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Colloid and Polymer Science
Published in: Colloid and Polymer Science 2/2014

01-02-2014 | Original Contribution

The electroactive multilayer films of polyelectrolytes and Prussian blue nanoparticles and their application for H2O2 sensors

Authors: Anna Pajor-Świerzy, Marta Kolasińska-Sojka, Piotr Warszyński

Published in: Colloid and Polymer Science | Issue 2/2014

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Abstract

Prussian blue (PB) nanoparticles were immobilized in polyelectrolyte (PE) multilayers of various compositions and thickness. Films containing nanoparticles and poly(allylamine hydrochloride) (PAH) were formed using the layer-by-layer adsorption method. A layer of branched poly(ethyleneimine) (PEI) was used to anchor the multilayer structure at the surface of a gold electrode. The films exhibited electroactive properties, increasing with the number of deposited PB layers. The properties of PEI/(PB/PAH) n multilayers were then compared with the ones containing additionally the conductive polymer poly(3,4-ethylenedioxythiophene)–poly(styrenesulfonate) (PEDOT:PSS). We found that the addition of the conductive, water-soluble polymer enhances the electroactive properties of the multilayer films. It also increased sensitivity of the multilayer-covered electrodes for electrochemical detection of hydrogen peroxide.
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Metadata
Title
The electroactive multilayer films of polyelectrolytes and Prussian blue nanoparticles and their application for H2O2 sensors
Authors
Anna Pajor-Świerzy
Marta Kolasińska-Sojka
Piotr Warszyński
Publication date
01-02-2014
Publisher
Springer Berlin Heidelberg
Published in
Colloid and Polymer Science / Issue 2/2014
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-013-3091-x

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