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Journal of Iron and Steel Research International
Erschienen in: Journal of Iron and Steel Research International 2/2020

23.11.2019 | Original Paper

Influence of annealing on microstructure and hydrogen storage properties of V48Fe12Ti15Cr25 alloy

verfasst von: Long Luo, Xuan Bian, Wen-yuan Wu, Ze-ming Yuan, Yong-zhi Li, Ting-ting Zhai, Feng Hu

Erschienen in: Journal of Iron and Steel Research International | Ausgabe 2/2020

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Abstract

V48Fe12Ti15Cr25 alloy was prepared using vacuum arc melting and was subsequently annealed for 10 h at 1273 K. The effects of annealing on the hydrogen storage properties and microstructure of the V48Fe12Ti15Cr25 alloys were investigated. The results indicated that the alloy consisted of main body-centered cubic, Ti-rich, and TiFe phases. After annealing, the kinetic properties of the alloy were improved but its hydrogen storage capacity was slightly reduced. The kinetic mechanisms of the hydrogen absorption and desorption of the alloys were studied. The dehydrogenation enthalpy of the alloy was decreased by 2.57 kJ/mol after annealing. Differential scanning calorimetry indicated that the hydride decomposition temperature of the annealed alloy was decreased. The hydrogen desorption activation energies of the as-cast and annealed alloys were calculated to be 79.41 and 71.25 kJ/mol, respectively. The results illustrated that annealing was a beneficial method of improving the kinetic and thermodynamic properties of the hydrogen absorption/desorption of the alloy.
Vorheriger Artikel Effect of intercritical deformation on tensile performance of a low-carbon Si–Mn steel processed by quenching and bainitic partitioning
Nächster Artikel Microstructural evolution and abrasive resistance of WC7Co ceramic particle-reinforced Ti6Al4V composite coating prepared by pulse laser cladding
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Metadaten
Titel
Influence of annealing on microstructure and hydrogen storage properties of V48Fe12Ti15Cr25 alloy
verfasst von
Long Luo
Xuan Bian
Wen-yuan Wu
Ze-ming Yuan
Yong-zhi Li
Ting-ting Zhai
Feng Hu
Publikationsdatum
23.11.2019
Verlag
Springer Singapore
Erschienen in
Journal of Iron and Steel Research International / Ausgabe 2/2020
Print ISSN: 1006-706X
Elektronische ISSN: 2210-3988
DOI
https://doi.org/10.1007/s42243-019-00337-4

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