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Published in: Polymer Bulletin 2/2011

01-01-2011 | Original paper

Heat resistant properties of PP/Al(OH)3/Mg(OH)2 flame retardant composites

Authors: J. Z. Liang, Y. J. Zhang, X. H. Jiang

Published in: Polymer Bulletin | Issue 2/2011

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Abstract

Vicat softening point temperature (T V) and heat deflection temperature (T d) are important parameters for characterization of heat resistant properties of polymeric materials. PP/Al(OH)3/Mg(OH)2 flame retardant composites were prepared using a twin-screw extruder, and the T V and T d of the composites were measured. The results showed that the T V and T d increased nonlinearly with an addition of the weight percentage of the flame retardant additives except for individual data points, while the T V and T d decreased with increasing the filler particle size when the content of flame retardant additives was constant. Under the same conditions, filling small amount of zinc borate into the composites might improve the heat resistant properties of the composite systems. Moreover, the morphology of the impact fracture surface of the specimens was observed by means of scanning electron microscope to understand the dispersion and distribution of the filler particles in the PP matrix.

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Literature
1.
go back to reference Bobovitch A, Gutman E, Schenker M, Utevski L, Muskatel M (1995) New approach to flame retardants: thermal polymerization on fillers. Mater Lett 23(4–6):317–320CrossRef Bobovitch A, Gutman E, Schenker M, Utevski L, Muskatel M (1995) New approach to flame retardants: thermal polymerization on fillers. Mater Lett 23(4–6):317–320CrossRef
2.
go back to reference Chiu SH, Wang WK (1998) Dynamic flame redundancy of polypropylene filled with ammonium polyphosphate, pentaerythritol and melamine additives. Polymer 39(10):1951–1955CrossRef Chiu SH, Wang WK (1998) Dynamic flame redundancy of polypropylene filled with ammonium polyphosphate, pentaerythritol and melamine additives. Polymer 39(10):1951–1955CrossRef
3.
go back to reference Chen YH, Liu Y, Wang Q, Yin HA, Aelmans N, Kierkels R (2003) Performance of intumescent flame retardant master batch synthesized through twin-screw reactively extruding technology: effect of component ratio. Polym Degrad Stab 81(2):215–224CrossRef Chen YH, Liu Y, Wang Q, Yin HA, Aelmans N, Kierkels R (2003) Performance of intumescent flame retardant master batch synthesized through twin-screw reactively extruding technology: effect of component ratio. Polym Degrad Stab 81(2):215–224CrossRef
4.
go back to reference Levchik SV, Weil ED (2005) Flame retardancy of thermoplastic polyesters: a review of the recent literature. Polym Int 54(1):11–35CrossRef Levchik SV, Weil ED (2005) Flame retardancy of thermoplastic polyesters: a review of the recent literature. Polym Int 54(1):11–35CrossRef
5.
go back to reference Carpentier F, Bourbigot S, Le Bras M, Delobel R, Foulon M (2000) Charring of fire retarded ethylene vinyl acetate copolymer magnesium hydroxide/zinc borate formulations. Polym Degrad Stab 69:83–92CrossRef Carpentier F, Bourbigot S, Le Bras M, Delobel R, Foulon M (2000) Charring of fire retarded ethylene vinyl acetate copolymer magnesium hydroxide/zinc borate formulations. Polym Degrad Stab 69:83–92CrossRef
6.
go back to reference Titelman GI, Gonen Y (2002) Discolouration of polypropylene-based compounds containing magnesium hydroxide. Polym Degrad Stab 77:345–352CrossRef Titelman GI, Gonen Y (2002) Discolouration of polypropylene-based compounds containing magnesium hydroxide. Polym Degrad Stab 77:345–352CrossRef
7.
go back to reference Sangcheol K (2003) Flame retardancy and smoke suppression of magnesium hydroxide filled polyethylene. J Polym Sci 41(9):936–944 Sangcheol K (2003) Flame retardancy and smoke suppression of magnesium hydroxide filled polyethylene. J Polym Sci 41(9):936–944
8.
