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Polymer Bulletin
Published in: Polymer Bulletin 4/2021

01-04-2020 | Original Paper

High permittivity ceramics-filled acrylonitrile butadiene rubber composites: influence of acrylonitrile content and ceramic type

Authors: Piyawadee Luangchuang, Narong Chueangchayaphan, Muhammad Azwadi Sulaiman, Wannarat Chueangchayaphan

Published in: Polymer Bulletin | Issue 4/2021

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Abstract

Influence of acrylonitrile content and ceramic type on cure characteristics, mechanical, morphological, and dielectric properties of acrylonitrile butadiene rubber (NBR) vulcanizates was examined. Two types of ceramic filler, namely barium titanate (BT) and calcium copper titanate (CCTO), were synthesized by solid-state reactions. The ceramic powders were then characterized by X-ray diffraction, particle size analyzer, and scanning electron microscopy (SEM). Ceramic/rubber composites were then mixed in an internal mixer at 60 °C and a rotor speed of 60 rpm. Two acrylonitrile contents of NBR, namely 33 wt% and 42 wt%, were tested. Incorporation of ceramic fillers in NBR matrix and increasing acrylonitrile content shortened scorch and cure times, but increased minimum, maximum, and delta torque. Furthermore, SEM results revealed that the BT-filled NBR composites showed better filler–matrix interactions than the CCTO-filled NBR composites. This matches the better mechanical and dielectric properties of the BT-filled NBR composites.
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Metadata
Title
High permittivity ceramics-filled acrylonitrile butadiene rubber composites: influence of acrylonitrile content and ceramic type
Authors
Piyawadee Luangchuang
Narong Chueangchayaphan
Muhammad Azwadi Sulaiman
Wannarat Chueangchayaphan
Publication date
01-04-2020
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 4/2021
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-020-03181-9

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