Top

Polymer Bulletin

Published in:

23-01-2023 | ORIGINAL PAPER

Influence of polyester dendrimers on swelling and adsorption of metal ion of PVA/PAA hydrogels

Authors: Rasha Elhodiry, Ali Elejmi, Wael Elhrari, Moftah Darwish, Zenab Abdoorhman

Published in: Polymer Bulletin | Issue 12/2023

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

In this study, polyester dendrimers based on triethanolamine were synthesized via a multi-step divergent approach. Triethanolamine was reacted with sebacoyl chloride and 1,4-butanediol as repeating units. The synthesized dendrimers up to G6.5 were characterized by FTIR, ¹H-NMR. The incorporation of selected generations G2.5, G4.5 and G6.5 dendrimers into PVA/PAA films and the influence of added dendrimers on the properties of the films were investigated. The results showed the gel content increased with an increase in the dendrimers content and generation number. The incorporation of dendrimers increases the swelling ability of the films. The highest swelling obtained was at low dendrimers content 1 w% and highest generation number G6.5. The films exhibited pH-sensitive behaviors where they decrease at low pH and expanded at pH 10. The ability of metal adsorption Fe²⁺, Cu²⁺, Ni²⁺ and Zn²⁺ was investigated, the addition of dendrimers enhanced the film adsorption, and the adsorption capacity increased with the increase in pH. The antimicrobial activity of the polyester dendrimers G2.5, G4.5 and G6.5 was investigated, against gram-positive Staphylococcus arouse (S. arouse) and gram-negative Escherichia coli (E. coli) bacteria. The results showed that G6.5 had the highest antimicrobial activity against S. arouse.

previous article An electrochemiluminescence aptasensor based on poly(aniline-luminol)/graphene oxide/chitosan for ultra-sensitive detection of Hg2+

next article The importance of polyurethane/carbon nanotubes composites fabrication method to mimic mechanical behavior of different types of soft tissues

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Frechet JMJ, Henmi M, Gitsov I, Aoshima S, Leduc MR, Grubbs RB (1995) Self-condensing vinyl polymerization: an approach to dendritic materials. Sciencs 269:8–11

Fischer M, Fritz V (1999) From design to application dendrimers: from design to application a progress report. Angew Chem Int Ed 38:884–905CrossRef

Mitsutoshi Jikei MK (2014) Hyperbranched polymers: a promising new class of materials. Prog Polym Sci 26:185–207

Kirchmajer DM, Watson CA, Ranson M, In Het PM (2013) Gelapin, a degradable genipin cross-linked gelatin hydrogel. RSC Adv 3:1073–1081CrossRef

Chen Q, Zhu L (2012) PVA/PVAm hydrogel membranes for removal of metal ions from aqueous solution. Appl Mech Mater 130–134:1507–1510CrossRef

Kim DS, Park HB, Rhim JW, Lee YM (2005) Proton conductivity and methanol transport behavior of cross-linked PVA/PAA/silica hybrid membranes. Solid State Ionics 176:117–126CrossRef

Bessbousse H, Verchère JF, Lebrun L (2012) Characterisation of metal-complexing membranes prepared by the semi-interpenetrating polymer networks technique. Application to the removal of heavy metal ions from aqueous solutions. Chem Eng J 187:16–28CrossRef

Ullah S, Hashmi M, Hussain N, Ullah A, Sarwar MN, Saito Y, Kim SH, Kim IS (2020) Stabilized nanofibers of polyvinyl alcohol (PVA) crosslinked by unique method for efficient removal of heavy metal ions. J Water Process Eng 33:101111CrossRef

Yue YM, Xu K, Liu XG, Chen Q, Sheng X, Wang PX (2008) Preparation and characterization of interpenetration polymer network films based on poly(vinyl alcohol) and poly(acrylic acid) for drug delivery. J Appl Polym Sci 108:3836–3842CrossRef

10.

