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Published in: Metallurgical and Materials Transactions B 6/2014

01-12-2014

Formation and Thermodynamics of Mg-Al-Ti-O Complex Inclusions in Mg-Al-Ti-Deoxidized Steel

Authors: Ying Ren, Lifeng Zhang, Wen Yang, Haojian Duan

Published in: Metallurgical and Materials Transactions B | Issue 6/2014

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Abstract

The formation of Mg-Al-Ti-O complex inclusions in steel was investigated by laboratory experiments and thermodynamic calculation. The composition evolutions of Mg-Al-Ti-O inclusions in steel with different contents of [Al], [Mg], and [Ti] were discussed. Mg-Al-Ti-O complex inclusion with high TiO x content was liquid at 1873 K (1600 °C), indicating MgAl2O4 spinel inclusions can be modified to low melting temperature ones by combining TiO x component. The stability diagram of Al-Mg-Ti-O system inclusions in the molten steel at 1873 K (1600 °C) was calculated, considering many kinds of oxide inclusions such as MgO, Al2O3, TiO x , MgTi2O4, MgAl2O4, Al2TiO5, and liquid inclusion. The thermodynamic calculations are in good agreement with experimental results, which can predict the formation of Al-Mg-Ti-O complex inclusions in molten steel with a large concentration range of [Al], [Mg], and [Ti].

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Literature
1.
2.
go back to reference O. Goro, Y. Koji, T. Syuji, and S. Ken-ichi: ISIJ Int., 2000, vol. 40, no. 2, pp. 121-28.CrossRef O. Goro, Y. Koji, T. Syuji, and S. Ken-ichi: ISIJ Int., 2000, vol. 40, no. 2, pp. 121-28.CrossRef
3.
4.
go back to reference S.B. Lee, J.H. Choi, H.G. Lee, P.H. Rhee, and S.M. Jung: Metall. Mater. Trans. B, 2005, vol. 36, no. 3, pp. 414-16.CrossRef S.B. Lee, J.H. Choi, H.G. Lee, P.H. Rhee, and S.M. Jung: Metall. Mater. Trans. B, 2005, vol. 36, no. 3, pp. 414-16.CrossRef
5.
go back to reference H. Todoroki, K. Mizuno, M. Noda, and T. Tohge: Steelmaking Conference Proceedings, Iron and Steel Society, Baltimore, MD, 2001, pp. 331-41. H. Todoroki, K. Mizuno, M. Noda, and T. Tohge: Steelmaking Conference Proceedings, Iron and Steel Society, Baltimore, MD, 2001, pp. 331-41.
6.
go back to reference J.H. Park and D. Kim: Metall. Mater. Trans. B, 2005, vol. 36, no. 4, pp. 495-502.CrossRef J.H. Park and D. Kim: Metall. Mater. Trans. B, 2005, vol. 36, no. 4, pp. 495-502.CrossRef
7.
go back to reference J.H. Park: Mater. Sci. Eng. A, 2008, vol. 472(1–2), pp. 43-51. J.H. Park: Mater. Sci. Eng. A, 2008, vol. 472(1–2), pp. 43-51.
8.
go back to reference T. Nishi and K. Shinme: Tetsu-to-Hagané, 1998, vol. 84, no. 12, pp. 837-43. T. Nishi and K. Shinme: Tetsu-to-Hagané, 1998, vol. 84, no. 12, pp. 837-43.
9.
go back to reference S. Yang, Q. Wang, L. Zhang, J. Li, and K. Peaslee: Metall. Mater. Trans. B, 2012, vol. 43, no. 4, pp. 731-50.CrossRef S. Yang, Q. Wang, L. Zhang, J. Li, and K. Peaslee: Metall. Mater. Trans. B, 2012, vol. 43, no. 4, pp. 731-50.CrossRef
10.
go back to reference W. Yang, S. Li, Y. Li, X. Wang, L. Zhang, X. Liu, and Q. Shan: Materials Processing Fundamentals—TMS 2013 Annual Meeting and Exhibition, San Antonio, TX, TMS, Warrendale, PA, 2013, pp. 3–16. W. Yang, S. Li, Y. Li, X. Wang, L. Zhang, X. Liu, and Q. Shan: Materials Processing Fundamentals—TMS 2013 Annual Meeting and Exhibition, San Antonio, TX, TMS, Warrendale, PA, 2013, pp. 3–16.
11.
go back to reference Y. Wanibe and K. Sano: J. Jpn. Inst. Met., 1966, vol. 30(7), pp. 674–78. Y. Wanibe and K. Sano: J. Jpn. Inst. Met., 1966, vol. 30(7), pp. 674–78.
