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Journal of Materials Science
Published in: Journal of Materials Science 12/2017

16-03-2017 | Original Paper

Formation of submicrometer titanium nitride from a titanium dioxide/phenolic resin composite

Authors: Ke-Han Wu, Guo-Hua Zhang, Hai-Peng Gou, Kuo-Chih Chou

Published in: Journal of Materials Science | Issue 12/2017

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Abstract

A commercial route has been developed to synthesize submicrometer titanium nitride from titanium dioxide/phenolic resin composite. The phenolic resin served as the carbon source and the titanium dioxide served as titanium source to produce titanium nitride in flowing ultrahigh purity N2 atmosphere at 1373–1773 K. Titania was embedded in a continuous phenolic resin dispersant. X-ray diffraction and field emission scanning electron microscope were employed to characterize the phase composition, microstructure and reaction mechanism. It was found that the reaction sequence was TiO2 → Ti4O7 → Ti3O5 → TiN and the whole formation process was consisted of chemical synthesis reaction process firstly and the following recrystalline-physical process. The optimal conditions to prepare titanium nitride powders were determined: the molar ratio of titanium dioxide to phenolic resin is 1:0.5; thermostatic temperature is 1773 K, and thermostatic time is 2 h. The stepped structure on the surface of product formed due to recrystallization. The particle size of the obtained titanium nitride powders is about 0.5 μm.
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Metadata
Title
Formation of submicrometer titanium nitride from a titanium dioxide/phenolic resin composite
Authors
Ke-Han Wu
Guo-Hua Zhang
Hai-Peng Gou
Kuo-Chih Chou
Publication date
16-03-2017
Publisher
Springer US
Published in
Journal of Materials Science / Issue 12/2017
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-0987-8

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