go back to reference Ahmad Ramazani SA, Rahimi A, Frounchi M, Radman S (2008) Investigation of flame retardancy and physical–mechanical properties of zinc borate and aluminum hydroxide propylene composites. Mater Des 29(5):1051–1056CrossRef Ahmad Ramazani SA, Rahimi A, Frounchi M, Radman S (2008) Investigation of flame retardancy and physical–mechanical properties of zinc borate and aluminum hydroxide propylene composites. Mater Des 29(5):1051–1056CrossRef
9.
go back to reference Jiao CM, Chen XL (2009) Flame retardant synergism of hydroxy silicone oil and Al(OH)3 in EVA composites. Polym Plast Technol Eng 48(6):665–670CrossRef Jiao CM, Chen XL (2009) Flame retardant synergism of hydroxy silicone oil and Al(OH)3 in EVA composites. Polym Plast Technol Eng 48(6):665–670CrossRef
10.
go back to reference Kobayashi Y, Tokoro Y, Watatani K (1998) Preparation of functionalized zinc borates and their coupling reaction with allylic acetates. Tetrahedron Lett 39:7537–7540CrossRef Kobayashi Y, Tokoro Y, Watatani K (1998) Preparation of functionalized zinc borates and their coupling reaction with allylic acetates. Tetrahedron Lett 39:7537–7540CrossRef
11.
go back to reference Bourbigot S, Le Bras M, Leeuwendal R, Shen KK, Schubert D (1999) Recent advances in the use of zinc borates in flame retardancy of EVA. Polym Degrad Stab 64(3):419–425CrossRef Bourbigot S, Le Bras M, Leeuwendal R, Shen KK, Schubert D (1999) Recent advances in the use of zinc borates in flame retardancy of EVA. Polym Degrad Stab 64(3):419–425CrossRef
12.
go back to reference Garba B (1999) Effect of zinc borate as flame retardant formulation on some tropical woods. Polym Degrad Stab 64:517–522CrossRef Garba B (1999) Effect of zinc borate as flame retardant formulation on some tropical woods. Polym Degrad Stab 64:517–522CrossRef
13.
go back to reference Giudice CA, Benitez JC (2001) Zinc borates as flame-retardant pigments in chlorine-containing coatings. Prog Org Coat 42:82–88CrossRef Giudice CA, Benitez JC (2001) Zinc borates as flame-retardant pigments in chlorine-containing coatings. Prog Org Coat 42:82–88CrossRef
14.
go back to reference Liang JZ (2002) Toughening and reinforcing in rigid inorganic particle filled polypropylene: a review. J Appl Polym Sci 83:1547–1555CrossRef Liang JZ (2002) Toughening and reinforcing in rigid inorganic particle filled polypropylene: a review. J Appl Polym Sci 83:1547–1555CrossRef
15.
go back to reference Tasdemir M, Biltekin H, Caneba GT (2009) Preparation and characterization of LDPE and PP-wood fiber composites. J Appl Polym Sci 112(5):3095–3102CrossRef Tasdemir M, Biltekin H, Caneba GT (2009) Preparation and characterization of LDPE and PP-wood fiber composites. J Appl Polym Sci 112(5):3095–3102CrossRef
16.
go back to reference Dubnikova IL, Nizhegorodtseva EI, Lomakin SM, Krasheninnikov VG, Gorenberg AY, Kuleznev VN (2008) Preparation and characteristics of composites based on polypropylene and ultradispersed calcium carbonate. Polym Sci Ser A 50(12):1214–1225CrossRef Dubnikova IL, Nizhegorodtseva EI, Lomakin SM, Krasheninnikov VG, Gorenberg AY, Kuleznev VN (2008) Preparation and characteristics of composites based on polypropylene and ultradispersed calcium carbonate. Polym Sci Ser A 50(12):1214–1225CrossRef
17.
go back to reference Peng HQ, Wang DY, Zhou Q, Wang YZ (2008) An S- and P-containing flame retardant for polypropylene. Chin J Polym Sci 26(3):299–309CrossRef Peng HQ, Wang DY, Zhou Q, Wang YZ (2008) An S- and P-containing flame retardant for polypropylene. Chin J Polym Sci 26(3):299–309CrossRef
18.
go back to reference Liang JZ, Zhang YJ (2010) A study on flame retardant properties of PP/Al(OH)3/Mg(OH)2 composites. Polym Int 59:539–542CrossRef Liang JZ, Zhang YJ (2010) A study on flame retardant properties of PP/Al(OH)3/Mg(OH)2 composites. Polym Int 59:539–542CrossRef
Metadata
Title
Heat resistant properties of PP/Al(OH)3/Mg(OH)2 flame retardant composites
Authors
J. Z. Liang
Y. J. Zhang
X. H. Jiang
Publication date
01-01-2011
Publisher
Springer-Verlag
Published in
Polymer Bulletin / Issue 2/2011
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-010-0331-9

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