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Colloid and Polymer Science

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01-02-2014 | Original Contribution

Effect of surfactant on electrokinetic properties of polyindole/TiO₂-conducting nanocomposites in aqueous and nonaqueous media

Authors: Halil Ibrahim Unal, Bekir Sahan, Ozlem Erol

Published in: Colloid and Polymer Science | Issue 2/2014

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Abstract

In this study, polyindole (PIN)/TiO₂ nanocomposites were synthesized with and without the presence of sodium dodecylsulfate, anionic surfactant, with two different PIN contents. The synthesized materials were subjected to various characterizations namely: particle size, apparent density, conductivity, dielectric constants, magnetic susceptibility, elemental analysis, Fourier transform infrared spectroscopy spectroscopy, thermogravimetric analysis, X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. Characterization results revealed the successful preparations of PIN/TiO₂ hybrid nanocomposites. Electrokinetic properties of all the materials were determined by zeta (ζ)-potential measurements in aqueous and nonqueous media. Effects of pH, temperature, presence of various electrolytes, and surfactants on electrokinetic properties of the materials were examined.

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Roy AS, Anilkumar KR, Ambika MVN (2011) Prasad, Core-shell method of synthesis, characterizations, and ac conductivity studies of polyaniline/n-TiO₂ composites. J Appl Polym Sci 121:675–680CrossRef

Yuvaraj H, Shim J-J, Lim KT (2010) Organic–inorganic polypyrrole-surface modified SiO₂ hybrid nanocomposites: a facile and gren synthetic approach. Polym Adv Technol 21:424–429

Eisazadeh H, Khorshidi HR (2010) Preparation and characterization of PAn-HPC/Fe₃O₄ and PAn-HPC/Fe₂O₃ nanocomposite using hydroxypropylcellulose as a steric stabilizer. Polym Plast Technol 49:1591–1596CrossRef

Gangopadhyay R, De A (2000) Conducting polymer nanocomposites: a brief overview. Chem Mater 12:608–622CrossRef

Uygun A, Turkoglu O, Sen S, Ersoy E, Yavuz AG, Batir GG (2009) The electrical conductivity properties of polythiophene/TiO₂ nanocomposites prepared in the presence of surfactants. Curr Appl Phys 9:866–871CrossRef

Erol O, Unal HI, Sari B (2010) Synthesis, electrorheology, and creep behaviors of in-situ intercalated polyindole/organo-montmorillonite conducting nanocomposite. Polym Compos 31:471–481

Trung VQ, Huyen DN (2009) Synthesis, properties and application of polyindole/TiO₂ nanocomposites. J Phys Conf Ser 187:012058CrossRef

Joshi L, Prakash R (2012) Polyindole-Au nanocomposite produced at the liquid/liquid interface. Mater Lett 66:250–253CrossRef

Joshi L, Singh AK, Prakash R (2012) Polyindole/carboxylated-multiwall carbon nanotube composites produced by in-situ and interfacial polymerization. Mater Chem Phys 135:80–87CrossRef

10.

Gomez Costa MB, Juarez JM, Martinez ML, Cussa J, Anunziata OA (2012) Synthesis and characterization of novel composite: polyindole included in nanostructured Al-MCM-41 material, Micropor. Mesoporous Mater 153:191–197CrossRef

11.

Chen H-J, Jian P-C, Chen J-H, Wang L, Chiu W-Y (2007) Nanosized-hybrid colloids of poly(acrylic acid)/titania prepared via in situ sol–gel reaction. Ceram Int 33:643–653CrossRef

12.

Sui X, Chu Y, Xing S, Yu M, Liu C (2004) Self-organization of spherical PANI/TiO₂ nanocomposites in reverse micelles. Colloid Surf A 251:103–107CrossRef

13.

Uygun A, Yavuz AG, Sen S, Omastová M (2009) Polythiophene/SiO₂ nanocomposites prepared in the presence of surfactants and their application to glucose biosensing. Synth Met 159:2022–2028CrossRef

14.

Christian Scientific Equipment Ltd. Road, magnetic susceptibility balance. Instruction Manual. Christian Scientific Equipment Ltd. East Gateshead Industrial Estate, UK no. 6232, p. 8, 1993.

