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Journal of Iron and Steel Research International

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23-11-2019 | Original Paper

Influence of annealing on microstructure and hydrogen storage properties of V₄₈Fe₁₂Ti₁₅Cr₂₅ alloy

Authors: Long Luo, Xuan Bian, Wen-yuan Wu, Ze-ming Yuan, Yong-zhi Li, Ting-ting Zhai, Feng Hu

Published in: Journal of Iron and Steel Research International | Issue 2/2020

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Abstract

V₄₈Fe₁₂Ti₁₅Cr₂₅ alloy was prepared using vacuum arc melting and was subsequently annealed for 10 h at 1273 K. The effects of annealing on the hydrogen storage properties and microstructure of the V₄₈Fe₁₂Ti₁₅Cr₂₅ alloys were investigated. The results indicated that the alloy consisted of main body-centered cubic, Ti-rich, and TiFe phases. After annealing, the kinetic properties of the alloy were improved but its hydrogen storage capacity was slightly reduced. The kinetic mechanisms of the hydrogen absorption and desorption of the alloys were studied. The dehydrogenation enthalpy of the alloy was decreased by 2.57 kJ/mol after annealing. Differential scanning calorimetry indicated that the hydride decomposition temperature of the annealed alloy was decreased. The hydrogen desorption activation energies of the as-cast and annealed alloys were calculated to be 79.41 and 71.25 kJ/mol, respectively. The results illustrated that annealing was a beneficial method of improving the kinetic and thermodynamic properties of the hydrogen absorption/desorption of the alloy.

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[1]

J.L. Gao, Y. Qi, Y.Q. Li, H.W. Shang, D.L. Zhao, Y.H. Zhang, J. Iron Steel Res. Int. 24 (2017) 198–205.

[2]

Z.M. Yuan, T. Yang, W.G. Bu, H.W. Shang, Y. Qi, Y.H. Zhang, Int. J. Hydrogen Energy 41 (2016) 5994–6003.

[3]

H.C. Lin, K.M. Lin, K.C. Wu, H.H. Hsiung, H.K. Tsai, Int. J. Hydrogen Energy 32 (2007) 4966–4972.

[4]

D.C. Feng, H. Sun, Z.H. Hou, D.L. Zhao, X.T. Wang, Y.H. Zhang, J. Iron Steel Res. Int. 24 (2017) 50–58.

[5]

D.C. Feng, H. Sun, X.T. Wang, Y.H. Zhang, J. Iron Steel Res. Int. 25 (2018) 746–754.

[6]

M. Anik, F. Karanfil, N. Küçükdeveci, Int. J. Hydrogen Energy 37 (2012) 299–308.

[7]

Y.H. Zhang, Z.C. Jia, Z.M. Yuan, T. Yang, Y. Qi, D.L. Zhao, J. Iron Steel Res. Int. 22 (2015) 757–770.

[8]

M.V. Lototsky, V.A. Yartys, I.Y. Zavaliy, J. Alloy. Compd. 404 (2005) 421–426.

[9]

X.P. Song, P. Pei, P.L. Zhang, G.L. Chen, J. Alloy. Compd. 455 (2008) 392–397.

[10]

X.B. Yu, Z Wu, B.J. Xia, T.Z. Huang, J.Z. Chen, Z.S. Wang, N.X. Xu, J. Mater. Res. 18 (2003) 2533–2536.

[11]

X.B. Yu, J.Z. Chen, Z. Wu, B.J. Xia, N.X. Xu, Int. J. Hydrogen Energy 29 (2004) 1377–1381.

[12]

X.B. Yu, Z.X. Yang, S.L. Feng, Z. Wu, N.X. Xu, Int. J. Hydrogen Energy 31 (2006) 1176–1181.

[13]

X.B. Yu, S.L. Feng, Z. Wu, B.J. Xia, N.X. Xu, J. Alloy. Compd. 393 (2005) 129–134.

