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Polymer Bulletin
Published in: Polymer Bulletin 12/2017

27-03-2017 | Original Paper

In situ polymerisation and characteristic properties of the waterborne graphene oxide/poly(siloxane-urethane)s nanocomposites

Authors: Maw-Cherng Suen, Jia-Hao Gu, Hsun-Tsing Lee, Cheng-Lung Wu, Chien-Shiun Liao, Jia-Jyun Yang

Published in: Polymer Bulletin | Issue 12/2017

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Abstract

In this study, waterborne graphene oxide/poly(siloxane-urethane)s (GO/SWPUs) nanocomposites were in situ synthesised. Therein, siloxane units facilitated the crosslinking of polyurethanes, and GO imparted the nanocomposites with special functions. With increasing GO content, the average particle size, viscosity, and ionic conductivity of the GO/SWPU dispersion increased, but the absolute value of the zeta potential decreased; this was due to ionic interactions between the COO−NH+(C2H5)3 ions of the SWPU and COO−H+ ions of the GO. The surface roughness of the GO/SWPU film was larger as GO content was higher, which was due to a strong interaction between the GO and SWPU phases. Increasing the GO content improved the thermal resistance, dynamic glass transition temperature, and tensile strength of the GO/SWPU film, but adding more than 0.1 wt% GO yielded unfavourable results. Thus, adding GO improved the thermal and mechanical properties of the GO/SWPU nanocomposites, but this improvement was observed only up to a certain GO concentration, possibly because of the agglutination of GO in SWPU. In addition, the surface and volumetric electrical resistivities of the GO/SWPU nanocomposites decreased when the GO content were increased.
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Metadata
Title
In situ polymerisation and characteristic properties of the waterborne graphene oxide/poly(siloxane-urethane)s nanocomposites
Authors
Maw-Cherng Suen
Jia-Hao Gu
Hsun-Tsing Lee
Cheng-Lung Wu
Chien-Shiun Liao
Jia-Jyun Yang
Publication date
27-03-2017
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 12/2017
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-017-1990-6

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