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Journal of Materials Science: Materials in Electronics

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26-03-2021

Enhanced optical, morphological, dielectric, and conductivity properties of gold nanoparticles doped with PVA/CMC blend as an application in organoelectronic devices

Authors: M. R. Atta, Qana A. Alsulami, G. M. Asnag, A. Rajeh

Published in: Journal of Materials Science: Materials in Electronics | Issue 8/2021

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Abstract

Stevia rebaudiana plant leaves were used for biosynthesis of gold nanoparticles (AuNPs). Transmission electron microscope images showed various shapes and sizes of AuNPs. Various amounts of AuNPs were added to polyvinyl alcohol/carboxymethylcellulose (PVA/CMC, 40/60) via the casting method. The X-ray diffraction (XRD) spectrum of pure blend shows the amorphous nature of the blend. FTIR spectra showed the interaction between PVA/CMC and AuNPs. The ultra-violet and visible spectra showed emerging new peak of surface plasmon resonance of AuNPs for the filled samples. The scanning electron microscope images showed bright spots on the sample’s surface, which was attributed to AuNPs. AC conductivity exhibited enhancement after the addition of gold nanoparticles. The ε′ and ε″ were reduced with increasing the frequency due to direction dipoles of applied electric field. Because of the mobile charges inside the polymeric backbone, higher values of ε′ and ε″ were observed at low frequencies. The tanδ showed increased with an increase in AuNPs concentration and decrease at high frequency, as expected.

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C. Yang, S. Lin, Alkaline composite PEO–PVA–glass-fibre-mat polymer electrolyte for Zn–air battery. J. Power Sources 112, 497–503 (2002)CrossRef

R. Kandulna, R.B. Choudhary, Concentration-dependent behaviors of ZnO-reinforced PVA–ZnO nanocomposites as electron transport materials for OLED application. Polym. Bull. 75, 3089–3107 (2018). https://doi.org/10.1007/s00289-017-2186-9CrossRef

A.M. Hezma, A. Rajeh, M.A. Mannaa, An insight into the effect of zinc oxide nanoparticles on the structural, thermal, mechanical properties and antimicrobial activity of Cs/PVA composite. Colloids Surfaces A Physicochem. Eng. Asp. 581, 123821 (2019). https://doi.org/10.1016/J.COLSURFA.2019.123821CrossRef

A. Rajeh, A.M. Hezma, Spectroscopic and drug delivery studies of moxifloxacin loaded polylactic acid/polycaprolacton polymeric matrix for medical application. Res. J. Pharm. Biol. Chem. Sci. 8, 1163–1170 (2017)

S. Choudhary, P. Dhatarwal, R.J. Sengwa, Study on crystalline phases and degree of crystallinity of the melt compounded PVA/MMT and PVA/PVP/MMT nanocomposites. Indian J. Pure Appl. Phys. 59(2), 92–102 (2021)

X. Ma, P.R. Chang, J. Yu, Properties of biodegradable thermoplastic pea starch/carboxymethyl cellulose and pea starch/microcrystalline cellulose composites. Carbohydr. Polym. 72, 369–375 (2008). https://doi.org/10.1016/J.CARBPOL.2007.09.002CrossRef

P.K. Varshney, S. Gupta, Natural polymer-based electrolytes for electrochemical devices: a review. Ionics 17, 479–483 (2011)CrossRef

M.M. Abutalib, Insights into the structural, optical, thermal, dielectric, and electrical properties of PMMA/PANI loaded with graphene oxide nanoparticles. Phys. B Condens. Matter. 552, 19–29 (2019). https://doi.org/10.1016/J.PHYSB.2018.09.034CrossRef

L.H. Gaabour, Spectroscopic and thermal analysis of polyacrylamide/chitosan (PAM/CS) blend loaded by gold nanoparticles. Results Phys. 7, 2153–2158 (2017). https://doi.org/10.1016/J.RINP.2017.06.027CrossRef

10.

A.M. Abdelghany, A.H. Oraby, M.O. Farea, Influence of green synthesized gold nanoparticles on the structural, optical, electrical and dielectric properties of (PVP/SA) blend. Phys. B Condens. Matter. 560, 162–173 (2019). https://doi.org/10.1016/J.PHYSB.2019.02.029CrossRef

11.

