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Published in: Journal of Sol-Gel Science and Technology 3/2018

20-01-2018 | Original Paper: Sol-gel and hybrid materials for dielectric, electronic, magnetic and ferroelectric applications

Influence of erbium on the structural, optical and magnetic properties of sol–gel Ce: YIG films

Authors: Suleiman M. Elhamali, N. B. Ibrahim, S. Radiman

Published in: Journal of Sol-Gel Science and Technology | Issue 3/2018

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Abstract

Sol–gel Y2.8-xCe0.2Er x Fe5O12 (x = 0.0, 0.2, 0. 4, 0.6, 0.8 and 1.0) nanofilms were successfully prepared for their potential use in nonreciprocal magneto-optical devices, such as isolators and circulators. The effect of Er-doped Ce-substituted yttrium iron garnet (Ce:YIG) was investigated using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), UV–vis spectrophotometry and vibrating sample magnetometry (VSM). Analysis of the diffractograms indicated a cubic garnet structure and the incorporation of the Er3+ ions into the Ce: YIG. The absorption bands in IR spectra revealed the fingerprint of the YIG structure in the obtained films. The optical transparency of the Er-doped Ce:YIG samples was above 98% in the visible and near infrared region wavelengths. All samples were soft ferrimagnetic films, as indicated by their hysteresis loops and low magnetic coercivity fields (~50 Oe). As more erbium ions were introduced, the saturation magnetisation decreased and the magnetic coercivity increased. These findings suggest that Er-doped Ce:YIG films may have a promising role in magneto-optical applications.