12.
go back to reference T.B. Braun, J.F. Elliott, and M.C. Flemings: Metall. Trans. B, 1979, vol. 10, pp. 171-84.CrossRef T.B. Braun, J.F. Elliott, and M.C. Flemings: Metall. Trans. B, 1979, vol. 10, pp. 171-84.CrossRef
13.
go back to reference A. Hayashi, T. Uenishi, H. Kandori, T. Miki, and M. Hino: ISIJ Int., 2008, vol. 48, no. 11, pp. 1533-41.CrossRef A. Hayashi, T. Uenishi, H. Kandori, T. Miki, and M. Hino: ISIJ Int., 2008, vol. 48, no. 11, pp. 1533-41.CrossRef
14.
go back to reference W. Yang, X. Wang, L. Zhang, Q. Shan, and X. Liu: Steel Res. Int., 2013, vol. 84, no. 5, pp. 473-89.CrossRef W. Yang, X. Wang, L. Zhang, Q. Shan, and X. Liu: Steel Res. Int., 2013, vol. 84, no. 5, pp. 473-89.CrossRef
15.
go back to reference W.Y. Cha, T. Miki, Y. Sasaki, and M. Hino: ISIJ Int., 2006, vol. 46, no. 7, pp. 987-95.CrossRef W.Y. Cha, T. Miki, Y. Sasaki, and M. Hino: ISIJ Int., 2006, vol. 46, no. 7, pp. 987-95.CrossRef
16.
go back to reference W.Y. Cha, T. Nagasaka, T. Miki, Y. Sasaki, and M. Hino: ISIJ Int., 2006, vol. 46, no. 7, pp. 996-1005.CrossRef W.Y. Cha, T. Nagasaka, T. Miki, Y. Sasaki, and M. Hino: ISIJ Int., 2006, vol. 46, no. 7, pp. 996-1005.CrossRef
17.
go back to reference J.J. Pak, J.O. Jo, S.I. Kim, W.Y. Kim, T.I. Chung, S.M. Seo, J.H. Park, and D.S. Kim: ISIJ Int., 2007, vol. 47, no. 1, pp. 16-24.CrossRef J.J. Pak, J.O. Jo, S.I. Kim, W.Y. Kim, T.I. Chung, S.M. Seo, J.H. Park, and D.S. Kim: ISIJ Int., 2007, vol. 47, no. 1, pp. 16-24.CrossRef
18.
go back to reference H. Itoh, M. Hino, and S. Ban-Ya: Metall. Mater. Trans. B, 1997, vol. 28, no. 5, pp. 953-56.CrossRef H. Itoh, M. Hino, and S. Ban-Ya: Metall. Mater. Trans. B, 1997, vol. 28, no. 5, pp. 953-56.CrossRef
19.
go back to reference K. Mizuno, H. Todoroki, M. Noda, and T. Tohge: Ironmaker Steelmaker 2001, vol. 28, no. 8, pp. 93-101. K. Mizuno, H. Todoroki, M. Noda, and T. Tohge: Ironmaker Steelmaker 2001, vol. 28, no. 8, pp. 93-101.
20.
go back to reference H. Todoroki and S. Inada: Bull. ISIJ, 2003, vol. 8, p. 575. H. Todoroki and S. Inada: Bull. ISIJ, 2003, vol. 8, p. 575.
21.
22.
go back to reference I.-H. Jung, G. Eriksson, P. Wu, and A. Pelton: ISIJ Int., 2009, vol. 49, no. 9, pp. 1290-97.CrossRef I.-H. Jung, G. Eriksson, P. Wu, and A. Pelton: ISIJ Int., 2009, vol. 49, no. 9, pp. 1290-97.CrossRef
23.
go back to reference N. Kikuchi, S. Nabeshima, Y. Kishimoto, T. Matsushita, and S. Sridhar: ISIJ Int., 2007, vol. 47, no. 9, pp. 1255-64.CrossRef N. Kikuchi, S. Nabeshima, Y. Kishimoto, T. Matsushita, and S. Sridhar: ISIJ Int., 2007, vol. 47, no. 9, pp. 1255-64.CrossRef
24.
go back to reference N. Kikuchi, S. Nabeshima, Y. Kishimoto, J. Nakano, and S. Sridhar: ISIJ Int., 2008, vol. 48, no. 7, pp. 954-62.CrossRef N. Kikuchi, S. Nabeshima, Y. Kishimoto, J. Nakano, and S. Sridhar: ISIJ Int., 2008, vol. 48, no. 7, pp. 954-62.CrossRef
25.
