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Polymer Bulletin
Published in: Polymer Bulletin 2/2011

01-01-2011 | Original Paper

Methacrylate-based ionic liquid: radical polymerization/copolymerization with methyl methacrylate and evaluation of molecular weight of the obtained homopolymers

Authors: Kozo Matsumoto, Bandana Talukdar, Takeshi Endo

Published in: Polymer Bulletin | Issue 2/2011

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Abstract

Azobisisobutyronitlite (AIBN)-induced free radical polymerization of a methacrylate-based ionic liquid monomer, 1-(2-methacryloxyethyl)-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (Met-IL) was carried out in a common organic solvent, N,N-dimethylformamide (DMF), and an ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (EMImTFSI). The molecular weight of the obtained poly(Met-IL) was evaluated by transforming it to non-ionic poly(methyl methacrylate) with hydrolysis of the imidazolium-salt-substituted pendant ester groups and methyl esterification. Radical copolymerization with methyl methacrylate (MMA) was also carried out in both DMF and EMImTFSI. Analysis of copolymer composition revealed that the reactivity of Met-IL was lower than that of MMA in both DMF and EMImTFSI solutions.
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Metadata
Title
Methacrylate-based ionic liquid: radical polymerization/copolymerization with methyl methacrylate and evaluation of molecular weight of the obtained homopolymers
Authors
Kozo Matsumoto
Bandana Talukdar
Takeshi Endo
Publication date
01-01-2011
Publisher
Springer-Verlag
Published in
Polymer Bulletin / Issue 2/2011
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-010-0275-0

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