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Published in: Cellulose 4/2017

09-02-2017 | Original Paper

Hydroxyethyl cellulose/bentonite/magnetite hybrid materials: structure, physicochemical properties, and antifungal activity

Authors: Olga V. Alekseeva, Anna N. Rodionova, Nadezhda A. Bagrovskaya, Alexandr V. Agafonov, Andrew V. Noskov

Published in: Cellulose | Issue 4/2017

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Abstract

Bentonite/magnetite powder was synthesized and characterized using laser diffraction, scanning electron microscopy, X-ray diffraction, low-temperature nitrogen adsorption–desorption technique, and magnetization measurements, revealing it to be a ferromagnetic material with mesopores. Hydroxyethyl cellulose was filled with bentonite/magnetite particles by mechanical dispersion to produce hybrid film materials that were studied using various methods. X-ray diffraction analysis showed that the interlayer distance in the clay was increased due to intercalation of polymer molecules. A concentration effect of the filling agent on the tensile properties of the hybrid material was revealed. Infrared (IR) spectrometry indicated an increase in the density of the hydrogen-bonding network. Microbiological tests showed that the HEC/bentonite/magnetite films exhibited antifungal effect against Candida albicans.

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Literature
go back to reference Alekseeva OV, Bagrovskaya NA, Noskov AV (2015a) Sorption of heavy metal ions by cellulose modified with fullerene. Russ J Appl Chem 88:436–441CrossRef Alekseeva OV, Bagrovskaya NA, Noskov AV (2015a) Sorption of heavy metal ions by cellulose modified with fullerene. Russ J Appl Chem 88:436–441CrossRef
go back to reference Awwad AM, Salem ND (2012) A green and facile approach for synthesis of magnetite nanoparticles. Nanosci Nanotechnol 2:208–213CrossRef Awwad AM, Salem ND (2012) A green and facile approach for synthesis of magnetite nanoparticles. Nanosci Nanotechnol 2:208–213CrossRef
go back to reference Barud HS, de Araújo Júnior AM, Santos DB, de Assunção RMN et al (2008) Thermal behavior of cellulose acetate produced from homogeneous acetylation of bacterial cellulose. Thermochim Acta 471:61–69CrossRef Barud HS, de Araújo Júnior AM, Santos DB, de Assunção RMN et al (2008) Thermal behavior of cellulose acetate produced from homogeneous acetylation of bacterial cellulose. Thermochim Acta 471:61–69CrossRef
go back to reference Bera O, Pilic B, Pavlicevic J et al (2011) Preparation and thermal properties of polystyrene/silica nanocomposites. Thermochim Acta 515:1–5CrossRef Bera O, Pilic B, Pavlicevic J et al (2011) Preparation and thermal properties of polystyrene/silica nanocomposites. Thermochim Acta 515:1–5CrossRef
go back to reference Biliuta G, Coseri S (2016) Magnetic cellulosic materials based on TEMPO-oxidized viscose fibers. Cellulose 23:3407–3415CrossRef Biliuta G, Coseri S (2016) Magnetic cellulosic materials based on TEMPO-oxidized viscose fibers. Cellulose 23:3407–3415CrossRef
go back to reference Blackwell J, Marchessault RH (1971) Infrared spectroscopy. Structure studies. In: Bikales NM, Segal L (eds) Cellulose and cellulose derivatives. Part IV. Wiley, New York, pp 1–38 Blackwell J, Marchessault RH (1971) Infrared spectroscopy. Structure studies. In: Bikales NM, Segal L (eds) Cellulose and cellulose derivatives. Part IV. Wiley, New York, pp 1–38
go back to reference Bochek AM, Zabivalova NM, Yudin VE et al (2011) Properties of carboxymethyl cellulose aqueous solutions with nanoparticle additives and the related composite films. Polym Sci Ser A 53:1167–1174CrossRef Bochek AM, Zabivalova NM, Yudin VE et al (2011) Properties of carboxymethyl cellulose aqueous solutions with nanoparticle additives and the related composite films. Polym Sci Ser A 53:1167–1174CrossRef