go back to reference N. Kikuchi, S. Nabeshima, Y. Kishimoto, and S. Sridhar: ISIJ Int., 2008, vol. 48, no. 7, pp. 934-43.CrossRef N. Kikuchi, S. Nabeshima, Y. Kishimoto, and S. Sridhar: ISIJ Int., 2008, vol. 48, no. 7, pp. 934-43.CrossRef
26.
go back to reference N. Kikuchi, S. Nabeshima, Y. Kishimoto, Y. Ishiguro, and S. Sridhar: ISIJ Int., 2009, vol. 49, no. 7, pp. 1036-45.CrossRef N. Kikuchi, S. Nabeshima, Y. Kishimoto, Y. Ishiguro, and S. Sridhar: ISIJ Int., 2009, vol. 49, no. 7, pp. 1036-45.CrossRef
27.
go back to reference N. Kikuchi, S. Nabeshima, T. Yamashita, Y. Kishimoto, S. Sridhar, and T. Nagasaka: ISIJ Int., 2011, vol. 51, no. 12, pp. 2019-28.CrossRef N. Kikuchi, S. Nabeshima, T. Yamashita, Y. Kishimoto, S. Sridhar, and T. Nagasaka: ISIJ Int., 2011, vol. 51, no. 12, pp. 2019-28.CrossRef
28.
go back to reference C. Wang, N.T. Nuhfer, and S. Ridhar: Metall. Mater. Trans. B, 2009, vol. 41B, pp. 1006–21. C. Wang, N.T. Nuhfer, and S. Ridhar: Metall. Mater. Trans. B, 2009, vol. 41B, pp. 1006–21.
29.
go back to reference C. Wang, N.T. Nuhfer, and S. Sridhar: Metall. Mater. Trans. B, 2009, vol. 40B, pp. 1022–34. C. Wang, N.T. Nuhfer, and S. Sridhar: Metall. Mater. Trans. B, 2009, vol. 40B, pp. 1022–34.
30.
go back to reference C. Wang, N.T. Nuhfer, and S. Ridhar: Metall. Mater. Trans. B, 2010, vol. 41B, pp. 1084–93. C. Wang, N.T. Nuhfer, and S. Ridhar: Metall. Mater. Trans. B, 2010, vol. 41B, pp. 1084–93.
31.
go back to reference C. Wang, N. Verma, Y. Kwon, W. Tiekink, N. Kikuchi, and S. Sridhar: ISIJ Int., 2011, vol. 51, no. 3, pp. 375-81.CrossRef C. Wang, N. Verma, Y. Kwon, W. Tiekink, N. Kikuchi, and S. Sridhar: ISIJ Int., 2011, vol. 51, no. 3, pp. 375-81.CrossRef
32.
go back to reference C. Yang, N. Lv, X. Wang, and W. Wang: J. Univ. Sci. Technol. Beijing, 2009, vol. 31(11), pp. 1390–93. C. Yang, N. Lv, X. Wang, and W. Wang: J. Univ. Sci. Technol. Beijing, 2009, vol. 31(11), pp. 1390–93.
33.
go back to reference Z. Hu, C. Yang, M. Jiang, G. Yang, W. Wang, and X. Wang: Jinshu Xuebao/Acta Metall. Sin., 2011, vol. 47(8), pp. 971–77. Z. Hu, C. Yang, M. Jiang, G. Yang, W. Wang, and X. Wang: Jinshu Xuebao/Acta Metall. Sin., 2011, vol. 47(8), pp. 971–77.
34.
go back to reference C. Yang, M. Jiang, X. Wang, and T. Ou: 2nd International Conference on Advanced Engineering Materials and Technology, AEMT 2012, vols. 535–537, Zhuhai, China, Trans Tech Publications, Dürnten, Switzerland, 2012, pp. 620–27. C. Yang, M. Jiang, X. Wang, and T. Ou: 2nd International Conference on Advanced Engineering Materials and Technology, AEMT 2012, vols. 535–537, Zhuhai, China, Trans Tech Publications, Dürnten, Switzerland, 2012, pp. 620–27.
35.
go back to reference Z. Hu, G. Yang, M. Jiang, W. Wang, and X. Wang: J. Univ. Sci. Technol. Beijing, 2012, vol. 34(40), pp. 1123–29. Z. Hu, G. Yang, M. Jiang, W. Wang, and X. Wang: J. Univ. Sci. Technol. Beijing, 2012, vol. 34(40), pp. 1123–29.
