W.B. Hong, S. Yang, H. Yan, X.M. Chen, Effects of water content during cold sintering process of NaCl ceramics. J. Alloys Compd. 787, 352–357 (2019)CrossRef
19.
go back to reference J. Ma, H. Li, H. Wang, C. Lin, X. Wu, T. Lin, X. Zheng, X. Yu, Composition, microstructure and electrical properties of K0.5Na0.5NbO3 ceramics fabricated by cold sintering assisted sintering. J. Eur. Ceram. Soc. 39, 986–993 (2019)CrossRef J. Ma, H. Li, H. Wang, C. Lin, X. Wu, T. Lin, X. Zheng, X. Yu, Composition, microstructure and electrical properties of K0.5Na0.5NbO3 ceramics fabricated by cold sintering assisted sintering. J. Eur. Ceram. Soc. 39, 986–993 (2019)CrossRef
20.
go back to reference H.Q. Huang, J. Tang, J. Liu, Preparation of Na0.5Bi0.5TiO3 ceramics by hydrothermal-assisted cold sintering. Ceram. Int. 45, 6753–6758 (2019)CrossRef H.Q. Huang, J. Tang, J. Liu, Preparation of Na0.5Bi0.5TiO3 ceramics by hydrothermal-assisted cold sintering. Ceram. Int. 45, 6753–6758 (2019)CrossRef
21.
go back to reference D.X. Wang, H.Z. Guo, C.S. Morandi, C.A. Randall, S. Trolier-McKinstry, Cold sintering and electrical characterization of lead zirconate titanate piezoelectric ceramics. APL Mater. 6, 016101 (2018)CrossRef D.X. Wang, H.Z. Guo, C.S. Morandi, C.A. Randall, S. Trolier-McKinstry, Cold sintering and electrical characterization of lead zirconate titanate piezoelectric ceramics. APL Mater. 6, 016101 (2018)CrossRef
22.
go back to reference O. Ozmen, C. Ozsoy-Keskinbora, E. Suvaci, Chemical stability of KNbO3, NaNbO3, and K0.5Na0.5NbO3 in aqueous medium. J. Am. Ceram. Soc. 101, 1074–1086 (2018)CrossRef O. Ozmen, C. Ozsoy-Keskinbora, E. Suvaci, Chemical stability of KNbO3, NaNbO3, and K0.5Na0.5NbO3 in aqueous medium. J. Am. Ceram. Soc. 101, 1074–1086 (2018)CrossRef
23.
go back to reference Y.J. Dai, X.W. Zhang, K.P. Chen, Morphotropic phase boundary and electrical properties of K1−xNaxNbO3 lead-free ceramics. Appl. Phys. Lett. 94, 042905 (2009)CrossRef Y.J. Dai, X.W. Zhang, K.P. Chen, Morphotropic phase boundary and electrical properties of K1−xNaxNbO3 lead-free ceramics. Appl. Phys. Lett. 94, 042905 (2009)CrossRef
24.
go back to reference J. Fu, R. Zuo, Y. Xu, J.-F. Li, M. Shi, Investigations of domain switching and lattice strains in (Na, K)NbO3-based lead-free ceramics across orthorhombic-tetragonal phase boundary. J. Eur. Ceram. Soc. 37, 975–983 (2017)CrossRef J. Fu, R. Zuo, Y. Xu, J.-F. Li, M. Shi, Investigations of domain switching and lattice strains in (Na, K)NbO3-based lead-free ceramics across orthorhombic-tetragonal phase boundary. J. Eur. Ceram. Soc. 37, 975–983 (2017)CrossRef
25.
go back to reference H.C. Thong, Q. Li, M.H. Zhang, C.L. Zhao, K.X. Huang, J.F. Li, K. Wang, Defect suppression in CaZrO3-modified (K, Na)NbO3-based lead-free piezoceramic by sintering atmosphere control. J. Am. Ceram. Soc. 101, 3393–3401 (2018)CrossRef H.C. Thong, Q. Li, M.H. Zhang, C.L. Zhao, K.X. Huang, J.F. Li, K. Wang, Defect suppression in CaZrO3-modified (K, Na)NbO3-based lead-free piezoceramic by sintering atmosphere control. J. Am. Ceram. Soc. 101, 3393–3401 (2018)CrossRef
26.
go back to reference M. Feizpour, T. Ebadzadeh, D. Jenko, Synthesis and characterization of lead-free piezoelectric (K0.50Na0.50)NbO3 powder produced at lower calcination temperatures: a comparative study with a calcination temperature of 850 °C. J. Eur. Ceram. Soc. 36, 1595–1603 (2016)CrossRef M. Feizpour, T. Ebadzadeh, D. Jenko, Synthesis and characterization of lead-free piezoelectric (K0.50Na0.50)NbO3 powder produced at lower calcination temperatures: a comparative study with a calcination temperature of 850 °C. J. Eur. Ceram. Soc. 36, 1595–1603 (2016)CrossRef
27.
go back to reference J.P. Ma, X.M. Chen, W.Q. Ouyang, J. Wang, H. Li, J.L. Fang, Microstructure, dielectric, and energy storage properties of BaTiO3 ceramics prepared via cold sintering. Ceram. Int. 44, 4436–4441 (2018)CrossRef J.P. Ma, X.M. Chen, W.Q. Ouyang, J. Wang, H. Li, J.L. Fang, Microstructure, dielectric, and energy storage properties of BaTiO3 ceramics prepared via cold sintering. Ceram. Int. 44, 4436–4441 (2018)CrossRef
28.