go back to reference Bochek AM, Shevchuk IL, Gavrilova II et al (2012) Properties of aqueous solutions of hydroxyethyl cellulose–poly(N-vinylformamide) blends and of the related composite films. Polym Sci Ser A 54:730–737CrossRef Bochek AM, Shevchuk IL, Gavrilova II et al (2012) Properties of aqueous solutions of hydroxyethyl cellulose–poly(N-vinylformamide) blends and of the related composite films. Polym Sci Ser A 54:730–737CrossRef
go back to reference Bruna JE, Galotto MJ, Guarda A et al (2014) A novel polymer based on MtCu2+/cellulose acetate with antimicrobial activity. Carbohydr Polym 102:317–323CrossRef Bruna JE, Galotto MJ, Guarda A et al (2014) A novel polymer based on MtCu2+/cellulose acetate with antimicrobial activity. Carbohydr Polym 102:317–323CrossRef
go back to reference Burnside SD, Giannelis EP (2000) Nanostructure and properties of polysiloxane-layered silicate nanocomposites. J Polym Sci Pol Phys 38:1595–1604CrossRef Burnside SD, Giannelis EP (2000) Nanostructure and properties of polysiloxane-layered silicate nanocomposites. J Polym Sci Pol Phys 38:1595–1604CrossRef
go back to reference Chen K, Wilkie CA, Vyazovkin S (2007) Nanoconfinement revealed in degradation and relaxation studies of two structurally different polystyrene–clay systems. J Phys Chem B 111:12685–12692CrossRef Chen K, Wilkie CA, Vyazovkin S (2007) Nanoconfinement revealed in degradation and relaxation studies of two structurally different polystyrene–clay systems. J Phys Chem B 111:12685–12692CrossRef
go back to reference Chen W, Xiao H, Xu H et al (2015) Photodegradation of methylene blue by TiO2–Fe3O4–bentonite magnetic nanocomposite. Int J Photoenergy. doi:10.1155/2015/591428 Chen W, Xiao H, Xu H et al (2015) Photodegradation of methylene blue by TiO2–Fe3O4–bentonite magnetic nanocomposite. Int J Photoenergy. doi:10.​1155/​2015/​591428
go back to reference Cho D-W, Jeon B-H, Chon C-M et al (2012) A novel chitosan/clay/magnetite composite for adsorption of Cu(II) and As(V). Chem Eng J 200–202:654–662CrossRef Cho D-W, Jeon B-H, Chon C-M et al (2012) A novel chitosan/clay/magnetite composite for adsorption of Cu(II) and As(V). Chem Eng J 200–202:654–662CrossRef
go back to reference Danilevicius A, Dobiliene J, Wutz C, Liesiene J (2007) Phenoxyhydroxypropylhydroxyethylcellulose—new amphiphilic cellulose derivative. Cellulose 14:321–329CrossRef Danilevicius A, Dobiliene J, Wutz C, Liesiene J (2007) Phenoxyhydroxypropylhydroxyethylcellulose—new amphiphilic cellulose derivative. Cellulose 14:321–329CrossRef
go back to reference Davaran S, Alimirzalu S, Nejati-Koshki K et al (2014) Physicochemical characteristics of Fe3O4 magnetic nanocomposites based on poly(N-isopropylacrylamide) for anti-cancer drug delivery. Asian Pac J Cancer Prev 15:49–54CrossRef Davaran S, Alimirzalu S, Nejati-Koshki K et al (2014) Physicochemical characteristics of Fe3O4 magnetic nanocomposites based on poly(N-isopropylacrylamide) for anti-cancer drug delivery. Asian Pac J Cancer Prev 15:49–54CrossRef
go back to reference Dennis HR, Hunter DL, Chang D et al (2001) Effect of melt processing conditions on the extent of exfoliation in organoclay-based nanocomposites. Polymer 42:9513–9522CrossRef Dennis HR, Hunter DL, Chang D et al (2001) Effect of melt processing conditions on the extent of exfoliation in organoclay-based nanocomposites. Polymer 42:9513–9522CrossRef
