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Journal of Materials Engineering and Performance

Published in:

01-08-2014

Electrochemical Evaluation of Corrosion on Borided and Non-borided Steels Immersed in 1 M HCl Solution

Authors: I. Mejía-Caballero, J. Martínez-Trinidad, M. Palomar-Pardavé, M. Romero-Romo, H. Herrera-Hernández, O. Herrera-Soria, I. Campos Silva

Published in: Journal of Materials Engineering and Performance | Issue 8/2014

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Abstract

In this study the corrosion resistances of AISI 1018 and AISI 304 borided and non-borided steels were estimated using polarization resistance and electrochemical impedance spectroscopy (EIS) techniques. Boriding of the steel samples was conducted using the powder-pack method at 1223 K with 6 h of exposure. Structural examinations of the surfaces of the borided steels showed the presence of a Fe₂B layer with isolated FeB teeth on the AISI 1018 steel, whereas a compact layer of FeB/Fe₂B was formed on the AISI 304 steel. Polarization resistance and EIS of the borided and non-borided steels surfaces were performed in a corrosive solution of 1 M HCl. The EIS data were analyzed during 43 days of exposure to the acid solution. Impedance curves obtained during this period for the borided and non-borided steels were modeled using equivalent electrical circuits. The results of both electrochemical techniques indicated that boride layers formed at the steel surfaces effectively protect the samples from the corrosive effects of HCl. The main corrosion processes observed on the boride layers were pitting and crevice corrosion.

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Title: Electrochemical Evaluation of Corrosion on Borided and Non-borided Steels Immersed in 1 M HCl Solution
Authors: I. Mejía-Caballero
J. Martínez-Trinidad
M. Palomar-Pardavé
M. Romero-Romo
H. Herrera-Hernández
O. Herrera-Soria
I. Campos Silva
Publication date: 01-08-2014
Publisher: Springer US
Published in: Journal of Materials Engineering and Performance / Issue 8/2014
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-014-1039-z

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