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Published in: Journal of Materials Science: Materials in Electronics 4/2018

24-11-2017

Facile preparation, characterization and highly effective microwave absorption performance of porous α-Fe2O3 nanorod–graphene composites

Authors: Lei Wang, Xiaoyu Bai, Min Wang

Published in: Journal of Materials Science: Materials in Electronics | Issue 4/2018

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Abstract

A facile process was developed for the synthesis of porous α-Fe2O3 nanorod–graphene (α-Fe2O3 nanorod–graphene) composites based on the reduction of graphene oxide sheets by Fe2+ in the presence cetyltrimethylammonium bromide (CTAB), followed by annealing in Ar atmosphere. When CTAB was added in the synthesis system, only porous α-Fe2O3 nanorods distributed uniformly on the surface of graphene (porous α-Fe2O3 nanorod–graphene). While both irregular and porous nanorod-shaped α-Fe2O3 nanoparticles coexisted on graphene surfaces (α-Fe2O3-graphene) and nanorod-shaped α-Fe2O3 tended to severely aggregate with each other without the addition of CTAB. In comparison with α-Fe2O3-graphene, porous α-Fe2O3 nanorod–graphene composites exhibit enhanced electromagnetic absorption in terms of both the maximum reflection loss value and the absorption bandwidth, which probably originates from the bigger electromagnetic attenuation constant induced by the better homogeneous morphology and uniform distribution of Fe2O3 on graphene surface.

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Literature
1.
go back to reference G.B. Sun, B.X. Dong, M.H. Cao, B.Q. Wei, C.W. Hu, Hierarchical dendrite-like magnetic materials of Fe3O4, γ-Fe2O3, and Fe with high performance of microwave absorption. Chem. Mater. 23(6), 1587–1593 (2011)CrossRef G.B. Sun, B.X. Dong, M.H. Cao, B.Q. Wei, C.W. Hu, Hierarchical dendrite-like magnetic materials of Fe3O4, γ-Fe2O3, and Fe with high performance of microwave absorption. Chem. Mater. 23(6), 1587–1593 (2011)CrossRef
2.
go back to reference L. Kong, C. Wang, X.W. Yin, X.M. Fan, W. Wang, J.F. Huang, Electromagnetic wave absorption properties of a carbon nanotube modified by a tetrapyridinoporphyrazine interface layer. J. Mater. Chem C 5, 7479–7488 (2017)CrossRef L. Kong, C. Wang, X.W. Yin, X.M. Fan, W. Wang, J.F. Huang, Electromagnetic wave absorption properties of a carbon nanotube modified by a tetrapyridinoporphyrazine interface layer. J. Mater. Chem C 5, 7479–7488 (2017)CrossRef
3.
go back to reference L. Kong, X.W. Yin, M.K. Han, X.Y. Yuan, Z.X. Hou, F. Ye, L.T. Zhang, L.F. Cheng, Z.W. Xu, J.F. Huang, Macroscopic bioinspired graphene sponge modified with in-situ grown carbon nanowires and its electromagnetic properties. Carbon 111, 94–102 (2017)CrossRef L. Kong, X.W. Yin, M.K. Han, X.Y. Yuan, Z.X. Hou, F. Ye, L.T. Zhang, L.F. Cheng, Z.W. Xu, J.F. Huang, Macroscopic bioinspired graphene sponge modified with in-situ grown carbon nanowires and its electromagnetic properties. Carbon 111, 94–102 (2017)CrossRef
4.
go back to reference P.B. Liu, Y. Huang, J. Yan, Y. Zhao, Magnetic graphene@PANI@porous TiO2 ternary composites for high-performance electromagnetic wave absorption. J. Mater. Chem. C 4, 6362–6370 (2016)CrossRef P.B. Liu, Y. Huang, J. Yan, Y. Zhao, Magnetic graphene@PANI@porous TiO2 ternary composites for high-performance electromagnetic wave absorption. J. Mater. Chem. C 4, 6362–6370 (2016)CrossRef
5.