go back to reference Dittrich B, Wartig K-A, Hofmann D et al (2013) Flame retardancy through carbon nanomaterials: carbon black, multiwall nanotubes, expanded graphite, multi-layer graphene and graphene in polypropylene. Polym Degrad Stab 98:1495–1505CrossRef Dittrich B, Wartig K-A, Hofmann D et al (2013) Flame retardancy through carbon nanomaterials: carbon black, multiwall nanotubes, expanded graphite, multi-layer graphene and graphene in polypropylene. Polym Degrad Stab 98:1495–1505CrossRef
go back to reference Dodi G, Hritcu D, Lisa G, Popa MI (2012) Core-shell magnetic chitosan particles functionalized by grafting: synthesis and characterization. Chem Eng J 203:130–141CrossRef Dodi G, Hritcu D, Lisa G, Popa MI (2012) Core-shell magnetic chitosan particles functionalized by grafting: synthesis and characterization. Chem Eng J 203:130–141CrossRef
go back to reference Emami-Razavi SH, Esmaeili N, Forouzannia SK et al (2006) Effect of bentonite on skin wound healing: experimental study in the rat model. Acta Med Iran 44:235–240 Emami-Razavi SH, Esmaeili N, Forouzannia SK et al (2006) Effect of bentonite on skin wound healing: experimental study in the rat model. Acta Med Iran 44:235–240
go back to reference Gabr MH, Phong NT, Abdelkareem MA et al (2013) Mechanical, thermal, and moisture absorption properties of nano-clay reinforced nano-cellulose biocomposites. Cellulose 20:819–826CrossRef Gabr MH, Phong NT, Abdelkareem MA et al (2013) Mechanical, thermal, and moisture absorption properties of nano-clay reinforced nano-cellulose biocomposites. Cellulose 20:819–826CrossRef
go back to reference Gerasin VA, Antipov EM, Karbushev VV et al (2013) New approaches to the development of hybrid nanocomposites: from structural materials to high-tech applications. Russ Chem Rev 82:303–332CrossRef Gerasin VA, Antipov EM, Karbushev VV et al (2013) New approaches to the development of hybrid nanocomposites: from structural materials to high-tech applications. Russ Chem Rev 82:303–332CrossRef
go back to reference Giannelis ER (1996) Polymer layered silicate nanocomposites. Adv Mater 8:29–35CrossRef Giannelis ER (1996) Polymer layered silicate nanocomposites. Adv Mater 8:29–35CrossRef
go back to reference Guinier A (2001) X-ray diffraction: in crystals, imperfect crystals, and amorphous bodies. Dover, New York Guinier A (2001) X-ray diffraction: in crystals, imperfect crystals, and amorphous bodies. Dover, New York
go back to reference Khashirova SYu, Musaev Y, Mikitaev AK et al (2009) Hybrid nanocomposites based on guanidine methacrylate monomer and polymer and layered aluminosilicates: synthesis, structure and properties. Polym Sci Ser B 51:377–382CrossRef Khashirova SYu, Musaev Y, Mikitaev AK et al (2009) Hybrid nanocomposites based on guanidine methacrylate monomer and polymer and layered aluminosilicates: synthesis, structure and properties. Polym Sci Ser B 51:377–382CrossRef
go back to reference Komarova GA, Starodubtsev SG, Khokhlov AR (2012) Magnetic alginate beads for the targeted delivery of functional hydrophobic compounds. Polym Sci Ser A 54:955–959CrossRef Komarova GA, Starodubtsev SG, Khokhlov AR (2012) Magnetic alginate beads for the targeted delivery of functional hydrophobic compounds. Polym Sci Ser A 54:955–959CrossRef
go back to reference Larraza I, Lypez-Gynzalez M, Corrales T, Marcelo G (2012) Hybrid materials: magnetite–polyethylenimine–montmorillonite, as magnetic adsorbents for Cr(VI) water treatment. J Colloid Interface Sci 385:24–33CrossRef Larraza I, Lypez-Gynzalez M, Corrales T, Marcelo G (2012) Hybrid materials: magnetite–polyethylenimine–montmorillonite, as magnetic adsorbents for Cr(VI) water treatment. J Colloid Interface Sci 385:24–33CrossRef
go back to reference Liao M-H, Chen D-H (2002) Preparation and characterization of a novel magnetic nano-adsorbent. J Mater Chem 12:3654–3659CrossRef Liao M-H, Chen D-H (2002) Preparation and characterization of a novel magnetic nano-adsorbent. J Mater Chem 12:3654–3659CrossRef