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Literature
1.
go back to reference Huang M, Zhang S (2002) Growth and characterization of rare-earth iron garnet single crystals modified by bismuth and ytterbium substituted for yttrium. Mater Chem Phys 73(2):314–317CrossRef Huang M, Zhang S (2002) Growth and characterization of rare-earth iron garnet single crystals modified by bismuth and ytterbium substituted for yttrium. Mater Chem Phys 73(2):314–317CrossRef
2.
go back to reference Xu Y, Yang JH, Zhang XJ (1994) Quantum theory of the strong magneto-optical effect of Ce-substituted yttrium iron garnet. Phys Rev B 50(18):13428CrossRef Xu Y, Yang JH, Zhang XJ (1994) Quantum theory of the strong magneto-optical effect of Ce-substituted yttrium iron garnet. Phys Rev B 50(18):13428CrossRef
3.
go back to reference Sekijima T, Funakoshi T, Katabe K, Tahara K, Fujii T, Wakino K, Okada M (1998) Growth and optical properties of Ce-substituted fibrous YIG single crystals. Jpn J Appl Phys 37(9R):4854CrossRef Sekijima T, Funakoshi T, Katabe K, Tahara K, Fujii T, Wakino K, Okada M (1998) Growth and optical properties of Ce-substituted fibrous YIG single crystals. Jpn J Appl Phys 37(9R):4854CrossRef
6.
go back to reference Mao T-C, Chen J-C (2006) Influence of the addition of CeO2 on the microstructure and the magnetic properties of yttrium iron garnet ceramic. J Magn Magn Mater 302(1):74–81CrossRef Mao T-C, Chen J-C (2006) Influence of the addition of CeO2 on the microstructure and the magnetic properties of yttrium iron garnet ceramic. J Magn Magn Mater 302(1):74–81CrossRef
7.
go back to reference Arsad A, Ibrahim N (2016) The effect of Ce doping on the structure, surface morphology and magnetic properties of Dy doped-yttrium iron garnet films prepared by a sol–gel method. J Magn Magn Mater 410:128–136CrossRef Arsad A, Ibrahim N (2016) The effect of Ce doping on the structure, surface morphology and magnetic properties of Dy doped-yttrium iron garnet films prepared by a sol–gel method. J Magn Magn Mater 410:128–136CrossRef
8.
go back to reference Daval J, Ferrand B, Geynet J, Challeton D, Peuzin J (1975) Liquid phase epitaxy and magneto-optical properties of garnet films for integrated optics. Mater Res Bull 10(2):95–102CrossRef Daval J, Ferrand B, Geynet J, Challeton D, Peuzin J (1975) Liquid phase epitaxy and magneto-optical properties of garnet films for integrated optics. Mater Res Bull 10(2):95–102CrossRef
10.
go back to reference Bi L, Hu J, Jiang P, Kim HS, Kim DH, Onbasli MC, Dionne GF, Ross CA (2013) Magneto-optical thin films for on-chip monolithic integration of non-reciprocal photonic devices. Materials 6(11):5094–5117CrossRef Bi L, Hu J, Jiang P, Kim HS, Kim DH, Onbasli MC, Dionne GF, Ross CA (2013) Magneto-optical thin films for on-chip monolithic integration of non-reciprocal photonic devices. Materials 6(11):5094–5117CrossRef
11.
go back to reference Kim H, Grishin A, Rao K (2001) Giant Faraday rotation of blue light in epitaxial Ce x Y3−xFe5O12 films grown by pulsed laser deposition. J Appl Phys 89(8):4380–4383CrossRef Kim H, Grishin A, Rao K (2001) Giant Faraday rotation of blue light in epitaxial Ce x Y3−xFe5O12 films grown by pulsed laser deposition. J Appl Phys 89(8):4380–4383CrossRef
12.
go back to reference Sekijima T, Kishimoto H, Fujii T, Wakino K, Okada M (1999) Magnetic, optical and microwave properties of rare-earth-substituted fibrous yttrium iron garnet single crystals grown by floating zone method. Jpn J Appl Phys 38(10R):5874CrossRef Sekijima T, Kishimoto H, Fujii T, Wakino K, Okada M (1999) Magnetic, optical and microwave properties of rare-earth-substituted fibrous yttrium iron garnet single crystals grown by floating zone method. Jpn J Appl Phys 38(10R):5874CrossRef
14.
go back to reference Öztürk Y, Mustafa Ero, Çelik E, Mermer Ö, Kahraman G, Avgýn I (2013) Structural and magnetic properties of cerium-doped yttrium-iron garnet thin films prepared on different substrates using the sol–gel process Mater Tehnol 47(1):59–63 Öztürk Y, Mustafa Ero, Çelik E, Mermer Ö, Kahraman G, Avgýn I (2013) Structural and magnetic properties of cerium-doped yttrium-iron garnet thin films prepared on different substrates using the sol–gel process Mater Tehnol 47(1):59–63
15.
go back to reference Aldbea FW, Ahmad N, Ibrahim N, Yahya M (2014) Effect of increasing pH value on the structural, optical and magnetic properties of yttrium iron garnet films prepared by a sol–gel method. J Sol–gel Sci Technol 71(1):31–37CrossRef Aldbea FW, Ahmad N, Ibrahim N, Yahya M (2014) Effect of increasing pH value on the structural, optical and magnetic properties of yttrium iron garnet films prepared by a sol–gel method. J Sol–gel Sci Technol 71(1):31–37CrossRef
16.
go back to reference Fu Y-P (2009) Electrical conductivity and magnetic properties of Li0.5Fe2.5−xCr x O4 ferrite. Mater Chem Phys 115(1):334–338CrossRef Fu Y-P (2009) Electrical conductivity and magnetic properties of Li0.5Fe2.5−xCr x O4 ferrite. Mater Chem Phys 115(1):334–338CrossRef
17.