go back to reference C. Wang, X.J. Han, P. Xu, X.L. Zhang, Y.C. Du, S.R. Hu, J.Y. Wang, X.H. Wang, The electromagnetic property of chemically reduced graphene oxide and its application as microwave absorbing material. Appl. Phys. Lett. 98, 072906 (2011)CrossRef C. Wang, X.J. Han, P. Xu, X.L. Zhang, Y.C. Du, S.R. Hu, J.Y. Wang, X.H. Wang, The electromagnetic property of chemically reduced graphene oxide and its application as microwave absorbing material. Appl. Phys. Lett. 98, 072906 (2011)CrossRef
6.
go back to reference F. Akbar, M. Kolahdouz, Sh Larimian, B. Radfar, H.H. Radamson, Graphene synthesis, characterization and its applications in nanophotonics, nanoelectronics, and nanosensing. J. Mater. Sci. 26(7), 4347–4379 (2015) F. Akbar, M. Kolahdouz, Sh Larimian, B. Radfar, H.H. Radamson, Graphene synthesis, characterization and its applications in nanophotonics, nanoelectronics, and nanosensing. J. Mater. Sci. 26(7), 4347–4379 (2015)
7.
go back to reference Y. Zhang, Y. Huang, T.F. Zhang, H.C. Chang, P.S. Xiao, H.H. Chen, Z.Y. Huan, Y.S. Chen, Broadband and tunable high-performance microwave absorption of an ultralight and highly compressible graphene foam. Adv. Mater 27(12), 2049–2053 (2015)CrossRef Y. Zhang, Y. Huang, T.F. Zhang, H.C. Chang, P.S. Xiao, H.H. Chen, Z.Y. Huan, Y.S. Chen, Broadband and tunable high-performance microwave absorption of an ultralight and highly compressible graphene foam. Adv. Mater 27(12), 2049–2053 (2015)CrossRef
8.
go back to reference H. Chuangang, M. Zhongyu, L. Gewu, C. Nan, D. Zelin, H. Minjia, Q. Liangti, 3D graphene–Fe3O4 nanocomposites with high-performance microwave absorption. Phys. Chem. Chem. Phys. 15(31), 13038–13043 (2013)CrossRef H. Chuangang, M. Zhongyu, L. Gewu, C. Nan, D. Zelin, H. Minjia, Q. Liangti, 3D graphene–Fe3O4 nanocomposites with high-performance microwave absorption. Phys. Chem. Chem. Phys. 15(31), 13038–13043 (2013)CrossRef
9.
go back to reference T.S. Wang, Z.H. Liu, M.M. Lu, B. Wen, Q.Y. Ouyang, Y.J. Chen, C.L. Zhu, P. Gao, C.Y. Li, M.S. Cao, L.H. Qi, Graphene–Fe3O4 nanohybrids: synthesis and excellent electromagnetic absorption properties. J. Appl. Phys. 113, 024314 (2013)CrossRef T.S. Wang, Z.H. Liu, M.M. Lu, B. Wen, Q.Y. Ouyang, Y.J. Chen, C.L. Zhu, P. Gao, C.Y. Li, M.S. Cao, L.H. Qi, Graphene–Fe3O4 nanohybrids: synthesis and excellent electromagnetic absorption properties. J. Appl. Phys. 113, 024314 (2013)CrossRef
10.
go back to reference W. Feng, Y.M. Wang, J.C. Chen, L. Wang, L.X. Guo, J.H. Ouyang, D.C. Jia, Y. Zhou, Reduced graphene oxide decorated with in-situ growing ZnO nanocrystals: facile synthesis and enhanced microwave absorption properties. Carbon 108, 52–60 (2016)CrossRef W. Feng, Y.M. Wang, J.C. Chen, L. Wang, L.X. Guo, J.H. Ouyang, D.C. Jia, Y. Zhou, Reduced graphene oxide decorated with in-situ growing ZnO nanocrystals: facile synthesis and enhanced microwave absorption properties. Carbon 108, 52–60 (2016)CrossRef
11.
go back to reference G.H. Pan, J. Zhu, S.L. Ma, G.B. Sun, X.J. Yang, Enhancing the electromagnetic performance of Co through the phase-controlled synthesis of hexagonal and cubic Co nanocrystals grown on graphene. ACS Appl. Mater. Interfaces 5(23), 12716–12724 (2013)CrossRef G.H. Pan, J. Zhu, S.L. Ma, G.B. Sun, X.J. Yang, Enhancing the electromagnetic performance of Co through the phase-controlled synthesis of hexagonal and cubic Co nanocrystals grown on graphene. ACS Appl. Mater. Interfaces 5(23), 12716–12724 (2013)CrossRef
12.
