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Journal of Materials Science: Materials in Electronics

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08-08-2019

Facile preparation of porous erythrocyte-like CuCo₂O₄ as active material of lithium ion batteries anode

Authors: Hongmei Xu, Xiaolan Song, Ying Zhang, Zhenzhen Qin, Ting Ma, Hui Wang

Published in: Journal of Materials Science: Materials in Electronics | Issue 17/2019

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Abstract

The porous erythrocyte-like CuCo₂O₄ was first prepared in this work by a convenient solvothermal post-calcination method used polyvinylpyrrolidone (PVP) as structure-directing agent and ethanol as solvent. When used as anode active materials of Li-ion batteries (LIBs), that 973 Ah/kg of reversible capacity and above 98% of coulombic efficiencies were made by the porous erythrocyte-like CuCo₂O₄ at 0.5 A/g of current density over 300 times. And cycling at 0.1 A/g of current density the starting specific discharge and charge capacities were 1428 and 1052 Ah/kg higher than theoretical capacity. Excellent cycling performance kept 96% of the reversible capacity retention. The superior rate performances were made at 0.1, 0.2, 0.5, 1, 2 and 0.1 A/g of current densities for 15 times. These exceptional electrochemical performances are all related to its particular compacted morphology and mesoporous spinel structure.

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L. Lu, F. Min, Z. Luo, S. Wang, F. Teng, G. Li, C. Feng, Synthesis and electrochemical properties of CuCo₂O₄ as anode material for lithium-ion battery. J. Nanosci. Nanotechnol. 17(7), 4763–4771 (2017). https://doi.org/10.1166/jnn.2017.13782 CrossRef

G. Gao, H.B. Wu, B. Dong, S. Ding, X.W. Lou, Growth of ultrathin ZnCo₂O₄ nanosheets on reduced graphene oxide with enhanced lithium storage properties. Adv Sci (Weinh) 2(1–2), 1400014 (2015). https://doi.org/10.1002/advs.201400014 CrossRef

G. Li, L. Xu, Y. Zhai, Y. Hou, Fabrication of hierarchical porous MnCo₂O₄ and CoMn₂O₄ microspheres composed of polyhedral nanoparticles as promising anodes for long-life LIBs. J. Mater. Chem. A 3(27), 14298–14306 (2015). https://doi.org/10.1039/c5ta03145a CrossRef

F. Fu, J. Li, Y. Yao, X. Qin, Y. Dou, H. Wang, J. Tsui, K.Y. Chan, M. Shao, Hierarchical NiCo₂O₄ micro- and nanostructures with tunable morphologies as anode materials for lithium- and sodium-ion batteries. ACS Appl. Mater. Interfaces. 9(19), 16194–16201 (2017). https://doi.org/10.1021/acsami.7b02175 CrossRef

G. Zhang, B.Y. Xia, C. Xiao, L. Yu, X. Wang, Y. Xie, X.W. Lou, General formation of complex tubular nanostructures of metal oxides for the oxygen reduction reaction and lithium-ion batteries. Angew. Chem. Int. Ed. Engl. 52(33), 8643–8647 (2013). https://doi.org/10.1002/anie.201304355 CrossRef

F. Niu, N. Wang, J. Yue, L. Chen, J. Yang, Y. Qian, Hierarchically porous CuCo₂O₄ microflowers: a superior anode material for Li-ion batteries and a stable cathode electrocatalyst for Li-O 2 batteries. Electrochim. Acta 208, 148–155 (2016). https://doi.org/10.1016/j.electacta.2016.05.026 CrossRef

M. Bhardwaj, A. Patrike, R. Naphade, S. Tonda, Y. Gawli, S. Ogale, Porous CuCo₂O₄ nanotubules for Li-ion battery anode. ChemistrySelect 2(10), 2922–2926 (2017). https://doi.org/10.1002/slct.201700183 CrossRef

S. Cai, G. Wang, M. Jiang, H. Wang, Template-free fabrication of porous CuCo₂O₄ hollow spheres and their application in lithium ion batteries. J. Solid State Electrochem. 21(4), 1129–1136 (2016). https://doi.org/10.1007/s10008-016-3414-1 CrossRef

Y. Sharma, N. Sharma, G.V.S. Rao, B.V.R. Chowdari, Lithium recycling behaviour of nano-phase-CuCo₂O₄ as anode for lithium-ion batteries. J. Power Sources 173(1), 495–501 (2007). https://doi.org/10.1016/j.jpowsour.2007.06.022 CrossRef

10.

M. Bhardwaj, A. Suryawanshi, R. Fernandes, S. Tonda, A. Banerjee, D. Kothari, S. Ogale, CuCo₂O₄ nanowall morphology as Li-ion battery anode: enhancing electrochemical performance through stoichiometry control. Mater. Res. Bull. 90, 303–310 (2017). https://doi.org/10.1016/j.materresbull.2016.12.014 CrossRef

11.