[14]

X.B. Yu, Z.W. Tang, D.L. Sun, L.Z Ouyang, M. Zhu, Prog. Mater. Sci. 88 (2017) 1–48.

[15]

T. Tamura, Y. Tominaga, K. Matsumoto, T. Fuda, T. Kuriiwa, A. Kamegawa, H. Takamura, M. Okada, J. Alloy. Compd. 330 (2002) 522–525.

[16]

S.W. Cho, C.S. Han, C.N. Park, E. Akiba, J. Alloy. Compd. 289 (1999) 244–250.

[17]

K. Asano, S. Hayashi, Y. Nakamura, E. Akiba, J. Alloy. Compd. 524 (2012) 63–68.

[18]

K. Asano, S. Hayashi, Y. Nakamura, Acta Mater. 83 (2015) 479–487.

[19]

K. Asano, S. Hayashi, Y. Nakamura, Int. J. Hydrogen Energy 41 (2016) 6369–6375.

[20]

H. Kim, K. Sakaki, I. Saita, H. Enoki, K. Noguchi, A. Machida, T. Watanuki, Y. Nakamura, Int. J. Hydrogen Energy 39 (2014) 10546–10551.

[21]

G. Mazzolai, Int. J. Hydrogen Energy 33 (2008) 7116–7121.

[22]

S.W. Cho, C.N. Park, J.H. Yoo, J. Choi, J.S. Park, C.Y. Suh, G. Shim, J. Alloy Compd. 403 (2005) 262–266.

[23]

T. Kabutomori, H. Takeda, Y. Wakisaka, K. Ohnishi, J. Alloy. Compd. 231 (1995) 528–532.

[24]

U. Ulmer, K. Asano, A. Patyk, H. Enoki, Y. Nakamur, A. Pohl, R. Dittmeyer, M. Fichtner, J. Alloy. Compd. 648 (2015) 1024–1030.

[25]

X.B. Yu, Z. Wu, F. Li, B.J. Xia, N.X. Xu, Appl. Phys. Lett. 84 (2004) 3199–3201.

[26]

X.B. Yu, Z. Wu, B.J. Xia, N.X. Xu, J. Alloy. Compd. 372 (2004) 272–277.

[27]

Y.G. Yan, Y.H. Chen, C.L. Wu, M.D. Tao, H. Liang, J. Power Sources 164 (2007) 799–802.

[28]

J. Mi, F. LÜ, X.P. Liu, L.J. Jiang, Z.N. Li, S.M. Wang, J. Rare Earth 28 (2010) 781–784.

[29]

J. Matsuda, E. Akiba, J. Alloy. Compd. 581 (2013) 369–372.

[30]

Z.W. Chen, X.Z. Xiao, L.X. Chen, X.L. Fan, L.X. Liu, S.Q. Li, H.W. Ge, Q.D. Wang, Int. J. Hydrogen Energy 38 (2013) 12803–12810.

[31]

Y.H. Zhang, Z.H. Hou, Y. Cai, H.W. Shang, Y. Qi, D.L. Zhao, J. Iron Steel Res. Int. 24 (2017) 296–305.

[32]

S. Suwarno, J.K. Solberg, J.P. Maehlen, B. Krogh, V.A. Yartys, Int. J. Hydrogen Energy 37 (2012) 7624–7628.

[33]

A. Kamegawa, T. Tamura, H. Takamura, M. Okada, J. Alloy. Compd. 356–357 (2003) 447–451.

[34]

X.P. Liu, L.J. Jiang, Z.N. Li, Z. Huang, S.M. Wang, J. Alloy. Compd. 471 (2009) L36–L38.