go back to reference C.X. Nan, M.F. Chen, Z.Z. Wan, T. Xin, S.L. Ming, Z.S. Bu, X.X. Ling, J. Man, W. Li, H. David, One-step synthesis of graphene/polyaniline hybrids by in situ intercalation polymerization and their electromagnetic properties. Nanoscale 6(14), 8140–8148 (2014)CrossRef C.X. Nan, M.F. Chen, Z.Z. Wan, T. Xin, S.L. Ming, Z.S. Bu, X.X. Ling, J. Man, W. Li, H. David, One-step synthesis of graphene/polyaniline hybrids by in situ intercalation polymerization and their electromagnetic properties. Nanoscale 6(14), 8140–8148 (2014)CrossRef
13.
go back to reference M. Oyharcbal, T. Olinga, M.P. Foul, S. Lacomme, E. Gontier, V. Vigneras, Influence of the morphology of polyaniline on the microwave absorption properties of epoxy polyaniline composites. Compos. Sci. Technol. 74, 107–112 (2013)CrossRef M. Oyharcbal, T. Olinga, M.P. Foul, S. Lacomme, E. Gontier, V. Vigneras, Influence of the morphology of polyaniline on the microwave absorption properties of epoxy polyaniline composites. Compos. Sci. Technol. 74, 107–112 (2013)CrossRef
14.
go back to reference Z. Wang, J.P. Zou, Z.H. Ding, J.F. Wu, P.H. Wang, S.W. Jin, H. Bi, Magnetic and microwave absorption properties of Ni microcrystals with hierarchical branch-like and flowers-like shapes. Mater. Chem. Phys. 142(1), 119–123 (2013)CrossRef Z. Wang, J.P. Zou, Z.H. Ding, J.F. Wu, P.H. Wang, S.W. Jin, H. Bi, Magnetic and microwave absorption properties of Ni microcrystals with hierarchical branch-like and flowers-like shapes. Mater. Chem. Phys. 142(1), 119–123 (2013)CrossRef
15.
go back to reference M. Zhou, X. Zhang, J.M. Wei, S.L. Zhao, L. Wang, B.X. Feng, Morphology-controlled synthesis and novel microwave absorption properties of hollow urchinlike α-MnO2 nanostructures. J. Phys. Chem. C 115(5), 1398–1402 (2011)CrossRef M. Zhou, X. Zhang, J.M. Wei, S.L. Zhao, L. Wang, B.X. Feng, Morphology-controlled synthesis and novel microwave absorption properties of hollow urchinlike α-MnO2 nanostructures. J. Phys. Chem. C 115(5), 1398–1402 (2011)CrossRef
16.
go back to reference Y. Lin, G. Yuan, S. Sheehan, S. Zhou, D. Wang, Hematite-based solar water splitting: challenges and opportunities. Energy Environ. Sci. 4, 4862–4869 (2011)CrossRef Y. Lin, G. Yuan, S. Sheehan, S. Zhou, D. Wang, Hematite-based solar water splitting: challenges and opportunities. Energy Environ. Sci. 4, 4862–4869 (2011)CrossRef
17.
go back to reference S.H. Yang, X.F. Song, P. Zhang, L. Gao, Heating-rate-induced porous α-Fe2O3 with controllable pore size and crystallinity grown on graphene for supercapacitors. ACS Appl. Mater. Interfaces 7(1), 75–79 (2015)CrossRef S.H. Yang, X.F. Song, P. Zhang, L. Gao, Heating-rate-induced porous α-Fe2O3 with controllable pore size and crystallinity grown on graphene for supercapacitors. ACS Appl. Mater. Interfaces 7(1), 75–79 (2015)CrossRef
18.
go back to reference L. Wang, Y. Huang, X. Sun, H.J. Huang, P.B. Liu, M. Zong, Y. Wang, Synthesis and microwave absorption enhancement of graphene@Fe3O4@SiO2@NiO nanosheet hierarchical structures. Nanoscale 6, 3157–3164 (2014)CrossRef L. Wang, Y. Huang, X. Sun, H.J. Huang, P.B. Liu, M. Zong, Y. Wang, Synthesis and microwave absorption enhancement of graphene@Fe3O4@SiO2@NiO nanosheet hierarchical structures. Nanoscale 6, 3157–3164 (2014)CrossRef
19.