H.M. Ragab, A. Rajeh, Structural, thermal, optical and conductive properties of PAM/PVA polymer composite doped with Ag nanoparticles for electrochemical application. J. Mater. Sci. Mater. Electron. 31, 16780–16792 (2020)CrossRef

12.

E.M. Abdelrazek, I.S. Elashmawi, A.M. Hezma, A. Rajeh, M. Kamal, Effect of an encapsulate carbon nanotubes (CNTs) on structural and electrical properties of PU/PVC nanocomposites. Phys. B Condens. Matter. 502, 48–55 (2016). https://doi.org/10.1016/j.physb.2016.08.040CrossRef

13.

A.M. Hezma, I.S. Elashmawi, A. Rajeh, M. Kamal, Change spectroscopic, thermal and mechanical studies of PU/PVC blends. Phys. B Condens. Matter. 495, 4–10 (2016)CrossRef

14.

I.S. Elashmawi, E.M. Abdelrazek, A.M. Hezma, A. Rajeh, Modification and development of electrical and magnetic properties of PVA/PEO incorporated with MnCl2. Phys. B Condens. Matter. 434, 57–63 (2014). https://doi.org/10.1016/j.physb.2013.10.038CrossRef

15.

E.M. Abdelrazek, I.S. Elashmawi, A.M. Hezma, A. Rajeh, The accessibility of change of the structural, morphological and thermal properties by intermolecular hydrogen bonding in PEO/PVA blend containing MnCl2. Int. J. Mod. App. Phys. 2, 83–96 (2012)

16.

N.H. Ahmad, M.I.N. Isa, Characterization of un-plasticized and propylene carbonate plasticized carboxymethyl cellulose doped ammonium chloride solid biopolymer electrolytes. Carbohydr. Polym. 137, 426–432 (2016). https://doi.org/10.1016/J.CARBPOL.2015.10.092CrossRef

17.

M.M. Abutalib, A. Rajeh, Structural, thermal, optical and conductivity studies of Co/ZnO nanoparticles doped CMC polymer for solid state battery applications. Polym. Testing 91, 106803 (2020)CrossRef

18.

A.M. Abdelghany, A.H. Oraby, G.M. Asnag, Structural, thermal and electrical studies of polyethylene oxide/starch blend containing green synthesized gold nanoparticles. J. Mol. Struct. 1180, 15–25 (2019)CrossRef

19.

A.A. Menazea, N.S. Awwad, H.A. Ibrahium, M.K. Ahmed, Casted polymeric blends of carboxymethyl cellulose/polyvinyl alcohol doped with gold nanoparticles via pulsed laser ablation technique; morphological features, optical and electrical investigation. Radiat. Phys. Chem. 177, 109155 (2020)CrossRef

20.

M.A. Morsi et al., Nanosecond laser-irradiation assisted the improvement of structural, optical and thermal properties of polyvinyl pyrrolidone/carboxymethyl cellulose blend filled with gold nanoparticles. J. Mater. Sci. Mater. Electron. 30, 2693–2705 (2019)CrossRef

21.

M.M. Abutalib, Effect of zinc oxide nanorods on the structural, thermal, dielectric and electrical properties of polyvinyl alcohol/carboxymethyle cellulose composites. Phys. B Condens. Matter. 557, 108–116 (2019). https://doi.org/10.1016/J.PHYSB.2019.01.018CrossRef

22.

S. Al-Thabaiti, M. Malik, A. Al-Youbi, Z. Khan, J. Hussain, Effects of surfactant and polymer on the morphology of advanced nanomaterials in aqueous solution. Int. J. Electrochem. Sci. 8, 204–218 (2013)

23.

A. Rajeh, M.A. Morsi, I.S. Elashmawi, Enhancement of spectroscopic, thermal, electrical and morphological properties of polyethylene oxide/carboxymethyl cellulose blends: combined FT-IR/DFT. Vacuum 159, 430–440 (2019)CrossRef

24.

M.A. Morsi et al., Effect of lithium titanate nanoparticles on the structural, optical, thermal and electrical properties of polyethylene oxide/carboxymethyl cellulose blend. J. Mater. Sci. Mater. Electron. 29(18), 15912–15925 (2018)CrossRef

25.

