Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Journal of Polymer Research
Published in: Journal of Polymer Research 2/2020

01-02-2020 | ORIGINAL PAPER

Influence of pentaerythritol on the properties of polyvinyl alcohol films for the polarizers

Authors: Sumei Zhang, Huiyang Yu, Qiang Chen, Haotian Hu, Yingxu Song, Jinyao Chen, Ya Cao, Ming Xiang

Published in: Journal of Polymer Research | Issue 2/2020

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Pentaerythritol was used as the plasticizer to prepare PVA films through solution casting method. The interaction between pentaerythritol and PVA was studied by FTIR. The crystallinity of raw PVA and modified PVA films was characterized by X-ray diffraction. The effect of the addition of pentaerythritol on the swelling properties, mechanical properties and optical properties of PVA films were investigated. The experimental results showed that the addition of pentaerythritol destroyed the hydrogen bonding in the PVA molecule and reduced the crystallinity of PVA. As the pentaerythritol content increased, the swelling property of the PVA films was significantly improved. The addition of pentaerythritol into PVA resulted in the increase of elongation at break, as well as the decrease of tensile strength. As the amount of pentaerythritol added, the optical performance of the PVA films was improved.
previous article New TEMPO containing polymers for all polymeric oxidation procedure
next article Mechanical and thermal properties of hyperbranched poly(ε-caprolactone) modified graphene/epoxy composites

