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Published in: Journal of Materials Engineering and Performance 7/2014

01-07-2014

Improvement of Superelastic Performance of Ti-Nb Binary Alloys for Biomedical Applications

Authors: W. Elmay, E. Patoor, T. Gloriant, F. Prima, P. Laheurte

Published in: Journal of Materials Engineering and Performance | Issue 7/2014

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Abstract

Recently, β-Ti-based alloys consisting of non-cytotoxic elements and possessing a low elastic modulus attracted considerable attention for biomedical applications. In addition to low elastic modulus, these alloys must also present a high strength level required to endure stresses. However, it is not easy to find a thermomechanical route in order to achieve low elastic modulus and high strength simultaneously. In this study, we show that severe cold-rolling deformation followed by a short aging treatment on Ti-Nb binary alloys, in order to produce ultrafine grains and/or omega phase, is an effective way to improve both strength and superelasticity. High stress (900 MPa), low modulus (35 GPa), and high recoverable strain (2.5%) are obtained using this route. The obtained results on mechanical properties are explained in relation with microstructure evolution during thermomechanical processing.

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Literature
1.
go back to reference K. Wang, The Use of Titanium for Medical Applications in the USA, Mater. Sci. Eng., 1996, A213, p 134–137CrossRef K. Wang, The Use of Titanium for Medical Applications in the USA, Mater. Sci. Eng., 1996, A213, p 134–137CrossRef
2.
go back to reference M. Niinomi, Mechanical Biocompatibilities of Titanium Alloys for Biomedical Applications, J. Mech. Behav. Biomed. Mater., 2008, 1, p 30–42CrossRef M. Niinomi, Mechanical Biocompatibilities of Titanium Alloys for Biomedical Applications, J. Mech. Behav. Biomed. Mater., 2008, 1, p 30–42CrossRef
3.
go back to reference W. Elmay, P. Laheurte, A. Eberhardt, B. Bolle, T. Gloriant, E. Patoor, F. Prima, P. Castany, and M. Wary, Stability and Elastic Properties of β Ti-Alloys for Biomedical Application Designed with Electronic Parameters, Eur. Phys. J. Conf., 2010, 6, p 29002 W. Elmay, P. Laheurte, A. Eberhardt, B. Bolle, T. Gloriant, E. Patoor, F. Prima, P. Castany, and M. Wary, Stability and Elastic Properties of β Ti-Alloys for Biomedical Application Designed with Electronic Parameters, Eur. Phys. J. Conf., 2010, 6, p 29002
4.
go back to reference D.L. Moffat and U.R. Kattner, The Stable and Metastable Ti-Nb Phase Diagrams, Metall. Trans. A, 1988, 19, p 2389–2397CrossRef D.L. Moffat and U.R. Kattner, The Stable and Metastable Ti-Nb Phase Diagrams, Metall. Trans. A, 1988, 19, p 2389–2397CrossRef
5.
go back to reference D.L. Moffat and D.C. Larbalestier, The Competition Between Martensite and Omega Phase in Quenched Ti-Nb Alloys, Metall. Trans. A, 1988, 19, p 1677–1686CrossRef D.L. Moffat and D.C. Larbalestier, The Competition Between Martensite and Omega Phase in Quenched Ti-Nb Alloys, Metall. Trans. A, 1988, 19, p 1677–1686CrossRef
6.
go back to reference T.W. Duerig, J. Albrecht, D. Richter, and P. Fischer, Formation and Reversion of Stress Induced Martensite in Ti-10V-2Fe-3Al, Acta Metall., 1982, 30, p 2161–2172CrossRef T.W. Duerig, J. Albrecht, D. Richter, and P. Fischer, Formation and Reversion of Stress Induced Martensite in Ti-10V-2Fe-3Al, Acta Metall., 1982, 30, p 2161–2172CrossRef
7.
go back to reference N. Sumitomo, K. Noritake, T. Hattori, K. Morikawa, and S. Niwa, Experiment Study on Fracture Fixation with Low Rigidity Titanium Alloy, J. Mater. Sci. Mater. Med., 2008, 19, p 1581–1586CrossRef N. Sumitomo, K. Noritake, T. Hattori, K. Morikawa, and S. Niwa, Experiment Study on Fracture Fixation with Low Rigidity Titanium Alloy, J. Mater. Sci. Mater. Med., 2008, 19, p 1581–1586CrossRef
8.