go back to reference Y.-H. Lee, J.-H. Cho, B.-I. Kim, D.-K. Choi, Piezoelectric properties and densification based on control of volatile mass of potassium and sodium in (K0.5Na0.5)NbO3 ceramics. Jpn. J. Appl. Phys. 47, 4620–4622 (2008)CrossRef Y.-H. Lee, J.-H. Cho, B.-I. Kim, D.-K. Choi, Piezoelectric properties and densification based on control of volatile mass of potassium and sodium in (K0.5Na0.5)NbO3 ceramics. Jpn. J. Appl. Phys. 47, 4620–4622 (2008)CrossRef
29.
go back to reference D.W. Wang, F. Hussain, A. Khesro, A. Feteira, Y. Tian, Q.L. Zhao, I.M. Reaney, Composition and temperature dependence of structure and piezoelectricity in (1−x)(K1−yNay)NbO3−x(Bi1/2Na1/2)ZrO3 lead-free ceramics. J. Am. Ceram. Soc. 100, 627–637 (2017)CrossRef D.W. Wang, F. Hussain, A. Khesro, A. Feteira, Y. Tian, Q.L. Zhao, I.M. Reaney, Composition and temperature dependence of structure and piezoelectricity in (1−x)(K1−yNay)NbO3−x(Bi1/2Na1/2)ZrO3 lead-free ceramics. J. Am. Ceram. Soc. 100, 627–637 (2017)CrossRef
30.
go back to reference L. Jin, F. Li, S.J. Zhang, Decoding the fingerprint of ferroelectric loops: comprehension of the material properties and structures. J. Am. Ceram. Soc. 97, 1–27 (2014)CrossRef L. Jin, F. Li, S.J. Zhang, Decoding the fingerprint of ferroelectric loops: comprehension of the material properties and structures. J. Am. Ceram. Soc. 97, 1–27 (2014)CrossRef
31.
go back to reference M. Dawber, K. Rabe, J. Scott, Physics of thin-film ferroelectric oxides. Rev. Mod. Phys. 77, 1083 (2005)CrossRef M. Dawber, K. Rabe, J. Scott, Physics of thin-film ferroelectric oxides. Rev. Mod. Phys. 77, 1083 (2005)CrossRef
32.
go back to reference H.C. Thong, C.L. Zhao, Z.X. Zhu, X. Chen, J.F. Li, K. Wang, The impact of chemical heterogeneity in lead-free (K, Na)NbO3 piezoelectric perovskite: ferroelectric phase coexistence. Acta Mater. 166, 551–559 (2019)CrossRef H.C. Thong, C.L. Zhao, Z.X. Zhu, X. Chen, J.F. Li, K. Wang, The impact of chemical heterogeneity in lead-free (K, Na)NbO3 piezoelectric perovskite: ferroelectric phase coexistence. Acta Mater. 166, 551–559 (2019)CrossRef
33.
go back to reference C.A. Randall, N. Kim, J.P. Kucera, W.W. Cao, T.R. Shrout, Intrinsic and extrinsic size effects in fine-grained morphotropic-phase-boundary lead zirconate titanate ceramics. J. Am. Ceram. Soc. 81, 677–688 (1998)CrossRef C.A. Randall, N. Kim, J.P. Kucera, W.W. Cao, T.R. Shrout, Intrinsic and extrinsic size effects in fine-grained morphotropic-phase-boundary lead zirconate titanate ceramics. J. Am. Ceram. Soc. 81, 677–688 (1998)CrossRef
34.
go back to reference J.F. Li, Y.H. Zhen, B.P. Zhang, L.M. Zhang, K. Wang, Normal sintering of (K, Na)NbO3-based lead-free piezoelectric ceramics. Ceram. Int. 34, 783–786 (2008)CrossRef J.F. Li, Y.H. Zhen, B.P. Zhang, L.M. Zhang, K. Wang, Normal sintering of (K, Na)NbO3-based lead-free piezoelectric ceramics. Ceram. Int. 34, 783–786 (2008)CrossRef
35.
go back to reference M. Eriksson, H.X. Yan, G. Viola, H.P. Ning, D. Gruner, M. Nygren, M.J. Reece, Z.J. Shen, Ferroelectric domain structures and electrical properties of fine-grained lead-free sodium potassium niobate ceramics. J. Am. Ceram. Soc. 94, 3391–3396 (2011)CrossRef M. Eriksson, H.X. Yan, G. Viola, H.P. Ning, D. Gruner, M. Nygren, M.J. Reece, Z.J. Shen, Ferroelectric domain structures and electrical properties of fine-grained lead-free sodium potassium niobate ceramics. J. Am. Ceram. Soc. 94, 3391–3396 (2011)CrossRef
36.
go back to reference L. Egerton, D.M. Dillon, Piezoelectric and dielectric properties of ceramics in the system potassium–sodium niobate. J. Am. Ceram. Soc. 42, 438–442 (1959)CrossRef L. Egerton, D.M. Dillon, Piezoelectric and dielectric properties of ceramics in the system potassium–sodium niobate. J. Am. Ceram. Soc. 42, 438–442 (1959)CrossRef
Metadata
Title
Effect of NaCl on the microstructure and electrical properties of K0.5Na0.5NbO3 ceramics prepared by cold sintering process
Authors
Mengshuang Chi
Weibing Ma
Jingdong Guo
Jinquan Wu
Tingting Li
Shenghui Wang
Pengfei Zhang
Publication date
14-11-2019
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 24/2019
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-02523-2

Other articles of this Issue 24/2019

Journal of Materials Science: Materials in Electronics 24/2019 Go to the issue