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Polymer Bulletin
Published in: Polymer Bulletin 2/2011

01-01-2011 | Original Paper

Synthesis of amphiphilic diblock copolymers by direct radical polymerization of acrylic acid via DPE method

Authors: Dong Lan, Dong Chen, Zhifeng Fu, Yan Shi

Published in: Polymer Bulletin | Issue 2/2011

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Abstract

Amphiphilic diblock copolymers, poly(methyl methacrylate)-b-poly(acrylic acid) (PMMA-b-PAA) was prepared by 1,1-diphenylethene (DPE) method. First, free radical polymerization of methyl methacrylate was carried out with AIBN as initiator in the presence of DPE, giving a DPE-containing PMMA precursor with controlled molecular weight. Amphiphilic diblock copolymer PMMA-b-PAA was then prepared by radical polymerization of acrylic acid (AA) in the presence of PMMA precursor. The formation of PMMA-b-PAA was confirmed by 1H NMR spectrum and gel permeation chromatography. Transmission electron microscopy and dynamic light scattering were used to detect the self-assembly behavior of the amphiphilic diblock polymers in methanol.
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Metadata
Title
Synthesis of amphiphilic diblock copolymers by direct radical polymerization of acrylic acid via DPE method
Authors
Dong Lan
Dong Chen
Zhifeng Fu
Yan Shi
Publication date
01-01-2011
Publisher
Springer-Verlag
Published in
Polymer Bulletin / Issue 2/2011
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-010-0263-4

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