Qureshi D, Nayak SK, Maji S, Anis A, Kim D, Pal K (2019) Environment sensitive hydrogels for drug delivery applications. Eur Polym J 120:109220CrossRef

11.

Lynch CR, Kondiah PPD, Choonara YE, du Toit LC, Ally N, Pillay V (2020) Hydrogel biomaterials for application in ocular drug delivery. Front Bioeng Biotechnol 8:1–18CrossRef

12.

Gudeman Linda F, Peppas Nikolaos A (1995) Preparation and characterization of pH-sensitive, interpenetrating networks of poly(vinyl alcohol) and poly(acrylic acid). J Appl Polym Sci 55:919–928

13.

Khandaker M (2013) Poly(vinyl alcohol)/poly(acrylic acid) hydrogel in a dc electric field: swelling, shape change, and actuation characteristics. Int J Mater Sci 3:133CrossRefPubMedPubMedCentral

14.

Wang M, Bai J, Shao K, Tang W, Zhao X, Lin D, Huang S, Chen C, Ding Z, Ye J (2021) Poly(vinyl alcohol) hydrogels: the old and new functional materials. Int J Polym Sci. https://doi.org/10.1155/2021/2225426CrossRef

15.

Al-qudah YHF, Mahmoud GA, Abdel Khalek MA (2014) Radiation crosslinked poly (vinyl alcohol)/acrylic acid copolymer for removal of heavy metal ions from aqueous solutions. J Radiat Res Appl Sci 7:135–145

16.

Cheng Y, Hu Y, Xu M, Qin M, Lan W, Huang D, Wei Y, Chen W (2020) High strength polyvinyl alcohol/polyacrylic acid (PVA/PAA) hydrogel fabricated by Cold–Drawn method for cartilage tissue substitutes. J Biomater Sci Polym Ed 31:1836–1851CrossRefPubMed

17.

Santiago-Morales J, Amariei G, Letón P, Rosal R (2016) Antimicrobial activity of poly(vinyl alcohol)-poly(acrylic acid) electrospun nanofibers. Colloids Surf B Biointerfaces 146:144–151CrossRefPubMed

18.

Byun H, Hong B, Sang YN, Sun YJ, Ji WR, Sang BL, Go YM (2008) Swelling behavior and drug release of poly(vinyl alcohol) hydrogel cross-linked with poly(acrylic acid). Macromol Res 16:189–193CrossRef

19.

He J, Chen JP (2014) Cu(II)-imprinted poly(vinyl alcohol)/poly(acrylic acid) membrane for greater enhancement in sequestration of copper ion in the presence of competitive heavy metal ions: material development, process demonstration, and study of mechanisms. Ind Eng Chem Res 53:20223–20233CrossRef

20.

Wang J, He H, Cooper RC, Yang H (2017) In situ-forming polyamidoamine dendrimer hydrogels with tunable properties prepared via Aza–Michael addition reaction. ACS Appl Mater Interfaces 9:10494–10503CrossRefPubMedPubMedCentral

21.

Khademhosseini AM, Alhadrami HA, Hussain A, Aldhahri M, AlNowaiser F, Al-Hazmi FA, Oklug R (2016) Hydrogels 2.0: improved properties with nanomaterial composites for biomedical applications manuscript version: accepted manuscript. Biomed Mater 11:2–38

22.

Amariei G, Santiago-Morales J, Boltes K, Letón P, Iriepa I, Moraleda I, Fernández-Alba AR, Rosal R (2017) Dendrimer-functionalized electrospun nanofibres as dual-action water treatment membranes. Sci Total Environ 601–602:732–740CrossRefPubMed

23.

Amariei G, Boltes K, Letón P, Iriepa I, Moraleda I, Rosal R (2017) Poly(amidoamine) dendrimers grafted on electrospun poly(acrylic acid)/poly(vinyl alcohol) membranes for host-guest encapsulation of antioxidant thymol. J Mater Chem B 5:6776–6785CrossRefPubMed

24.

