Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Published in:
Odorant Detection and Discrimination in the Olfactory System Read chapter Read first chapter

2011 | OriginalPaper | Chapter

66. Electrochemically Synthesized Molecularly Imprinted Polymers for Sensing Applications

Authors : Elisabetta Mazzotta, Cosimino Malitesta

Published in: Sensors and Microsystems

Publisher: Springer Netherlands

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

A novel imprinting scheme, combining for the first time electropolymerization with metal-ion coordination, has been proposed. A MIP for a pesticide (4-(2,4-dichlorophenoxy)butyric acid (2,4-DB)) has been prepared from a Co-porphyrin (Co(III)tetrakis(o-aminophenyl) porphyrin (CoTAPP)) as functional monomer. Such an approach aims to combine advantages of electropolymerization with ones related to the use of metal complexes in imprinting procedures. After verification of template entrapment and subsequent removal by XPS spectroscopy, the imprinting effect was verified by comparing electrochemical responses of MIP and not-imprinted polymer (NIP) tested by Cyclic Voltammetry (CV). MIP revealed an enhanced electrocatalytic activity towards 2,4-DB reduction as well as a good selectivity against both pesticides and structurally related compounds.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
previous chapter Multiple Minima Hypersurfaces Procedures for Biomimetic Ligands Screening
next chapter Wireless Energy Consumption Monitor
Literature
1.
Ye L, Haupt K (2004) Molecularly imprinted polymers as antibody and receptor mimics for assays, sensors and drug discovery. Anal Bioanal Chem 378:1887–1897CrossRef
2.
Holthoff EL, Bright FV (2007) Molecularly templated materials in chemical sensing. Anal Chim Acta 594:147–161CrossRef
3.
Malitesta C, Losito I, Zambonin PG (1999) Molecularly imprinted electrosynthesized polymers: new materials for biomimetic sensors. Anal Chem 71:1366–1370CrossRef
4.
Blanco-Lopez MC, Gutierrez-Fernandez S, Lobo-Castanon MJ, Miranda-Ordieres AJ, Tunon-Blanco P (2004) Electrochemical sensing with electrodes modified with molecularly imprinted polymer films. Anal Bioanal Chem 378:1922–1928CrossRef
5.
Ozcan L, Sahin Y (2007) Determination of paracetamol based on electropolymerized-molecularly imprinted polypyrrole modified pencil graphite electrode. Sensor Actuat B 127:362–369CrossRef
6.
Mazzotta E, Malitesta C (2008) Preliminary study on electrosynthesis of a Co-porphyrin based molecularly imprinted polymer for the selective detection of the herbicide 2,4-dichlorophenoxy carboxylic acid. Sensor Lett 6:618–622CrossRef
7.
Dhal PK (2001) Metal-ion coordination in designing molecularly imprinted polymeric receptors. In: Sellergren B (ed) Man-made mimics of antibodies and their applications in analytical chemistry, molecularly imprinted polymers. Elsevier Science, Amsterdam, pp 185–201
8.
Gómez-Caballero A, Ugarte A, Sánchez-Ortega A, Unceta N, Goicolea MA, Barrio RJ (2010) Molecularly imprinted poly[tetra(o-aminophenyl)porphyrin] as a stable and selective coating for the development of voltammetric sensors. J Electroanal Chem 638:246–253CrossRef
Metadata
Title
Electrochemically Synthesized Molecularly Imprinted Polymers for Sensing Applications
Authors
Elisabetta Mazzotta
Cosimino Malitesta
Copyright Year
2011
Publisher
Springer Netherlands
Book
Sensors and Microsystems

Print ISBN: 978-94-007-1323-9

Electronic ISBN: 978-94-007-1324-6

Copyright Year: 2011

DOI
https://doi.org/10.1007/978-94-007-1324-6_66