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Journal of Coatings Technology and Research

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19-05-2017

Hollow mesoporous silica nanoparticles loaded with phosphomolybdate as smart anticorrosive pigment

Authors: C. Zea, R. Barranco-García, J. Alcántara, B. Chico, M. Morcillo, D. de la Fuente

Published in: Journal of Coatings Technology and Research | Issue 4/2017

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Abstract

Recent developments in surface science and technology open up new opportunities for the development of smart pigments through the integration of nanoscale containers loaded with active components into coatings. Regarding the external factor to trigger the inhibitor release, a change in pH is a very interesting stimulus since corrosion activity leads to local changes in pH. Although several types of nanocontainers and encapsulation approaches have been proposed and studied to meet this goal, mesoporous silica nanoparticles (MSNs) are especially interesting as they retain their solid properties as long as pH of the surrounding medium does not exceed ~11. On the other hand, the use of hollow mesoporous silica nanoparticles (HMSNs) with a large cavity inside each original mesoporous silica nanoparticle has recently gained increasing interest due to the higher loading capacity. In the present work, an environmentally friendly corrosion inhibitor with good anticorrosive behavior when applied on steel substrates, sodium phosphomolybdate, has been successfully loaded and encapsulated on HMSNs. The pH-dependent release of the corrosion inhibitor from the loaded/encapsulated HMSNs has been confirmed. In addition, an improved anticorrosive behavior of the coatings formulated with loaded/encapsulated HMSNs has been observed by Scanning Kelvin Probe (SKP).

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Title: Hollow mesoporous silica nanoparticles loaded with phosphomolybdate as smart anticorrosive pigment
Authors: C. Zea
R. Barranco-García
J. Alcántara
B. Chico
M. Morcillo
D. de la Fuente
Publication date: 19-05-2017
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 4/2017
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-017-9924-7

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