go back to reference L. Girod, V. Berry-Kromer, T. Ben Zineb, A. Eberhardt, E. Patoor, and B. Prandi, Evaluation of the immediate post-operative bone-implant condition of a proximal interphalangeal joint prosthesis by a comparative FEA modelling, Int. J. Interact. Des Manuf., 2010, 4, p 157–167CrossRef L. Girod, V. Berry-Kromer, T. Ben Zineb, A. Eberhardt, E. Patoor, and B. Prandi, Evaluation of the immediate post-operative bone-implant condition of a proximal interphalangeal joint prosthesis by a comparative FEA modelling, Int. J. Interact. Des Manuf., 2010, 4, p 157–167CrossRef
9.
go back to reference F. Sun, Y.L. Hao, S. Nowak, T. Gloriant, P. Laheurte, and F. Prima, A thermo-mechanical treatment to improve the superelastic performances of biomedical Ti-26Nb and Ti-20Nb-6Zr (at.%) alloys, J. Mech. Behav. Biomed. Mater., 2011, 4, p 1864–1872CrossRef F. Sun, Y.L. Hao, S. Nowak, T. Gloriant, P. Laheurte, and F. Prima, A thermo-mechanical treatment to improve the superelastic performances of biomedical Ti-26Nb and Ti-20Nb-6Zr (at.%) alloys, J. Mech. Behav. Biomed. Mater., 2011, 4, p 1864–1872CrossRef
10.
go back to reference F. Sun, S. Nowak, T. Gloriant, P. Laheurte, A. Eberhardt, and F. Prima, Influence of a Short Thermal Treatment on the Superelastic Properties of a Titanium-Based Alloy, Scripta Mater., 2010, 63, p 1053–1056CrossRef F. Sun, S. Nowak, T. Gloriant, P. Laheurte, A. Eberhardt, and F. Prima, Influence of a Short Thermal Treatment on the Superelastic Properties of a Titanium-Based Alloy, Scripta Mater., 2010, 63, p 1053–1056CrossRef
11.
go back to reference H.Y. Kim, J.I. Kim, T. Inamura, H. Hosoda, and S. Miyazaki, Effect of Thermo-Mechanical Treatment on Mechanical Properties and Shape Memory Behavior of Ti-(26-28) at.% Nb alloys, Mater. Sci. Eng. A, 2006, 438, p 839–843CrossRef H.Y. Kim, J.I. Kim, T. Inamura, H. Hosoda, and S. Miyazaki, Effect of Thermo-Mechanical Treatment on Mechanical Properties and Shape Memory Behavior of Ti-(26-28) at.% Nb alloys, Mater. Sci. Eng. A, 2006, 438, p 839–843CrossRef
12.
go back to reference A. Danno, C.C. Wong, S. Tong, A. Jarfors, K. Nishino, and T. Furuta, ct of Cold Severe Deformation by Multi Directional Forging on Elastic Modulus of Multi-Functional Ti + 25 mol.% (Ta, Nb, V) + (Zr, Hr, O) Alloy, Mater. Design., 2010, 31, p 61–65CrossRef A. Danno, C.C. Wong, S. Tong, A. Jarfors, K. Nishino, and T. Furuta, ct of Cold Severe Deformation by Multi Directional Forging on Elastic Modulus of Multi-Functional Ti + 25 mol.% (Ta, Nb, V) + (Zr, Hr, O) Alloy, Mater. Design., 2010, 31, p 61–65CrossRef
13.
go back to reference J.I. Kim, H.Y. Kim, T. Inamura, H. Hosoda, and S. Miyazaki, Effect of Annealing Temperature on Microstructure and Shape Memory Characteristics of Ti-22Nb-6Zr (at.%) Biomedical Alloy, Mater. Trans., 2006, 47, p 505–512CrossRef J.I. Kim, H.Y. Kim, T. Inamura, H. Hosoda, and S. Miyazaki, Effect of Annealing Temperature on Microstructure and Shape Memory Characteristics of Ti-22Nb-6Zr (at.%) Biomedical Alloy, Mater. Trans., 2006, 47, p 505–512CrossRef
14.
go back to reference S. Miyazaki, H.Y. Kim, and H. Hosoda, Development and characterization of Ni-free Ti-base shape memory and superelastic alloys, Mater. Sci. Eng. A, 2006, 438, p 18–24CrossRef S. Miyazaki, H.Y. Kim, and H. Hosoda, Development and characterization of Ni-free Ti-base shape memory and superelastic alloys, Mater. Sci. Eng. A, 2006, 438, p 18–24CrossRef
15.
go back to reference O.M. Ivasishin, P.E. Markovsky, Y.V. Matviychuk, S.L. Semiatin, C.H. Ward, and S. Fox, A Comparative Study of the Mechanical Properties of High-Strength β-Titanium Alloys, J. Alloy Compd., 2008, 457, p 296–309CrossRef O.M. Ivasishin, P.E. Markovsky, Y.V. Matviychuk, S.L. Semiatin, C.H. Ward, and S. Fox, A Comparative Study of the Mechanical Properties of High-Strength β-Titanium Alloys, J. Alloy Compd., 2008, 457, p 296–309CrossRef
16.