go back to reference Pecharsky VK, Zavalij PY (2009) Fundamentals of powder diffraction and structural characterization of materials, vol 69. Springer Pecharsky VK, Zavalij PY (2009) Fundamentals of powder diffraction and structural characterization of materials, vol 69. Springer
18.
go back to reference Suryanarayana C, Norton MG (2013) X-ray diffraction: a practical approach. Springer Science & Business Media Suryanarayana C, Norton MG (2013) X-ray diffraction: a practical approach. Springer Science & Business Media
19.
go back to reference Shaiboub R, Ibrahim NBy, Abdullah M, Abdulhade F (2012) The physical properties of erbium-doped yttrium iron garnet films prepared by sol–gel method. J Nanomater 2012:2 Shaiboub R, Ibrahim NBy, Abdullah M, Abdulhade F (2012) The physical properties of erbium-doped yttrium iron garnet films prepared by sol–gel method. J Nanomater 2012:2
20.
go back to reference Zhou Y, Switzer JA (1996) Growth of cerium (IV) oxide films by the electrochemical generation of base method. J Alloy Compd 237(1–2):1–5CrossRef Zhou Y, Switzer JA (1996) Growth of cerium (IV) oxide films by the electrochemical generation of base method. J Alloy Compd 237(1–2):1–5CrossRef
21.
go back to reference Hofmeister A, Campbell K (1992) Infrared spectroscopy of yttrium aluminum, yttrium gallium, and yttrium iron garnets. J Appl Phys 72(2):638–646CrossRef Hofmeister A, Campbell K (1992) Infrared spectroscopy of yttrium aluminum, yttrium gallium, and yttrium iron garnets. J Appl Phys 72(2):638–646CrossRef
22.
go back to reference Beregi E, Hild E (1986) IR spectroscopic investigation of the garnet materials used in the microwave electronics. Period Polytech Chem Eng 30(3–4):235 Beregi E, Hild E (1986) IR spectroscopic investigation of the garnet materials used in the microwave electronics. Period Polytech Chem Eng 30(3–4):235
23.
go back to reference Niyaifar M, Mohammadpour H, Behmanesh A (2016) Correlation of structural distortion with magnetic properties of Pr-YIG system. J Alloy Compd 683:495–500CrossRef Niyaifar M, Mohammadpour H, Behmanesh A (2016) Correlation of structural distortion with magnetic properties of Pr-YIG system. J Alloy Compd 683:495–500CrossRef
24.
go back to reference Boudiar T, Payet-Gervy B, Blanc-Mignon M-F, Rousseau J-J, Le Berre M, Joisten H (2004) Magneto-optical properties of yttrium iron garnet (YIG) thin films elaborated by radio frequency sputtering. J Magn Magn Mater 284:77–85CrossRef Boudiar T, Payet-Gervy B, Blanc-Mignon M-F, Rousseau J-J, Le Berre M, Joisten H (2004) Magneto-optical properties of yttrium iron garnet (YIG) thin films elaborated by radio frequency sputtering. J Magn Magn Mater 284:77–85CrossRef
25.
go back to reference Wei Y, Wallace RM, Seabaugh AC (1996) Void formation on ultrathin thermal silicon oxide films on the Si (100) surface. Appl Phys Lett 69(9):1270–1272CrossRef Wei Y, Wallace RM, Seabaugh AC (1996) Void formation on ultrathin thermal silicon oxide films on the Si (100) surface. Appl Phys Lett 69(9):1270–1272CrossRef
28.
go back to reference Goto T, Eto Y, Kobayashi K, Haga Y, Inoue M, Ross C (2013) Vacuum annealed cerium-substituted yttrium iron garnet films on non-garnet substrates for integrated optical circuits. J Appl Phys 113(17):17A939CrossRef Goto T, Eto Y, Kobayashi K, Haga Y, Inoue M, Ross C (2013) Vacuum annealed cerium-substituted yttrium iron garnet films on non-garnet substrates for integrated optical circuits. J Appl Phys 113(17):17A939CrossRef
29.
go back to reference Ibrahim N, Arsad A (2016) Investigation of nanostructural, optical and magnetic properties of cerium-substituted yttrium iron garnet films prepared by a sol gel method. J Magn Magn Mater 401:572–578CrossRef Ibrahim N, Arsad A (2016) Investigation of nanostructural, optical and magnetic properties of cerium-substituted yttrium iron garnet films prepared by a sol gel method. J Magn Magn Mater 401:572–578CrossRef
30.
go back to reference Krishnan NR, Jeffery R, Martyniuk M, Woodward R, Saunders M, Dell J, Faraone L (2016) Preparation and characterization of cerium substituted bismuth dysprosium iron garnets for magneto-optic applications. IEEE Trans Magn 52(7):1–4CrossRef Krishnan NR, Jeffery R, Martyniuk M, Woodward R, Saunders M, Dell J, Faraone L (2016) Preparation and characterization of cerium substituted bismuth dysprosium iron garnets for magneto-optic applications. IEEE Trans Magn 52(7):1–4CrossRef
31.
go back to reference Sekhar MC, Singh MR (2012) Fabrication and characterization of Bismuth-Cerium composite iron garnet epitaxial films for magneto optical applications. J Appl Phys 112(8):083525CrossRef Sekhar MC, Singh MR (2012) Fabrication and characterization of Bismuth-Cerium composite iron garnet epitaxial films for magneto optical applications. J Appl Phys 112(8):083525CrossRef
32.
go back to reference Hansen P, Krumme J-P (1984) Magnetic and magneto-optical properties of garnet films. Thin Solid Films 114(1):69–107CrossRef Hansen P, Krumme J-P (1984) Magnetic and magneto-optical properties of garnet films. Thin Solid Films 114(1):69–107CrossRef
33.