S. Liu, S. Zhang, Y. Xing, S. Wang, R. Lin, X. Wei, L. He, Facile synthesis of hierarchical mesoporous CuxCo_3−xO₄ nanosheets array on conductive substrates with high-rate performance for Li-ion batteries. Electrochim. Acta 150, 75–82 (2014). https://doi.org/10.1016/j.electacta.2014.10.131 CrossRef

12.

J. Ma, H. Wang, X. Yang, Y. Chai, R. Yuan, Porous carbon-coated CuCo₂O₄ concave polyhedrons derived from metal–organic frameworks as anodes for lithium-ion batteries. J. Mater. Chem. A 3(22), 12038–12043 (2015). https://doi.org/10.1039/c5ta00890e CrossRef

13.

W. Lei, L. Nie, S. Liu, Y. Zhuo, R. Yuan, Influence of annealing temperature on microstructure and lithium storage performance of self-templated CuxCo_3−xO₄ hollow microspheres. RSC Adv. 6(67), 62640–62646 (2016). https://doi.org/10.1039/c6ra10215h CrossRef

14.

A. Basu, M. Bhardwaj, Y. Gawli, C. Rode, S. Ogale, A robust highly flexible all-solid-state micro pseudocapacitor based on ternary oxide CuCo₂O₄ having ultrathin porous nanowall type morphology blended with CNT. ChemistrySelect 1(16), 5159–5164 (2016). https://doi.org/10.1002/slct.201601348 CrossRef

15.

P. Li, W. Sun, Q. Yu, P. Yang, J. Qiao, Z. Wang, D. Rooney, K. Sun, An effective three-dimensional ordered mesoporous CuCo₂O₄ as electrocatalyst for Li-O₂ batteries. Solid State Ionics 289, 17–22 (2016). https://doi.org/10.1016/j.ssi.2016.02.014 CrossRef

16.

Y. Jin, L. Wang, Q. Jiang, X. Du, C. Ji, X. He, Mesoporous MnCo₂O₄ microflower constructed by sheets for lithium ion batteries. Mater. Lett. 177, 85–88 (2016). https://doi.org/10.1016/j.matlet.2016.04.157 CrossRef

17.

L. Guo, Q. Ru, X. Song, S. Hu, Y. Mo, Mesoporous ZnCo₂O₄ microspheres as an anode material for high-performance secondary lithium ion batteries. RSC Adv. 5(25), 19241–19247 (2015). https://doi.org/10.1039/c4ra15553j CrossRef

18.

H.S. Jadhav, S.M. Pawar, A.H. Jadhav, G.M. Thorat, J.G. Seo, Hierarchical mesoporous 3D flower-like CuCo₂O₄/NF for high-performance electrochemical energy storage. Sci Rep 6, 31120 (2016). https://doi.org/10.1038/srep31120 CrossRef

19.

X. Liang, Q. Wang, Y. Ma, D. Zhang, A high performance asymmetric supercapacitor based on in situ prepared CuCo₂O₄ nanowires and PPy nanoparticles on a two-ply carbon nanotube yarn. Dalton Trans. 47(47), 17146–17152 (2018). https://doi.org/10.1039/c8dt03938k CrossRef

20.

M. Pang, S. Jiang, J. Zhao, S. Zhang, R. Liu, W. Qu, Q. Pan, B. Xing, L. Gu, H. Wang, Designed fabrication of three-dimensional δ-MnO₂-cladded CuCo₂O₄ composites as an outstanding supercapacitor electrode material. N. J. Chem. 42(23), 19153–19163 (2018). https://doi.org/10.1039/c8nj03774d CrossRef

21.

W. Kang, Y. Tang, W. Li, Z. Li, X. Yang, J. Xu, C.S. Lee, Porous CuCo₂O₄ nanocubes wrapped by reduced graphene oxide as high-performance lithium-ion battery anodes. Nanoscale 6(12), 6551–6556 (2014). https://doi.org/10.1039/c4nr00446a CrossRef

22.

C. Cheng, F. Chen, J. Wang, G. Lai, H. Yi, Synthesis of nano-CuCo₂O₄ with high electrochemical performance as anode material in lithium-ion batteries. J. Electron. Mater. 45(1), 553–556 (2015). https://doi.org/10.1007/s11664-015-4148-z CrossRef

23.

J. Cheng, X. Li, Z. Wang, H. Guo, W. Peng, Q. Hu, Cubic CuCo₂O₄ microspheres with FeO nanowires link as free-standing anode for high-performance lithium ion batteries. Ceram. Int. 42(2), 2871–2875 (2016). https://doi.org/10.1016/j.ceramint.2015.09.153 CrossRef

24.