go back to reference W. Elmay, F. Prima, T. Gloriant, B. Bolle, Y. Zhong, E. Patoor, and P. Laheurte, Effects of Thermomechanical Process on the Microstructure and Mechanical Properties of a Fully Martensitic Titanium-Based Biomedical Alloy, J. Mech. Behav. Biomed. Mater., 2013, 18, p 47–56CrossRef W. Elmay, F. Prima, T. Gloriant, B. Bolle, Y. Zhong, E. Patoor, and P. Laheurte, Effects of Thermomechanical Process on the Microstructure and Mechanical Properties of a Fully Martensitic Titanium-Based Biomedical Alloy, J. Mech. Behav. Biomed. Mater., 2013, 18, p 47–56CrossRef
17.
go back to reference N. Tsuji, T. Iwata, M. Sato, S. Fujimoto, and Y. Minamino, Aging Behavior of Ultrafine Grained Al-2wt.%Cu Alloy Severely Deformed by Accumulative Roll Bonding (ARB), Sci. Technol. Adv. Mater., 2004, 5, p 173–180CrossRef N. Tsuji, T. Iwata, M. Sato, S. Fujimoto, and Y. Minamino, Aging Behavior of Ultrafine Grained Al-2wt.%Cu Alloy Severely Deformed by Accumulative Roll Bonding (ARB), Sci. Technol. Adv. Mater., 2004, 5, p 173–180CrossRef
18.
go back to reference F. Sun, Y.L. Hao, J.Y. Zhang, and F. Prima, Contribution of Nano-Sized Lamellar Microstructure on Recoverable Strain of Ti-24Nb-4Zr-7.9Sn Titanium Alloy, Mater. Sci. Eng. A, 2011, 528, p 7811–7815CrossRef F. Sun, Y.L. Hao, J.Y. Zhang, and F. Prima, Contribution of Nano-Sized Lamellar Microstructure on Recoverable Strain of Ti-24Nb-4Zr-7.9Sn Titanium Alloy, Mater. Sci. Eng. A, 2011, 528, p 7811–7815CrossRef
19.
go back to reference P. Laheurte, A. Eberhardt, and M.J. Philippe, Influence on the Pseudoelasticity of a Metastable Beta Titanium Alloy, Mater. Sci. Eng. A, 2005, 396, p 223–230CrossRef P. Laheurte, A. Eberhardt, and M.J. Philippe, Influence on the Pseudoelasticity of a Metastable Beta Titanium Alloy, Mater. Sci. Eng. A, 2005, 396, p 223–230CrossRef
20.
go back to reference P. Laheurte, F. Prima, A. Eberhardt, T. Gloriant, M. Wary, and E. Patoor, Mechanical Properties of Low Modulus β Titanium Alloys Designed from the Electronic Approach, J. Mech. Behav. Biomed. Mater., 2010, 3, p 565–573CrossRef P. Laheurte, F. Prima, A. Eberhardt, T. Gloriant, M. Wary, and E. Patoor, Mechanical Properties of Low Modulus β Titanium Alloys Designed from the Electronic Approach, J. Mech. Behav. Biomed. Mater., 2010, 3, p 565–573CrossRef
21.
go back to reference Y. Ohmori, T. Ogo, K. Nakai, and S. Kobayashi, Effect of ω Phase Precipitation on β→α, α″ Transformations in a Metastable β Titanium Alloys, Mater. Sci. Eng. A, 2001, 312, p 182–188CrossRef Y. Ohmori, T. Ogo, K. Nakai, and S. Kobayashi, Effect of ω Phase Precipitation on β→α, α″ Transformations in a Metastable β Titanium Alloys, Mater. Sci. Eng. A, 2001, 312, p 182–188CrossRef
22.
go back to reference H.Y. Kim, J.I. Kim, T. Inamura, H. Hosoda, and S. Miyazaki, Effect of Thermo-Mechanical Treatment on Mechanical Properties and Shape Memory Behavior of Ti-(26-28) at.% Nb Alloys, Mater. Sci. Eng. A, 2006, 438-440, p 839–843CrossRef H.Y. Kim, J.I. Kim, T. Inamura, H. Hosoda, and S. Miyazaki, Effect of Thermo-Mechanical Treatment on Mechanical Properties and Shape Memory Behavior of Ti-(26-28) at.% Nb Alloys, Mater. Sci. Eng. A, 2006, 438-440, p 839–843CrossRef
23.
go back to reference D. Kent, G. Wang, Z. Yu, and M.S. Dargusch, Pseudoelastic Behaviour of a β Ti-25Nb-3Zr-3Mo-2Sn Alloy, Mater. Sci. Eng. A, 2010, 527, p 2246–2252CrossRef D. Kent, G. Wang, Z. Yu, and M.S. Dargusch, Pseudoelastic Behaviour of a β Ti-25Nb-3Zr-3Mo-2Sn Alloy, Mater. Sci. Eng. A, 2010, 527, p 2246–2252CrossRef
Metadata
Title
Improvement of Superelastic Performance of Ti-Nb Binary Alloys for Biomedical Applications
Authors
W. Elmay
E. Patoor
T. Gloriant
F. Prima
P. Laheurte
Publication date
01-07-2014
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 7/2014
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-014-0876-0

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