go back to reference M.B. Sassin, A.N. Mansour, K.A. Pettigrew, D.R. Rolison, J.W. Long, Electroless deposition of conformal nanoscale iron oxide on carbon nanoarchitectures for electrochemical charge storage. ACS Nano 4(8), 4505–4514 (2010)CrossRef M.B. Sassin, A.N. Mansour, K.A. Pettigrew, D.R. Rolison, J.W. Long, Electroless deposition of conformal nanoscale iron oxide on carbon nanoarchitectures for electrochemical charge storage. ACS Nano 4(8), 4505–4514 (2010)CrossRef
20.
go back to reference S.H. Song, K.H. Park, B.H. Kim, Y.W. Choi, G.H. Jun, D.J. Lee, B.S. Kong, K.W. Paik, S. Jeon, Enhanced thermal conductivity of epoxy-graphene composites by using non-oxidized graphene flakes with non-covalent functionalization. Adv. Mater. 25(5), 732–737 (2013)CrossRef S.H. Song, K.H. Park, B.H. Kim, Y.W. Choi, G.H. Jun, D.J. Lee, B.S. Kong, K.W. Paik, S. Jeon, Enhanced thermal conductivity of epoxy-graphene composites by using non-oxidized graphene flakes with non-covalent functionalization. Adv. Mater. 25(5), 732–737 (2013)CrossRef
21.
go back to reference Y.Q. Zou, J. Kan, Y. Wang, Fe2O3-graphene rice-on-sheet nanocomposite for high and fast lithium ion storage. J. Phys. Chem. C 115(42), 20747–20753 (2011)CrossRef Y.Q. Zou, J. Kan, Y. Wang, Fe2O3-graphene rice-on-sheet nanocomposite for high and fast lithium ion storage. J. Phys. Chem. C 115(42), 20747–20753 (2011)CrossRef
22.
go back to reference Y. Yuan, W. Jiang, Y.J. Wang, P. Shen, F.S. Li, P.Y. Li, F.Q. Zhao, H.X. Gao, Hydrothermal preparation of Fe2O3/graphene nanocomposite and its enhanced catalytic activity on the thermal decomposition of ammonium perchlorate. Appl. Surf. Sci. 303(1), 354–359 (2014)CrossRef Y. Yuan, W. Jiang, Y.J. Wang, P. Shen, F.S. Li, P.Y. Li, F.Q. Zhao, H.X. Gao, Hydrothermal preparation of Fe2O3/graphene nanocomposite and its enhanced catalytic activity on the thermal decomposition of ammonium perchlorate. Appl. Surf. Sci. 303(1), 354–359 (2014)CrossRef
23.
go back to reference L.L. Tian, Q.C. Zhuang, J. Li, C. Wu, Y.L. Shi, S.G. Sun, The production of self-assembled Fe2O3–graphene hybrid materials by a hydrothermal process for improved Li-cycling. Electrochim. Acta 65, 153–158 (2012)CrossRef L.L. Tian, Q.C. Zhuang, J. Li, C. Wu, Y.L. Shi, S.G. Sun, The production of self-assembled Fe2O3–graphene hybrid materials by a hydrothermal process for improved Li-cycling. Electrochim. Acta 65, 153–158 (2012)CrossRef
24.
go back to reference P. Song, X.Y. Zhang, M.X. Sun, X.L. Cui, Y.H. Lin, Synthesis of graphene nanosheets via oxalic acid-induced chemical reduction of exfoliated graphite oxide. RSC Adv. 2, 1168–1173 (2012)CrossRef P. Song, X.Y. Zhang, M.X. Sun, X.L. Cui, Y.H. Lin, Synthesis of graphene nanosheets via oxalic acid-induced chemical reduction of exfoliated graphite oxide. RSC Adv. 2, 1168–1173 (2012)CrossRef
25.
go back to reference S. Stankovich, D.A. Dikin, R.D. Piner, K.A. Kohlhaas, A. Kleinhammes, Y.Y. Jia, Y. Wu, S.T. Nguyen, R.S. Ruoff, Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45(7), 1558–1565 (2007)CrossRef S. Stankovich, D.A. Dikin, R.D. Piner, K.A. Kohlhaas, A. Kleinhammes, Y.Y. Jia, Y. Wu, S.T. Nguyen, R.S. Ruoff, Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45(7), 1558–1565 (2007)CrossRef
26.