go back to reference Lou Z, Zhou Z, Zhang W et al (2015) Magnetized bentonite by Fe3O4 nanoparticles treated as adsorbent for methylene blue removal from aqueous solution: synthesis, characterization, mechanism, kinetics and regeneration. J Taiwan Inst Chem E 49:199–205CrossRef Lou Z, Zhou Z, Zhang W et al (2015) Magnetized bentonite by Fe3O4 nanoparticles treated as adsorbent for methylene blue removal from aqueous solution: synthesis, characterization, mechanism, kinetics and regeneration. J Taiwan Inst Chem E 49:199–205CrossRef
go back to reference Luo K, Yin J, Khutoryanskaya OV, Khutoryanskiy VV (2008) Mucoadhesive and elastic films based on blends of chitosan and hydroxyethylcellulose. Macromol Biosci 8:184–192CrossRef Luo K, Yin J, Khutoryanskaya OV, Khutoryanskiy VV (2008) Mucoadhesive and elastic films based on blends of chitosan and hydroxyethylcellulose. Macromol Biosci 8:184–192CrossRef
go back to reference Ma M, Zhang Y, Yu W et al (2003) Preparation and characterization of magnetite nanoparticles coated by amino silane. Colloid Surf A 212:219–226CrossRef Ma M, Zhang Y, Yu W et al (2003) Preparation and characterization of magnetite nanoparticles coated by amino silane. Colloid Surf A 212:219–226CrossRef
go back to reference Maity D, Kale SN, Kaul-Ghanekar R et al (2009) Studies of magnetite nanoparticles synthesized by thermal decomposition of iron(III) acetylacetonate in tri(ethylene glycol). J Magn Magn Mater 321:3093–3098CrossRef Maity D, Kale SN, Kaul-Ghanekar R et al (2009) Studies of magnetite nanoparticles synthesized by thermal decomposition of iron(III) acetylacetonate in tri(ethylene glycol). J Magn Magn Mater 321:3093–3098CrossRef
go back to reference Mao H, Liu X, Yang J et al (2014) Synthesis of magnetic FexOy@silica-pillared clay (SPC) composites via a novel sol–gel route for controlled drug release and targeting. Mater Sci Eng C 40:102–108CrossRef Mao H, Liu X, Yang J et al (2014) Synthesis of magnetic FexOy@silica-pillared clay (SPC) composites via a novel sol–gel route for controlled drug release and targeting. Mater Sci Eng C 40:102–108CrossRef
go back to reference Marins JA, Soares BG, Barud HS, Ribeiro SJL (2013) Flexible magnetic membranes based on bacterial cellulose and its evaluation as electromagnetic interference shielding material. Mater Sci Eng C 33:3994–4001CrossRef Marins JA, Soares BG, Barud HS, Ribeiro SJL (2013) Flexible magnetic membranes based on bacterial cellulose and its evaluation as electromagnetic interference shielding material. Mater Sci Eng C 33:3994–4001CrossRef
go back to reference Meng N, Zhou N-L, Zhang S-Q, Shen J (2009) Synthesis and antimicrobial activities of polymer/montmorillonite–chlorhexidine acetate nanocomposite films. Appl Clay Sci 42:667–670CrossRef Meng N, Zhou N-L, Zhang S-Q, Shen J (2009) Synthesis and antimicrobial activities of polymer/montmorillonite–chlorhexidine acetate nanocomposite films. Appl Clay Sci 42:667–670CrossRef
go back to reference Meng X, Yang L, Kennedy JF, Tian S (2010) Effects of chitosan and oligochitosan on growth of two fungal pathogens and physiological properties in pear fruit. Carbohydr Polym 81:70–75CrossRef Meng X, Yang L, Kennedy JF, Tian S (2010) Effects of chitosan and oligochitosan on growth of two fungal pathogens and physiological properties in pear fruit. Carbohydr Polym 81:70–75CrossRef
go back to reference Pakhomov Y, Blinkova LP, Dmitrieva OV et al (2016) Resuscitating factors for nonculturable cells. In: Lopez-Bonilla JL, Abdullin MI, Zaikov GE (eds) Physical chemistry for the chemical and biochemical sciences. CRC Press, Oakville, pp 335–342CrossRef Pakhomov Y, Blinkova LP, Dmitrieva OV et al (2016) Resuscitating factors for nonculturable cells. In: Lopez-Bonilla JL, Abdullin MI, Zaikov GE (eds) Physical chemistry for the chemical and biochemical sciences. CRC Press, Oakville, pp 335–342CrossRef