[35]

M. Okada, T. Kuriiwa, T. Tamura, H. Takamura, A. Kamegawa, J. Alloy. Compd. 330 (2002) 511–516.

[36]

S. Cho, G. Shim, G. Cho, C. Park, J. Yoo, J. Choi, J. Alloy. Compd. 430 (2007) 136–141.

[37]

M. Tsukahara, Mater. Trans. 52 (2011) 68–72.

[38]

Z.M. Hang, X.Z. Xiao, S.Q. Li, H.W. Ge, C.P. Chen, L.X. Chen, J. Alloy. Compd. 529 (2012) 128–133.

[39]

Y.F. Zhu, H.G. Pan, M.X. Gao, Y.F. Liu, Q.D. Wang, J. Alloy. Compd. 348 (2003) 301–308.

[40]

M.H. Rong, F. Wang, J. Wang, Z.M. Wang, H.Y. Zhou, Prog. Nat. Sci. 27 (2017) 543–549.

[41]

E. Akiba, H. Iba, Intermetallics 6 (1998) 461–470.

[42]

Y.G. Yan, Y.G. Chen, X.X. Zhou, H. Liang, C.L. Wu, M.D. Tao, J. Alloy. Compd. 453 (2008) 428–432.

[43]

Y.G. Yan, Y.G. Chen, H. Liang, X.X. Zhou, C.L. Wu, M.D. Tao, L.J. Pang, J. Alloy. Compd. 454 (2008) 427–431.

[44]

J.Y. Wang, R.R. Jeng, J.K. Nieh, S.Y. Lee, S.L. Lee, H.Y. Bor, Int. J. Hydrogen Energy 32 (2007) 3959–3964.

[45]

Y. Nakamura, K. Oikawa, T. Kamiyama, E. Akiba, J. Alloy. Comp. 316 (2001) 284–289.

[46]

N. Endo, I. Saita, Y. Nakamura, H. Saitoh, A. Machida, Int. J. Hydrogen Energy 40 (2015) 3283–3287.

[47]

H.Y. Leng, Z.G. Yu, J. Yin, Q. Li, Z. Wu, K.C. Chou, Int. J. Hydrogen Energy 42 (2017) 23731–23736.

[48]

P. Lv, J. Huot, Energy 138 (2017) 375–382.

[49]

Y.P. Pang, Q. Li, Int. J. Hydrogen Energy 41 (2016) 18072–18087.

[50]

B.K. Singh, S.W. Cho, K.S. Bartwal, Int. J. Hydrogen Energy 39 (2014) 8351–8356.

[51]

P. Pei, X.P. Song, J. Liu, G.L. Chen, X.B. Qin, B.Y. Wang, Int. J. Hydrogen Energy 34 (2009) 8094–8100.

[52]

H.Y. Zhou, F. Wang, J. Wang, Z.M. Wang, Q.R. Yao, J.Q. Deng, C.Y. Tang, G.H. Rao, Int. J. Hydrogen Energy 39 (2014) 14887–14895.

[53]

E.D. Wu, W.H. Li, J. Li, Int. J. Hydrogen Energy 37 (2012) 1509–1517.

[54]

T.D. Wu, X.Y. Xue, T.B. Zhang, R. Hu, H.C. Kou, J.S. Li, J. Alloy. Compd. 645 (2015) 358–368.

[55]

H.E. Kissinger, Anal. Chem. 29 (1957) 1702–1706.

Title: Influence of annealing on microstructure and hydrogen storage properties of V48Fe12Ti15Cr25 alloy
Authors: Long Luo
Xuan Bian
Wen-yuan Wu
Ze-ming Yuan
Yong-zhi Li
Ting-ting Zhai
Feng Hu
Publication date: 23-11-2019
Publisher: Springer Singapore
Published in: Journal of Iron and Steel Research International / Issue 2/2020
Print ISSN: 1006-706X
Electronic ISSN: 2210-3988
DOI: https://doi.org/10.1007/s42243-019-00337-4

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Influence of annealing on microstructure and hydrogen storage properties of V₄₈Fe₁₂Ti₁₅Cr₂₅ alloy

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