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Published in: Journal of Materials Science: Materials in Electronics 4/2014

01-04-2014

Effect of Zn addition on primary silicon morphology and B distribution in Si–Al alloy

Authors: Jiayan Li, Pengjun Jia, Yaqiong Li, Panpan Cao, Yao Liu, Yi Tan

Published in: Journal of Materials Science: Materials in Electronics | Issue 4/2014

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Abstract

Si–Al–Zn alloy melts were used for silicon purification by the solvent refining process. The effect of metal Zn addition on alloy macrostructure, primary Si morphology, as well as B distribution in Si–Al alloy during solvent refining process was studied in this work. The three main results were as follows. First, with the increasing of Zn content in Si–Al alloy, the primary silicon changed from slender plate-like to irregular and short, meanwhile the distribution of primary silicon changed from bottom to central and top. Second, the more Zn content in Si–Al alloy, the more inclusions of eutectic melts will be in primary silicon, which results in diffusion difficulty of impurity B in inclusions. Third and last, with increasing Zn content, the refining ratio of B increased gradually and removal fraction of B decreased accordingly.

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Literature
1.
go back to reference H. Yang, H. Wang, The materials characteristic and the efficiency degradation of solar cells from solar grade silicon from a metallurgical process route. J. Mater. Sci. 46, 1044 (2011)CrossRef H. Yang, H. Wang, The materials characteristic and the efficiency degradation of solar cells from solar grade silicon from a metallurgical process route. J. Mater. Sci. 46, 1044 (2011)CrossRef
2.
go back to reference K. Fujiwara, W. Pan, K. Sawada, M. Tokairin, N. Usami, Y. Nose, A. Nomura, T. Shishido, K. Nakajima, Processes for upgrading metallurgical grade silicon to solar grade silicon. J. Cryst. Growth 292, 282 (2006)CrossRef K. Fujiwara, W. Pan, K. Sawada, M. Tokairin, N. Usami, Y. Nose, A. Nomura, T. Shishido, K. Nakajima, Processes for upgrading metallurgical grade silicon to solar grade silicon. J. Cryst. Growth 292, 282 (2006)CrossRef
3.
go back to reference K. Visnovec, C. Variawa, T. Utigard, A. Mitrasinovic, Elimination of impurities from the surface of silicon using hydrochloric and nitric acid. Mater. Sci. Semicond. Process. 16, 106 (2013)CrossRef K. Visnovec, C. Variawa, T. Utigard, A. Mitrasinovic, Elimination of impurities from the surface of silicon using hydrochloric and nitric acid. Mater. Sci. Semicond. Process. 16, 106 (2013)CrossRef
4.
go back to reference B.P. Lee, H.M. Lee, D.H. Park, J.S. Shin, T.U. Yu, B.M. Moon, Refining of MG-S i by hybrid melting using steam plasma and EMC. Sol. Energy Mater. Sol. Cells 95, 56 (2011)CrossRef B.P. Lee, H.M. Lee, D.H. Park, J.S. Shin, T.U. Yu, B.M. Moon, Refining of MG-S i by hybrid melting using steam plasma and EMC. Sol. Energy Mater. Sol. Cells 95, 56 (2011)CrossRef
5.
go back to reference K. Hanazawa, N. Yuge, Y. Kato, Evaporation of phosphorus in molten silicon by an electron beam irradiation method. Mater. Trans. 45, 844 (2004)CrossRef K. Hanazawa, N. Yuge, Y. Kato, Evaporation of phosphorus in molten silicon by an electron beam irradiation method. Mater. Trans. 45, 844 (2004)CrossRef
6.
go back to reference Y.V. Meteleva-Fischer, Y. Yang, R. Boom, B. Kraaijveld, H. Kuntzel, Slag treatment followed by acid leaching as a route to solar-grade silicon. JOM 64, 957 (2012)CrossRef Y.V. Meteleva-Fischer, Y. Yang, R. Boom, B. Kraaijveld, H. Kuntzel, Slag treatment followed by acid leaching as a route to solar-grade silicon. JOM 64, 957 (2012)CrossRef
7.
go back to reference J. Safarian, G. Tranell, M. Tangstad, Processes for upgrading metallurgical grade silicon to solar grade silicon. Energy Procedia 20, 88 (2012)CrossRef J. Safarian, G. Tranell, M. Tangstad, Processes for upgrading metallurgical grade silicon to solar grade silicon. Energy Procedia 20, 88 (2012)CrossRef
8.