M.A. Morsi, M. Abdelaziz, A.H. Oraby, I. Mokhles, Structural, optical, thermal, and dielectric properties of polyethylene oxide/carboxymethyl cellulose blend filled with barium titanate. J. Phys. Chem. Solids 125, 103–114 (2019)CrossRef

26.

C. Basavaraja, J.K. Kim, Characterization and temperature-dependent conductivity of polyaniline nanocomposites encapsulating gold nanoparticles on the surface of carboxymethyl cellulose. Mater. Sci. Eng. B 178(2), 167–173 (2013)CrossRef

27.

M.A. Morsi, S.A. El-Khodary, A. Rajeh, Enhancement of the optical, thermal and electrical properties of PEO/PAM: Li polymer electrolyte films doped with Ag nanoparticles. Phys. B Condens. Matter. 539, 88–96 (2018)CrossRef

28.

A. Hebeish, M. Hashem, M.A. El-Hady, S. Sharaf, Development of CMC hydrogels loaded with silver nano-particles for medical applications. Carbohydr. Polymers 92, 407–413 (2013)CrossRef

29.

I. Jahit, N. Nazmi, M. Isa, N. Sarbon, Preparation and physical properties of gelatin/CMC/chitosan composite films as affected by drying temperature. Int. Food Res. J. 3, 1068–1074 (2016)

30.

M.M. Abutalib, A. Rajeh, Influence of MWCNTs/Li-doped TiO₂ nanoparticles on the structural, thermal, electrical and mechanical properties of poly (ethylene oxide)/poly (methylmethacrylate) composite. J. Organomet. Chem. 918, 121309 (2020). https://doi.org/10.1016/J.JORGANCHEM.2020.121309CrossRef

31.

A. El-Aziz, A. Ramadan, M.R. Al-Othman, M.A. Mahmoud, Degradation of DDT by gold nanoparticles synthesised using Lawsonia inermis for environmental safety. Biotechnol. Biotechnol. Equip. 32(5), 1174–1182 (2018)CrossRef

32.

M.M. Abdelrazek et al., Structural, optical, morphological and thermal properties of PEO/PVP blend containing different concentrations of biosynthesized Au nanoparticles. J. Mater. Res. Technol. 7, 419–431 (2018)CrossRef

33.

A.M. Abdelghany, E.M. Abdelrazek, S.I. Badr, M.A. Morsi, Effect of gamma-irradiation on (PEO/PVP)/Au nanocomposite: materials for electrochemical and optical applications. Mater. Des. 97, 532–543 (2016). https://doi.org/10.1016/j.matdes.2016.02.082CrossRef

34.

G. Patel, M. Sureshkumar, P. Patel, Spectroscopic investigation and characterizations of PAM/PEO blends films. Soft Sci. Res. Publ. 4, 9–24 (2015)

35.

A.M. Hezma et al., Enhancement of the thermal and mechanical properties of polyurethane/polyvinyl chloride blend by loading single walled carbon nanotubes. Progress Natl. Sci. Mater. Int. 27, 338–343 (2017)CrossRef

36.

N. Haleem et al., Synthesis of carboxymethyl cellulose from waste of cotton ginning industry. Carbohyd. Polym. 113, 249–255 (2014)CrossRef

37.

M.O. Farea, A.M. Abdelghany, M.S. Meikhail, A.H. Oraby, Effect of cesium bromide on the structural, optical, thermal and electrical properties of polyvinyl alcohol and polyethylene oxide. J. Mater. Res. Technol. 9, 1530–1538 (2020)CrossRef

38.

M.M. Abutalib, A. Rajeh, Preparation and characterization of polyaniline/sodium alginate-doped TiO₂ nanoparticles with promising mechanical and electrical properties and antimicrobial activity for food packaging applications. J. Mater. Sci. Mater. Electron. 31, 1–13 (2020). https://doi.org/10.1007/s10854-020-03483-8CrossRef

39.

M.M. Abutalib, A. Rajeh, Influence of Fe₃O₄ nanoparticles on the optical, magnetic and electrical properties of PMMA/PEO composites: combined FT-IR/DFT for electrochemical applications. J. Organomet. Chem. 920, 121348 (2020). https://doi.org/10.1016/J.JORGANCHEM.2020.121348CrossRef

40.