36.
go back to reference A.D. Pelton, G. Eriksson, G. Krajewski, M. Goebbels, and E. Woermann: Zeitchrift Phys. Chem., 1998, vol. 207, pp. 163-80.CrossRef A.D. Pelton, G. Eriksson, G. Krajewski, M. Goebbels, and E. Woermann: Zeitchrift Phys. Chem., 1998, vol. 207, pp. 163-80.CrossRef
37.
38.
go back to reference H. Fujimura, S. Tsuge, Y. Komizo, and T. Nishizawa: Tetsu-to-Hagané, 2001, vol. 87, no. 11, pp. 707-12. H. Fujimura, S. Tsuge, Y. Komizo, and T. Nishizawa: Tetsu-to-Hagané, 2001, vol. 87, no. 11, pp. 707-12.
39.
go back to reference S.C. Park, I.H. Jung, K.S. Oh, and H.G. Lee: ISIJ Int., 2004, vol. 44, no. 6, pp. 1016-23.CrossRef S.C. Park, I.H. Jung, K.S. Oh, and H.G. Lee: ISIJ Int., 2004, vol. 44, no. 6, pp. 1016-23.CrossRef
40.
go back to reference J.H. Park, S.B. Lee, and H.R. Gaye: Metall. Mater. Trans. B, 2008, vol. 39B, pp. 853–61. J.H. Park, S.B. Lee, and H.R. Gaye: Metall. Mater. Trans. B, 2008, vol. 39B, pp. 853–61.
41.
go back to reference H. Ono, K. Nakajima, R. Maruo, S. Agawa, and T. Usui: ISIJ Int., 2009, vol. 49, no. 7, pp. 957-64.CrossRef H. Ono, K. Nakajima, R. Maruo, S. Agawa, and T. Usui: ISIJ Int., 2009, vol. 49, no. 7, pp. 957-64.CrossRef
42.
go back to reference H. Ono, K. Nakajima, T. Ibuta, and T. Usui: ISIJ Int., 2010, vol. 50, no. 12, pp. 1955-58.CrossRef H. Ono, K. Nakajima, T. Ibuta, and T. Usui: ISIJ Int., 2010, vol. 50, no. 12, pp. 1955-58.CrossRef
43.
go back to reference Y. Song, G. Li, and F. Yang: J. Univ. Sci. Technol. Beijing, 2011, vol. 33(10), pp. 1214–19. Y. Song, G. Li, and F. Yang: J. Univ. Sci. Technol. Beijing, 2011, vol. 33(10), pp. 1214–19.
44.
45.
go back to reference M. Jiang, X. Wang, B. Chen, and W. Wang: ISIJ Int., 2008, vol. 48, no. 7, pp. 885-90.CrossRef M. Jiang, X. Wang, B. Chen, and W. Wang: ISIJ Int., 2008, vol. 48, no. 7, pp. 885-90.CrossRef
46.
go back to reference M. Jiang, X. Wang, B. Chen, and W. Wang: ISIJ Int., 2010, vol. 50, no. 1, pp. 95-104.CrossRef M. Jiang, X. Wang, B. Chen, and W. Wang: ISIJ Int., 2010, vol. 50, no. 1, pp. 95-104.CrossRef
47.
go back to reference Y.J. Kang, L. Fan, M. Kazuki, and S. Du: Steel Res. Int., 2006, vol. 77, no. 11, pp. 785-92. Y.J. Kang, L. Fan, M. Kazuki, and S. Du: Steel Res. Int., 2006, vol. 77, no. 11, pp. 785-92.
48.
go back to reference N. Verma, P.C. Pistorius, and R.J. Fruehan: Proc. AISTech 2011 Iron & Steel Technology Conference and Exposition, vol. 2, AISTech, Warrendale, PA, 2011, pp. 607–15. N. Verma, P.C. Pistorius, and R.J. Fruehan: Proc. AISTech 2011 Iron & Steel Technology Conference and Exposition, vol. 2, AISTech, Warrendale, PA, 2011, pp. 607–15.
49.
go back to reference E.B. Pretorius, H.G. Oltmann, and T. Cash: Proc. AISTech 2009 Iron & Steel Technology Conference and Exposition, vol. 1, AISTech, Warrendale, PA, 2009, pp. 1035–49. E.B. Pretorius, H.G. Oltmann, and T. Cash: Proc. AISTech 2009 Iron & Steel Technology Conference and Exposition, vol. 1, AISTech, Warrendale, PA, 2009, pp. 1035–49.
50.
go back to reference S.K. Michelic, M. Hartl, and C. Bernhard: Proc. AISTech 2011 Iron & Steel Technology Conference and Exposition, vol. 2, AISTech, Warrendale, PA, 2011, pp. 617–26. S.K. Michelic, M. Hartl, and C. Bernhard: Proc. AISTech 2011 Iron & Steel Technology Conference and Exposition, vol. 2, AISTech, Warrendale, PA, 2011, pp. 617–26.