go back to reference T. Yoshikawa, K. Morita, Refining of silicon during its solidification from a Si–Al melt. JOM 64, 946 (2012)CrossRef T. Yoshikawa, K. Morita, Refining of silicon during its solidification from a Si–Al melt. JOM 64, 946 (2012)CrossRef
9.
go back to reference T. Yoshikawa, K. Morita, Removal of B from Si by solidification refining with Si–Al melts. Metall. Mater. Trans. B 36(6), 731 (2005)CrossRef T. Yoshikawa, K. Morita, Removal of B from Si by solidification refining with Si–Al melts. Metall. Mater. Trans. B 36(6), 731 (2005)CrossRef
10.
go back to reference T. Yoshikawa, K. Morita, Refining of silicon during its solidification from a Si–Al melt. J. Cryst. Growth 311, 776 (2009)CrossRef T. Yoshikawa, K. Morita, Refining of silicon during its solidification from a Si–Al melt. J. Cryst. Growth 311, 776 (2009)CrossRef
11.
go back to reference X. Ma, T. Yoshikawa, K. Morita, Removal of boron from silicon–tin solvent by slag treatment. Metall. Mater. Trans. B 44, 528 (2013)CrossRef X. Ma, T. Yoshikawa, K. Morita, Removal of boron from silicon–tin solvent by slag treatment. Metall. Mater. Trans. B 44, 528 (2013)CrossRef
12.
go back to reference X. Ma, T. Yoshikawa, K. Morita, Si growth by directional solidification of Si–Sn alloys to produce solar-grade Si. J. Cryst. Growth 377, 192 (2013)CrossRef X. Ma, T. Yoshikawa, K. Morita, Si growth by directional solidification of Si–Sn alloys to produce solar-grade Si. J. Cryst. Growth 377, 192 (2013)CrossRef
13.
go back to reference Visnovec K (2012) Refining of Silicon during its Solidification from a Cu–Si melt. Master Dissertation, University of Toronto Visnovec K (2012) Refining of Silicon during its Solidification from a Cu–Si melt. Master Dissertation, University of Toronto
14.
go back to reference S. Esfahani, M. Barati, Purification of metallurgical silicon using iron as an impurity getter part I: growth and separation of Si. Met. Mater. Int. 17, 823 (2011)CrossRef S. Esfahani, M. Barati, Purification of metallurgical silicon using iron as an impurity getter part I: growth and separation of Si. Met. Mater. Int. 17, 823 (2011)CrossRef
15.
go back to reference S. Esfahani, M. Barati, Purification of metallurgical silicon using iron as impurity getter, part II: extent of silicon purification. Met. Mater. Int. 17, 1009 (2011)CrossRef S. Esfahani, M. Barati, Purification of metallurgical silicon using iron as impurity getter, part II: extent of silicon purification. Met. Mater. Int. 17, 1009 (2011)CrossRef
16.
go back to reference T. Suzuki, “Aluminium–silicon–zinc”, ternary alloys. VCH 8, 338 (1993) T. Suzuki, “Aluminium–silicon–zinc”, ternary alloys. VCH 8, 338 (1993)
17.
go back to reference M. Aono, Y. Ambo, K. Yanagase, Y. Hoshino, Y. Sato, Measurement of the viscosity of molten Zn–Al Alloy. Thermophys. Prop. 27, 200 (2006) M. Aono, Y. Ambo, K. Yanagase, Y. Hoshino, Y. Sato, Measurement of the viscosity of molten Zn–Al Alloy. Thermophys. Prop. 27, 200 (2006)
18.
go back to reference J. Li, Y. Liu, Y. Tan, Y. Li, L. Zhang, S. Wu, P. Jia, Effect of tin addition on primary silicon recovery in Si–Al melt during solidification refining of silicon. J. Cryst. Growth 371, 1 (2013)CrossRef J. Li, Y. Liu, Y. Tan, Y. Li, L. Zhang, S. Wu, P. Jia, Effect of tin addition on primary silicon recovery in Si–Al melt during solidification refining of silicon. J. Cryst. Growth 371, 1 (2013)CrossRef
19.
go back to reference M.W. Ullah, T. Carlberg, Silicon crystal morphologies during solidification refining from Al–Si melts. J. Cryst. Growth 318, 212 (2011)CrossRef M.W. Ullah, T. Carlberg, Silicon crystal morphologies during solidification refining from Al–Si melts. J. Cryst. Growth 318, 212 (2011)CrossRef
Metadata
Title
Effect of Zn addition on primary silicon morphology and B distribution in Si–Al alloy
Authors
Jiayan Li
Pengjun Jia
Yaqiong Li
Panpan Cao
Yao Liu
Yi Tan
Publication date
01-04-2014
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 4/2014
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-014-1794-5

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