M.M. Abutalib, A. Rajeh, Influence of ZnO/Ag nanoparticles doping on the structural, thermal, optical and electrical properties of PAM/PEO composite. Phys. B 578, 411796 (2020)CrossRef

41.

M.A. Morsi, A. Rajeh, A.A. Al-Muntaser, Reinforcement of the optical, thermal and electrical properties of PEO based on MWCNTs/Au hybrid fillers: nanodielectric materials for organoelectronic devices. Compos. Part B Eng. 73, 106957 (2019)CrossRef

42.

A. Rajeh, H.M. Ragab, M.M. Abutalib, Co doped ZnO reinforced PEMA/PMMA composite: structural, thermal, dielectric and electrical properties for electrochemical applications. J. Mol. Struct. (2020). https://doi.org/10.1016/j.molstruc.2020.128447CrossRef

43.

M.A. Morsi et al., Nd: YAG nanosecond laser induced growth of Au nanoparticles within CMC/PVA matrix: multifunctional nanocomposites with tunable optical and electrical properties. Compos. Commun. 24, 100662 (2021)CrossRef

44.

E.M. Abdelrazek, I.S. Elashmawi, H.M. Ragab, Manifestation of MnCl₂ fillers incorporated into the polymer matrices in their dielectric properties. Phys. B 403, 3097–3104 (2008)CrossRef

45.

P. Dhatarwal, S. Choudhary, R.J. Sengwa, Electrochemical performance of Li+-ion conducting solid polymer electrolytes based on PEO–PMMA blend matrix incorporated with various inorganic nanoparticles for the lithium ion batteries. Compos. Commun. 10, 11–17 (2018)CrossRef

46.

H. Peng, G. Ma, W. Ying, A. Wang, H. Huang, Z. Lei, In situ synthesis of polyaniline/sodium carboxymethyl cellulose nanorods for high-performance redox supercapacitors. J. Power Sources 211, 40–45 (2012)CrossRef

47.

Q.A. Alsulami, Structural, dielectric, and magnetic studies based on MWCNTs/NiFe₂O₄/ZnO nanoparticles dispersed in polymer PVA/PEO for electromagnetic applications. J. Mater. Sci. Mater. Electron. 32, 2906–2924 (2021)CrossRef

48.

M.M. Abutalib, A. Rajeh, Enhanced structural, electrical, mechanical properties and antibacterial activity of Cs/PEO doped mixed nanoparticles (Ag/TiO₂) for food packaging applications. Polym. Testing 93, 107013 (2020)CrossRef

49.

K.N. Kumar, M. Kang, K. Sivaiah, M. Ravi, Y.C. Ratnakaram, Enhanced electrical properties of polyethylene oxide (PEO) + polyvinylpyrrolidone (PVP): Li+ blended polymer electrolyte films with addition of Ag nanofiller. Ionics 22, 815–825 (2016). https://doi.org/10.1007/s11581-015-1599-4CrossRef

50.

O. Pravakar, T. Siddaiah, P.V.R.K. Ramacharyulu, N.O. Gopal, C. Ramu, H. Nagabhushana, Spectroscopic, thermal, structural and electrical studies on VO2+ ions doped PVA/MAA: EA polymer blend films. J. Sci. Adv. Mater. Dev. 4, 267–275 (2019). https://doi.org/10.1016/J.JSAMD.2019.03.004CrossRef

51.

G.M. Asnag, A.H. Oraby, A.M. Abdelghany, Green synthesis of gold nanoparticles and its effect on the optical, thermal and electrical properties of carboxymethyl cellulose. Compos. Part B Eng. 172, 436–446 (2019). https://doi.org/10.1016/J.COMPOSITESB.2019.05.044CrossRef

Title: Enhanced optical, morphological, dielectric, and conductivity properties of gold nanoparticles doped with PVA/CMC blend as an application in organoelectronic devices
Authors: M. R. Atta
Qana A. Alsulami
G. M. Asnag
A. Rajeh
Publication date: 26-03-2021
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 8/2021
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-021-05701-3

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