Luthar S, Cicchetti D, Becker B (2013) Hyperbranched polyester hydrogels with controlled drug release and cell adhesion properties. Biomacromol 14:1–22

25.

Desai PN, Yuan Q, Yang H (2010) Synthesis and characterization of photocurable polyamidoamine dendrimer hydrogels as a versatile platform for tissue engineering and drug delivery. Biomacromol 11:666–673CrossRef

26.

Taniguchi I, Kai T, Duan S, Kazama S, Jinnai H (2015) A compatible crosslinker for enhancement of CO₂ capture of poly(amidoamine) dendrimer-containing polymeric membranes. J Memb Sci 475:175–183CrossRef

27.

Duan S, Kai T, Saito T, Yamazaki K, Ikeda K (2014) Effect of cross-linking on the mechanical and thermal properties of poly(amidoamine) dendrimer/poly(vinyl alcohol) hybrid membranes for CO₂ separation. Membranes (Basel) 4:200–209CrossRefPubMed

28.

Hu D, Huang Y, Liu H, Wang H, Wang S, Shen M, Zhu M, Shi X (2014) The assembly of dendrimer-stabilized gold nanoparticles onto electrospun polymer nanofibers for catalytic applications. J Mater Chem A 2:2323–2332CrossRef

29.

Mousavi S, Shahraki F, Aliabadi M, Haji A, Deuber F, Adlhart C (2019) Nanofiber immobilized CeO₂/dendrimer nanoparticles: an efficient photocatalyst in the visible and the UV. Appl Surf Sci 479:608–618CrossRef

30.

He G, Zhu C, Ye S, Cai W, Yin Y, Zheng H, Yi Y (2016) Preparation and properties of novel hydrogel based on chitosan modified by poly(amidoamine) dendrimer. Int J Biol Macromol 91:828–837CrossRefPubMed

31.

Pawlaczyk M, Schroeder G (2020) Efficient removal of Ni(II) and Co(II) ions from aqueous solutions using silica-based hybrid materials functionalized with PAMAM dendrimers. Solvent Extr Ion Exch 38:496–521CrossRef

32.

Zhang Y, Chi H, Zhang W, Sun Y, Liang Q, Gu Y, Jing R (2014) Highly efficient adsorption of copper ions by a PVP-reduced graphene oxide based on a new adsorptions mechanism. Nano-Micro Lett 6:80–87CrossRef

33.

Long Zhao HM (2008) Adsorption of heavy metal ions from aqueous solution onto chitosan entrapped CM-cellulose hydrogels synthesized by irradiation. J Appl Polym Sci 110:1388–1395CrossRef

34.

Dai J, Yan H, Yang H, Cheng R (2010) Simple method for preparation of chitosan/poly(acrylic acid) blending hydrogel beads and adsorption of copper(II) from aqueous solutions. Chem Eng J 165:240–249CrossRef

Title: Influence of polyester dendrimers on swelling and adsorption of metal ion of PVA/PAA hydrogels
Authors: Rasha Elhodiry
Ali Elejmi
Wael Elhrari
Moftah Darwish
Zenab Abdoorhman
Publication date: 23-01-2023
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 12/2023
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-023-04692-x

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 12/2023

Improved synergistic effects among iron oxide, molybdenum disulfide, and multi-wall carbon nanotubes-based rubber composites for stretchable devices

An all-biomass adsorbent: competitive removal and correlative mechanism of Cu2+, Pb2+, Cd2+ from multi-element aqueous solutions

Preparation and properties of an antimicrobial silane-modified polyether sealant

Graphene-enhanced double-network ionogel electrolytes for energy storage and strain sensing

Nano TiO2-doped sodium alginate/hydroxypropyl methylcellulose synthesis of bionanocomposite membrane and its use in controlled release of anti-cancer drug 5-fluorouracil

Experimental investigation of absorption shielding efficiency of rubber composites

Premium Partners