51.
go back to reference N. Verma, P.C. Pistorius, R.J. Fruehan, M.S. Potter, H.G. Oltmann, and E.B. Pretorius: Calcium Modification of Spinel Inclusions in Aluminum-Killed Steel: Reaction Steps, vol. 43, Springer, Boston, MA, 2012, pp. 830-40. N. Verma, P.C. Pistorius, R.J. Fruehan, M.S. Potter, H.G. Oltmann, and E.B. Pretorius: Calcium Modification of Spinel Inclusions in Aluminum-Killed Steel: Reaction Steps, vol. 43, Springer, Boston, MA, 2012, pp. 830-40.
52.
go back to reference C.W. Seo, S.H. Kim, S.K. Jo, M.O. Suk, and S.M. Byun: Metall. Mater. Trans. B, 2010, vol. 41B, pp. 790–97. C.W. Seo, S.H. Kim, S.K. Jo, M.O. Suk, and S.M. Byun: Metall. Mater. Trans. B, 2010, vol. 41B, pp. 790–97.
53.
go back to reference S. Mizoguehi and J.C. Takamura: Proc. 6th International Iron and Steel Congress, Nagoya, ISIJ, 1990, pp. 591–97. S. Mizoguehi and J.C. Takamura: Proc. 6th International Iron and Steel Congress, Nagoya, ISIJ, 1990, pp. 591–97.
54.
go back to reference S. Mizoguehi and J.C. Takamura: Proc. 6th International Iron and Steel Congress, Nagoya, Japan, Iron and Steel Institute of Japan, Tokyo, Japan, 1990, pp. 598–604. S. Mizoguehi and J.C. Takamura: Proc. 6th International Iron and Steel Congress, Nagoya, Japan, Iron and Steel Institute of Japan, Tokyo, Japan, 1990, pp. 598–604.
56.
go back to reference I.-H. Jung, S.A. Decterov, and A.D. Pelton: ISIJ Int., 2004, vol. 44, no. 3, pp. 527-36.CrossRef I.-H. Jung, S.A. Decterov, and A.D. Pelton: ISIJ Int., 2004, vol. 44, no. 3, pp. 527-36.CrossRef
57.
go back to reference The Japan Society for the Promotion of Science: Steelmaking Data Sourcebook, Gordon and Breach Science, New York, NY, 1988. The Japan Society for the Promotion of Science: Steelmaking Data Sourcebook, Gordon and Breach Science, New York, NY, 1988.
58.
go back to reference Y. Guo and C. Wang: Metall. Trans. B, 1990, vol. 21, pp. 543-47. Y. Guo and C. Wang: Metall. Trans. B, 1990, vol. 21, pp. 543-47.
59.
go back to reference W.Y. Cha, T. Nagasaka, T. Miki, Y. Sasaki, and M. Hino: ISIJ Int., 2006, vol. 46, no. 7, pp. 996-1005.CrossRef W.Y. Cha, T. Nagasaka, T. Miki, Y. Sasaki, and M. Hino: ISIJ Int., 2006, vol. 46, no. 7, pp. 996-1005.CrossRef
60.
go back to reference N. Satoh, T. Taniguchi, S. Mishima, T. Oka, T. Miki, and M. Hino: Tetsu-to-Hagané, 2009, vol. 95, no. 12, pp. 827-36.CrossRef N. Satoh, T. Taniguchi, S. Mishima, T. Oka, T. Miki, and M. Hino: Tetsu-to-Hagané, 2009, vol. 95, no. 12, pp. 827-36.CrossRef
61.
go back to reference S.K. Jo, S.H. Kim, and Bo Song: Metall. Mater. Trans. B, 2002, vol. 33, no. 5, pp. 703-09.CrossRef S.K. Jo, S.H. Kim, and Bo Song: Metall. Mater. Trans. B, 2002, vol. 33, no. 5, pp. 703-09.CrossRef
Metadata
Title
Formation and Thermodynamics of Mg-Al-Ti-O Complex Inclusions in Mg-Al-Ti-Deoxidized Steel
Authors
Ying Ren
Lifeng Zhang
Wen Yang
Haojian Duan
Publication date
01-12-2014
Publisher
Springer US
Published in
Metallurgical and Materials Transactions B / Issue 6/2014
Print ISSN: 1073-5615
Electronic ISSN: 1543-1916
DOI
https://doi.org/10.1007/s11663-014-0121-0

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