Y. Zhang, H. Liu, M. Huang, J.M. Zhang, W. Zhang, F. Dong, Y.X. Zhang, Engineering ultrathin Co(OH)₂ nanosheets on dandelion-like CuCo₂O₄ microspheres for binder-free supercapacitors. ChemElectroChem 4(3), 721–727 (2017). https://doi.org/10.1002/celc.201600661 CrossRef

25.

Niu JL, Zeng CH, Peng HJ, Lin XM, Sathishkumar P, Cai YP (2017) Formation of N-doped carbon-coated ZnO/ZnCo₂O₄/CuCo₂O₄ derived from a polymetallic metal-organic framework: toward high-rate and long-cycle-life lithium storage. Small. https://doi.org/10.1002/smll.201702150

26.

D. Han, H. Hu, B. Liu, G. Song, H. Yan, J. Di, CuCo₂O₄ nanoparticles encapsulated by onion-like carbon layers: a promising solution for high-performance lithium ion battery. Ceram. Int. 42(10), 12460–12466 (2016). https://doi.org/10.1016/j.ceramint.2016.05.025 CrossRef

27.

A.F. Shaikh, R.S. Kalubarme, M.S. Tamboli, S.S. Patil, M.V. Kulkarni, D.R. Patil, S.W. Gosavi, C.-J. Park, B.B. Kale, Nanowires of Ni substituted MnCo₂O₄ as an anode material for high performance lithium-ion battery. ChemistrySelect 2(17), 4630–4637 (2017). https://doi.org/10.1002/slct.201700267 CrossRef

28.

Hu X, Zhang S, Li X, Sun X, Cai S, Ji H, Hou F, Zheng C, Hu W (2017) Large-scale and template-free synthesis of hierarchically porous MnCo₂O_4.5 as anode material for lithium-ion batteries with enhanced electrochemical performance. J. Mater. Sci. 52 (9):5268–5282. https://doi.org/10.1007/s10853-017-0767-5

29.

J. Li, J. Wang, X. Liang, Z. Zhang, H. Liu, Y. Qian, S. Xiong, Hollow MnCo₂O₄ submicrospheres with multilevel interiors: from mesoporous spheres to yolk-in-double-shell structures. ACS Appl. Mater. Interfaces. 6(1), 24–30 (2014). https://doi.org/10.1021/am404841t CrossRef

30.

P. Zeng, X. Wang, M. Ye, Q. Ma, J. Li, W. Wang, B. Geng, Z. Fang, Excellent lithium ion storage property of porous MnCo₂O₄ nanorods. RSC Adv. 6(27), 23074–23084 (2016). https://doi.org/10.1039/c5ra26176g CrossRef

31.

F. Jiang, Q. Su, H. Li, L. Yao, H. Deng, G. Du, Growth of ultrafine CuCo₂O₄ nanoparticle on graphene with enhanced lithium storage properties. Chem. Eng. J. 314, 301–310 (2017). https://doi.org/10.1016/j.cej.2016.11.064 CrossRef

32.

Y. Li, M. Liu, S. Hou, P. Wang, X. Pan, M. Xie, Y. Chen, L. Zhao, Direct growth of urchin-like CuCo₂O₄ on Ni foam for ultrahigh capacity and excellent rate ability of lithium ion batteries. Appl. Surf. Sci. 458, 517–522 (2018). https://doi.org/10.1016/j.apsusc.2018.07.071 CrossRef

33.

S.M. Pawar, B.S. Pawar, B. Hou, A.T.A. Ahmed, H.S. Chavan, Y. Jo, S. Cho, J. Kim, J. Seo, S. Cha, A.I. Inamdar, H. Kim, H. Im, Facile electrodeposition of high-density CuCo₂O₄ nanosheets as a high-performance Li-ion battery anode material. J. Ind. Eng. Chem. 69, 13–17 (2019). https://doi.org/10.1016/j.jiec.2018.09.042 CrossRef

34.

H. Zhang, Z. Tang, K. Zhang, L. Wang, H. Shi, G. Zhang, H. Duan, Pseudo-solid-solution CuCo₂O₄/C nanofibers as excellent anodes for lithium ion batteries. Electrochim. Acta 247, 692–700 (2017). https://doi.org/10.1016/j.electacta.2017.07.063 CrossRef

Title: Facile preparation of porous erythrocyte-like CuCo2O4 as active material of lithium ion batteries anode
Authors: Hongmei Xu
Xiaolan Song
Ying Zhang
Zhenzhen Qin
Ting Ma
Hui Wang
Publication date: 08-08-2019
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 17/2019
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-019-02001-9

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