go back to reference Pastukhov AV, Davankov VA, Lubentsova KI et al (2013) Structure and properties of magnetic composite sorbents based on hypercrosslinked polystyrenes. Russ J Phys Chem A 87:1702–1708CrossRef Pastukhov AV, Davankov VA, Lubentsova KI et al (2013) Structure and properties of magnetic composite sorbents based on hypercrosslinked polystyrenes. Russ J Phys Chem A 87:1702–1708CrossRef
go back to reference Pershina AG, Sazonov AE, Filimonov VD (2014) Magnetic nanoparticles–DNA interactions: design and applications of nanobiohybrid systems. Russ Chem Rev 83:299–322CrossRef Pershina AG, Sazonov AE, Filimonov VD (2014) Magnetic nanoparticles–DNA interactions: design and applications of nanobiohybrid systems. Russ Chem Rev 83:299–322CrossRef
go back to reference Pomonis PJ, Tsaous ET (2009) Frenkel–Halsey–Hill equation, dimensionality of adsorption, and pore anisotropy. Langmuir 25:9986–9994CrossRef Pomonis PJ, Tsaous ET (2009) Frenkel–Halsey–Hill equation, dimensionality of adsorption, and pore anisotropy. Langmuir 25:9986–9994CrossRef
go back to reference Sing KSW (1998) Adsorption methods for the characterization of porous materials. Adv Colloid Interface 76–77:3–11CrossRef Sing KSW (1998) Adsorption methods for the characterization of porous materials. Adv Colloid Interface 76–77:3–11CrossRef
go back to reference Vaia RA, Giannelis EP (1997) Lattice model of polymer melt intercalation in organically-modified layered silicates. Macromolecules 30:7990–7999CrossRef Vaia RA, Giannelis EP (1997) Lattice model of polymer melt intercalation in organically-modified layered silicates. Macromolecules 30:7990–7999CrossRef
go back to reference Wilpiszewska K, Antosik AK, Spychay T (2015) Novel hydrophilic carboxymethyl starch/montmorillonite nanocomposite films. Carbohydr Polym 128:82–89CrossRef Wilpiszewska K, Antosik AK, Spychay T (2015) Novel hydrophilic carboxymethyl starch/montmorillonite nanocomposite films. Carbohydr Polym 128:82–89CrossRef
go back to reference Yuan P, Fan M, Yang D et al (2009) Montmorillonite-supported magnetite nanoparticles for the removal of hexavalent chromium [Cr(VI)] from aqueous solutions. J Hazard Mater 166:821–829CrossRef Yuan P, Fan M, Yang D et al (2009) Montmorillonite-supported magnetite nanoparticles for the removal of hexavalent chromium [Cr(VI)] from aqueous solutions. J Hazard Mater 166:821–829CrossRef
go back to reference Zhao Z, Tang T, Qin Y, Huang B (2003) Effects of surfactant loadings on the dispersion of clays in maleated polypropylene. Langmuir 19:7157–7159CrossRef Zhao Z, Tang T, Qin Y, Huang B (2003) Effects of surfactant loadings on the dispersion of clays in maleated polypropylene. Langmuir 19:7157–7159CrossRef
go back to reference Zhong Y, Wang SQ (2003) Exfoliation and yield behavior in nanodispersions of organically modified montmorillonite clay. J Rheol 47:483–496CrossRef Zhong Y, Wang SQ (2003) Exfoliation and yield behavior in nanodispersions of organically modified montmorillonite clay. J Rheol 47:483–496CrossRef
Metadata
Title
Hydroxyethyl cellulose/bentonite/magnetite hybrid materials: structure, physicochemical properties, and antifungal activity
Authors
Olga V. Alekseeva
Anna N. Rodionova
Nadezhda A. Bagrovskaya
Alexandr V. Agafonov
Andrew V. Noskov
Publication date
09-02-2017
Publisher
Springer Netherlands
Published in
Cellulose / Issue 4/2017
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-017-1212-2

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