go back to reference Wood D, Remeika J (1967) Effect of impurities on the optical properties of yttrium iron garnet. J Appl Phys 38(3):1038–1045CrossRef Wood D, Remeika J (1967) Effect of impurities on the optical properties of yttrium iron garnet. J Appl Phys 38(3):1038–1045CrossRef
34.
go back to reference Xu H, Yang H, Lu L (2008) Effect of erbium oxide on synthesis and magnetic properties of yttrium-iron garnet nanoparticles in organic medium. J Mater Sci: Mater Electron 19(6):509–513 Xu H, Yang H, Lu L (2008) Effect of erbium oxide on synthesis and magnetic properties of yttrium-iron garnet nanoparticles in organic medium. J Mater Sci: Mater Electron 19(6):509–513
35.
go back to reference Bushev P, Feofanov A, Rotzinger H, Protopopov I, Cole J, Wilson C, Fischer G, Lukashenko A, Ustinov A (2011) Ultralow-power spectroscopy of a rare-earth spin ensemble using a superconducting resonator. Phys Rev B 84(6):060501CrossRef Bushev P, Feofanov A, Rotzinger H, Protopopov I, Cole J, Wilson C, Fischer G, Lukashenko A, Ustinov A (2011) Ultralow-power spectroscopy of a rare-earth spin ensemble using a superconducting resonator. Phys Rev B 84(6):060501CrossRef
36.
go back to reference Doualan J, Labbé C, Le Boulanger P, Margerie J, Moncorgé R, Timonen H (1995) Energy levels of the laser active Er3+ ion in each of the two crystallographic sites of yttrium orthosilicate. J Phys: Condens Matter 7(26):5111 Doualan J, Labbé C, Le Boulanger P, Margerie J, Moncorgé R, Timonen H (1995) Energy levels of the laser active Er3+ ion in each of the two crystallographic sites of yttrium orthosilicate. J Phys: Condens Matter 7(26):5111
37.
go back to reference Aldbea FW, Ibrahim N (2015) An overview about the garnet thin films (terbium yttrium iron garnet and aluminum terbium yttrium iron garnet) structural and magnetic properties. J Mater Sci Appl 5(1):185–194 Aldbea FW, Ibrahim N (2015) An overview about the garnet thin films (terbium yttrium iron garnet and aluminum terbium yttrium iron garnet) structural and magnetic properties. J Mater Sci Appl 5(1):185–194
38.
go back to reference Kittel C, McEuen P, McEuen P (1976) Introduction to Solid State Physics, vol 8, Wiley, New York Kittel C, McEuen P, McEuen P (1976) Introduction to Solid State Physics, vol 8, Wiley, New York
39.
go back to reference Elhamali SM, Ibrahim N, Radiman S (2016) Structural, optical and magnetic properties of YIG doped with erbium and terbium nanofilms using sol–gel method. J Adv Nanomater 1(1):11CrossRef Elhamali SM, Ibrahim N, Radiman S (2016) Structural, optical and magnetic properties of YIG doped with erbium and terbium nanofilms using sol–gel method. J Adv Nanomater 1(1):11CrossRef
40.
go back to reference Öztürk Y, Avgin I, Erol M, Çelik E (2009) Cerium-doped yttrium iron garnet thin films prepared by sol–gel process: synthesis, characterization, and magnetic properties. In: Advances in Nanoscale Magnetism. Springer, pp 113–129 Öztürk Y, Avgin I, Erol M, Çelik E (2009) Cerium-doped yttrium iron garnet thin films prepared by sol–gel process: synthesis, characterization, and magnetic properties. In: Advances in Nanoscale Magnetism. Springer, pp 113–129
41.
go back to reference Chang S, Huang W (2005) Texture effect on magnetic properties by alloying specific elements in non-grain oriented silicon steels. ISIJ Int 45(6):918–922CrossRef Chang S, Huang W (2005) Texture effect on magnetic properties by alloying specific elements in non-grain oriented silicon steels. ISIJ Int 45(6):918–922CrossRef
42.
go back to reference Praveena K, Srinath S (2014) Effect of Gd3+ on dielectric and magnetic properties of Y3Fe5O12. J Magn Magn Mater 349:45–50CrossRef Praveena K, Srinath S (2014) Effect of Gd3+ on dielectric and magnetic properties of Y3Fe5O12. J Magn Magn Mater 349:45–50CrossRef
43.
go back to reference Rastogi A, Moorthy V (2002) Magnetic properties of multilayers of nano thin Co, Ce-doped and undoped yttrium iron garnet films for magneto-optic applications. Mater Sci Eng: B 95(2):131–136CrossRef Rastogi A, Moorthy V (2002) Magnetic properties of multilayers of nano thin Co, Ce-doped and undoped yttrium iron garnet films for magneto-optic applications. Mater Sci Eng: B 95(2):131–136CrossRef
44.
go back to reference Akhtar MN, Khan MA, Ahmad M, Murtaza G, Raza R, Shaukat S, Asif M, Nasir N, Abbas G, Nazir M (2014) Y3Fe5O12 nanoparticulate garnet ferrites: comprehensive study on the synthesis and characterization fabricated by various routes. J Magn Magn Mater 368:393–400CrossRef Akhtar MN, Khan MA, Ahmad M, Murtaza G, Raza R, Shaukat S, Asif M, Nasir N, Abbas G, Nazir M (2014) Y3Fe5O12 nanoparticulate garnet ferrites: comprehensive study on the synthesis and characterization fabricated by various routes. J Magn Magn Mater 368:393–400CrossRef
Metadata
Title
Influence of erbium on the structural, optical and magnetic properties of sol–gel Ce: YIG films
Authors
Suleiman M. Elhamali
N. B. Ibrahim
S. Radiman
Publication date
20-01-2018
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 3/2018
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-017-4576-8

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