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Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 3/2022

05-05-2022 | Invited Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Hydrothermal synthesis of perovskite-type solid electrolyte nanoplate

Authors: Ken-ichi Mimura, Naoki Hamao, Hiroki Itasaka, Zheng Liu, Koichi Hamamoto

Published in: Journal of Sol-Gel Science and Technology | Issue 3/2022

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Abstract

Perovskite-type (A,La)TiO3 (A: Li or Na) nanoplates were synthesized by hydrothermal reaction using titanium bis(ammonium lactate) dihydroxide as a starting material at 260 °C for 48 h. When NaOH was used as a mineralizer, perovskite single phase was obtained, but when LiOH was used, impurities including lanthanum hydroxide were obtained, and no perovskite phase was obtained. Scanning transmission electron microscopy (STEM) analyses demonstrated that perovskite NPs have plate-like morphology with plane index of {100}. Energy dispersive X-ray spectroscopy (EDX) revealed that Na partly occupied in A-site of perovskite structure. The nanoplates were pressed into a pellet and sintered at 1000 °C. The pellet exhibited an ionic conductivity of 3.8 × 10−6 S/cm.
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Metadata
Title
Hydrothermal synthesis of perovskite-type solid electrolyte nanoplate
Authors
Ken-ichi Mimura
Naoki Hamao
Hiroki Itasaka
Zheng Liu
Koichi Hamamoto
Publication date
05-05-2022
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 3/2022
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-022-05810-3

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