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
Xue B, Zhang J, Zhou T (2015) Moving-window two-dimensional correlation infrared spectroscopic study on the dissolution process of poly(vinyl alcohol). Anal Bioanal Chem 407(29):8765–8771CrossRef
2.
Shin EJ, Lyoo WS, Lee YH (2012) Effect of boric acid treatment method on the characteristics of poly(vinyl alcohol)/iodine polarizing film. J Appl Polym Sci 123(2):672–681CrossRef
3.
Lyoo W, Yeum J, Ghim H, Park J, Lee S, Kim J, Shin D, Lee J (2003) Effect of the molecular weight of poly(vinyl alcohol) on the water stability of a syndiotactic poly(vinyl alcohol)/iodine complex film. Colloid Polym Sci 281(5):416–422CrossRef
4.
Mohsin M, Hossin A, Haik Y (2011) Thermomechanical properties of poly(vinyl alcohol) plasticized with varying ratios of sorbitol. Mater Sci Eng A 528(3):925–930CrossRef
5.
Shin EJ, Lyoo WS, Lee YH (2008) Making polyvinyl alcohol films iodinated at solution state before casting and its application. J Appl Polym Sci 109(2):1143–1149CrossRef
6.
Zhang R, Zhang Q, Ji Y, Su F, Meng L, Qi Z, Lin Y, Li X, Chen X, Lv F, Li L (2018) Stretch-induced complexation reaction between poly(vinyl alcohol) and iodine: an in situ synchrotron radiation small- and wide-angle X-ray scattering study. Soft Matter 14(13):2535–2546CrossRef
7.
Yoon SD, Chough SH, Park HR (2007) Preparation of resistant starch/poly (vinyl alcohol) blend films with added plasticizer and crosslinking agents. J Appl Polym Sci 106(4):2485–2493CrossRef
8.
Dai H, Wang J, Liu N (2019) Preparation and properties of poly (vinyl alcohol) films using carbohydrates as plasticizers. Journal of Vinyl and Additive Technology 25(S1):E181–E187CrossRef
9.
Lin C-A, Ku T-H (2008) Shear and elongational flow properties of thermoplastic polyvinyl alcohol melts with different plasticizer contents and degrees of polymerization. J Mater Process Technol 200(1–3):331–338CrossRef
10.
Wang R, Wang Q, Li L (2003) Evaporation behaviour of water and its plasticizing effect in modified poly (vinyl alcohol) systems. Polym Int 52(12):1820–1826CrossRef
11.
Sothornvit R, Krochta J (2000) Plasticizer effect on oxygen permeability of β-lactoglobulin films. J Agric Food Chem 48(12):6298–6302CrossRef
12.
Jiang X, Jiang T, Gan L, Zhang X, Dai H, Zhang X (2012) The plasticizing mechanism and effect of calcium chloride on starch/poly (vinyl alcohol) films. Carbohydr Polym 90(4):1677–1684CrossRef
13.
Jang J, Lee DK (2003) Plasticizer effect on the melting and crystallization behavior of polyvinyl alcohol. Polymer 44(26):8139–8146CrossRef
14.
Wu W, Tian H, Xiang A (2012) Influence of polyol plasticizers on the properties of polyvinyl alcohol films fabricated by melt processing. J Polym Environ 20(1):63–69CrossRef
15.
Lin F, Wu W, Sun H, Xiang A (2011) Plasticization and crystallization behaviors of polyvinyl alcohol plasticized with various Polyol systems. J Polym Mater 28(4):577–586CrossRef
16.
Han MH, Lyoo WS (2010) Preparation of syndiotacticity-rich high molecular weight poly (vinyl alcohol)/iodine polarizing film with high water resistance. J Appl Polym Sci 115(2):917–922CrossRef
17.
Lyoo WS, Yeum JH, Park JM, Kwak JW, Kim JH, Kim SS, Ji BC, Noh SK (2005) Role of molecular weight of atactic poly (vinyl alcohol)(PVA) in the polarizing efficiency of PVA/azo dye complex film with high durability. J Appl Polym Sci 96(4):967–974CrossRef
18.
Holland BJ, Hay JN (2002) The thermal degradation of poly (vinyl acetate) measured by thermal analysis–Fourier transform infrared spectroscopy. Polymer 43(8):2207–2211CrossRef
19.
Mitić Ž, Cakić M, Nikolić G (2010) Fourier-transform IR spectroscopic investigations of cobalt (II)–dextran complexes by using D 2 O isotopic exchange. J Spectrosc 24(3–4):269–275CrossRef
20.
Cakić M, Mitić Ž, Nikolić GS, Ilić L, Nikolić GM (2008) The investigations of bioactive copper (II) complexes with reduced low-molar dextran. J Spectrosc 22(2–3):177–185CrossRef
21.
Du H, Zhou T, Zhang J, Liu X (2010) Moving-window two-dimensional correlation infrared spectroscopy study on structural variations of partially hydrolyzed poly (vinyl alcohol). Anal Bioanal Chem 397(7):3127–3132CrossRef
22.
Mansur HS, Oréfice RL, Mansur AAP (2004) Characterization of poly(vinyl alcohol)/poly(ethylene glycol) hydrogels and PVA-derived hybrids by small-angle X-ray scattering and FTIR spectroscopy. Polymer 45(21):7193–7202CrossRef
23.
Zhang H, Wang Q, Li L (2009) Dehydration of water-plasticized poly(vinyl alcohol) systems: particular behavior of isothermal mass transfer. Polym Int 58(1):97–104CrossRef
24.
Wang FC (2000) Polymer additive analysis by pyrolysis–gas chromatography: I. Plasticizers. J Chromatogr A 883(1–2):199–210CrossRef
25.
Takamiya H, Tanahashi Y, Matsuyama T, Tanigami T, Yamaura K, Matsuzawa S (1993) On the poly(vinyl alcohol)–iodine complexes. J Appl Polym Sci 50(10):1807–1813CrossRef
Metadata
Title
Influence of pentaerythritol on the properties of polyvinyl alcohol films for the polarizers
Authors
Sumei Zhang
Huiyang Yu
Qiang Chen
Haotian Hu
Yingxu Song
Jinyao Chen
Ya Cao
Ming Xiang
Publication date
01-02-2020
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 2/2020
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-020-2006-z

Other articles of this Issue 2/2020

Journal of Polymer Research 2/2020 Go to the issue

Correction

Correction to: Preparation and characterization of renewable composites from Polylactide and Rice husk for 3D printing applications

ORIGINAL PAPER

Effects of magnetically modified natural zeolite addition on the crosslink density, mechanical, morphological, and damping properties of SIR 20 natural rubber reinforced with nanosilica compounds

ORIGINAL PAPER

Oxygen-rich porous carbons from carbonyl modified hyper-cross-linked polymers for efficient CO2 capture

ORIGINAL PAPER

Synthesis optimization and characterization of high molecular weight polymeric nanoparticles as EOR agent for harsh condition reservoirs

ORIGINAL PAPER

Potency of nanolay on structural, mechanical and gas barrier properties of poly(ethylene terephthalate) Nanohybrid

ORIGINAL PAPER

Superabsorbent polymer based on guar gum-graft-acrylamide: synthesis and characterization

Premium Partners

    Image Credits