15.

Halsey TC (1992) Electrorheological fluids. Science 258:761–766CrossRef

16.

Basavaraja C, Pierson R, Huh DS (2008) Synthesis, characterization, and comparative study of conducting polyaniline/lead titanate and polyaniline–dodecylbenzenesulfonic acid/lead titanate composites. J Appl Polym Sci 108:1070–1078CrossRef

17.

Khorshidi HR, Eisazadeh H, Khesali AR (2011) Preparation and characterization of polyaniline containing Fe₃O₄ nanoparticles using sodium dodecylbenzenesulfonate as a surfactant. High Perform Polymer 23(2):125–131CrossRef

18.

Kuramoto N, Genies EM (1995) Micellar chemical polymerization of aniline. Synth Met 68(2):191–194CrossRef

19.

Xing S, Zhao G (2006) Morphology and thermostability of polypyrrole prepared from SDBS aqueous solution. Polym Bull 57:933–943CrossRef

20.

Unal HI, Sahan B, Erol O (2012) Investigation of electrokinetic and electrorheological properties of polyindole prepared in the presence of a surfactant. Mater Chem Phys 134:382–391CrossRef

21.

Luo Q, Li X, Wang D, Wang Y, An J (2011) Photocatalytic activity of polypyrrole/TiO₂ nanocomposites under visible and UV light. J Mater Sci 46:1646–1654CrossRef

22.

Dhawan SK, Singh K, Bakhshi AK, Ohlan A (2009) Conducting polymer embedded with nanoferrite and titanium dioxide nanoparticles for microwave absorption. Synth Met 159:2259–2262CrossRef

23.

Gumus OY, Unal HI, Erol O, Sari B (2011) Synthesis, characterization, and colloidal properties of polythiophene/borax conducting composite. Polym Compos 32:418–426CrossRef

24.

Yukselen Y, Kaya A (2003) Zeta potential of kaolinite in the presence of alkali, alkaline earth and hydrolyzable metal ions. Water Air Soil Pollut 145:155–168CrossRef

25.

Kosmulski M, Gustafsson J, Rosenholm JB (1999) Ion specificity and viscosity of rutile dispersions. Colloid Polym Sci 277:550–556CrossRef

26.

Yukselen-Aksoy Y, Kaya A (2011) A study of factors affecting on the zeta potential of kaolinite and quartz powder. Environ Earth Sci 62:697–705CrossRef

27.

Jimeinez ML, Delgado AV, Lyklema J (2012) Hydrolysis versus ion correlation models in electrokinetic charge inversion: establishing application ranges. Langmuir 28:6786–6793CrossRef

28.

Russel WB, Saville DA, Schowalter WR (1989) Colloidal dispersions. Cambridge University Press, CambridgeCrossRef

29.

Tkachenko NH, Yaremko ZM, Bellmann C, Soltys MM (2006) The influence of ionic and nonionic surfactants on aggregative stability and electrical surface properties of aqueous suspensions of titanium dioxide. J Colloid Interf Sci 299:686–695CrossRef

30.

Sato T, Kohnosu S (1991) Effect of surfactant concentration on the stability of aqueous titanium dioxide suspensions. J Colloid Interf Sci 143:434–439CrossRef

31.

Imae T, Muto K, Ikeda S (1991) The pH dependence of dispersion of TiO₂ particles in aqueous surfactant solutions. Colloid Polym Sci 269:43–48CrossRef

32.

Kirby J, Hasselbrink EF (2004) Zeta potential of microfluidic substrates. Electrophoresis 25:203–213

33.

Lin T, Kodger TE, Weitz DA (2013) Transport of charged colloids in a nonpolar solvent. Soft Matter 9:5173–5177CrossRef

Title: Effect of surfactant on electrokinetic properties of polyindole/TiO2-conducting nanocomposites in aqueous and nonaqueous media
Authors: Halil Ibrahim Unal
Bekir Sahan
Ozlem Erol
Publication date: 01-02-2014
Publisher: Springer Berlin Heidelberg
Published in: Colloid and Polymer Science / Issue 2/2014
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-013-3094-7

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