go back to reference A.P. Singh, M. Mishra, P. Sambyal, B.K. Gupta, B.P. Singh, A. Chandra, S.K. Dhawan, Encapsulation of γ-Fe2O3 decorated reduced graphene oxide in polyaniline core–shell tubes as an exceptional tracker for electromagnetic environmental pollution. J. Mater. Chem. A 2, 3581–3593 (2014)CrossRef A.P. Singh, M. Mishra, P. Sambyal, B.K. Gupta, B.P. Singh, A. Chandra, S.K. Dhawan, Encapsulation of γ-Fe2O3 decorated reduced graphene oxide in polyaniline core–shell tubes as an exceptional tracker for electromagnetic environmental pollution. J. Mater. Chem. A 2, 3581–3593 (2014)CrossRef
27.
go back to reference J.J. Jiang, D. Li, D.Y. Geng, J. An, J. He, W. Liu, Z.D. Zhang, Microwave absorption properties of core double-shell FeCo/C/BaTiO3 nanocomposites. Nanoscale 6, 3967–3971 (2014)CrossRef J.J. Jiang, D. Li, D.Y. Geng, J. An, J. He, W. Liu, Z.D. Zhang, Microwave absorption properties of core double-shell FeCo/C/BaTiO3 nanocomposites. Nanoscale 6, 3967–3971 (2014)CrossRef
28.
go back to reference J. Zhu, H. Gu, Z. Luo, N. Haldolaarachige, D.P. Young, S. Wei, Z. Guo, Carbon nanostructure-derived polyaniline metacomposites: electrical, dielectric, and giant magnetoresistive properties. Langmuir 28(27), 10246–10255 (2012)CrossRef J. Zhu, H. Gu, Z. Luo, N. Haldolaarachige, D.P. Young, S. Wei, Z. Guo, Carbon nanostructure-derived polyaniline metacomposites: electrical, dielectric, and giant magnetoresistive properties. Langmuir 28(27), 10246–10255 (2012)CrossRef
29.
go back to reference G. Zheng, X. Yin, S. Liu, X. Liu, J. Deng, Q. Li, Improved electromagnetic absorbing properties of Si3N4–SiC/SiO2 composite ceramics with multi-shell microstructure. J. Eur. Ceram. Soc 33(11), 2173–2180 (2013)CrossRef G. Zheng, X. Yin, S. Liu, X. Liu, J. Deng, Q. Li, Improved electromagnetic absorbing properties of Si3N4–SiC/SiO2 composite ceramics with multi-shell microstructure. J. Eur. Ceram. Soc 33(11), 2173–2180 (2013)CrossRef
30.
go back to reference B. Zhao, G. Shao, B.B. Fan, W.Y. Zhao, S.H. Zhang, K.K. Guan, R. Zhang, In situ synthesis of novel urchin-like ZnS/Ni3S2@Ni composite with a core–shell structure for efficient electromagnetic absorption. J. Mater. Chem. C 3, 10862–10869 (2015)CrossRef B. Zhao, G. Shao, B.B. Fan, W.Y. Zhao, S.H. Zhang, K.K. Guan, R. Zhang, In situ synthesis of novel urchin-like ZnS/Ni3S2@Ni composite with a core–shell structure for efficient electromagnetic absorption. J. Mater. Chem. C 3, 10862–10869 (2015)CrossRef
31.
go back to reference R.F. Zhuo, L. Qiao, H.T. Feng, J.T. Chen, D. Yan, Microwave absorption properties and the isotropic antenna mechanism of ZnO nanotrees. J. Appl. Phys. 104, 094101 (2008)CrossRef R.F. Zhuo, L. Qiao, H.T. Feng, J.T. Chen, D. Yan, Microwave absorption properties and the isotropic antenna mechanism of ZnO nanotrees. J. Appl. Phys. 104, 094101 (2008)CrossRef
Metadata
Title
Facile preparation, characterization and highly effective microwave absorption performance of porous α-Fe2O3 nanorod–graphene composites
Authors
Lei Wang
Xiaoyu Bai
Min Wang
Publication date
24-11-2017
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 4/2018
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-8273-8

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