Skip to main content
Top
Published in: Journal of Sol-Gel Science and Technology 2/2018

09-04-2018 | Original Paper: Sol-gel and hybrid materials for optical, photonic and optoelectronic applications

Influence of the spin acceleration time on the properties of ZnO:Ga thin films deposited by sol–gel method

Authors: M. Sbeta, A. Atilgan, A. Atli, A. Yildiz

Published in: Journal of Sol-Gel Science and Technology | Issue 2/2018

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

A detailed study of the structural, morphological, optical, and electrical properties of the spin-coated Ga-doped ZnO (GZO) films in which these properties are altered by varying the spin acceleration time (tacc) was undertaken. The results showed that, by varying tacc, there is no significant variation in crystal size, and band gap energy of the films, while some physical parameters such as strain \(\left( \varepsilon \right)\), surface roughness (RMS), and porosity (P) are remarkably varied. By increasing tacc from 0 to 8 s, \(\varepsilon\), RMS, and P, were increased by 230, 83, and 49%, respectively. Electrical data were presented to demonstrate unambiguously that the variation in the films resistivity (ρ) is closely connected to the change in these parameters. To explain these findings, a simple formula was proposed in the investigated range of tacc, which demonstrated that ρ is more related to \(\varepsilon\) and P, and then to RMS.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Serin T, Atilgan A, Kara I, Yildiz A (2017) Electron transport in Al-Cu co-doped ZnO thin films. J Appl Phys 121:095303CrossRef Serin T, Atilgan A, Kara I, Yildiz A (2017) Electron transport in Al-Cu co-doped ZnO thin films. J Appl Phys 121:095303CrossRef
2.
go back to reference Yildiz A, Uzun S, Serin N, Serin T (2016) Influence of grain boundaries on the figure of merit of undoped and Al, In, Sn doped ZnO thin films for photovoltaic applications. Scr Mater 113:23–26CrossRef Yildiz A, Uzun S, Serin N, Serin T (2016) Influence of grain boundaries on the figure of merit of undoped and Al, In, Sn doped ZnO thin films for photovoltaic applications. Scr Mater 113:23–26CrossRef
3.
go back to reference Tsay C-Y, Lee W-C (2013) Effect of dopants on the structural, optical and electrical properties of sol-gel derived ZnO semiconductor thin films. Curr Appl Phys 13:60–65CrossRef Tsay C-Y, Lee W-C (2013) Effect of dopants on the structural, optical and electrical properties of sol-gel derived ZnO semiconductor thin films. Curr Appl Phys 13:60–65CrossRef
4.
go back to reference Tsay C-Y, Wu C-W, Lei C-M, Chen F-S, Lin C-K (2010) Microstructural and optical properties of Ga-doped ZnO semiconductor thin films prepared by sol-gel process. Thin Solid Films 519:1516–1520CrossRef Tsay C-Y, Wu C-W, Lei C-M, Chen F-S, Lin C-K (2010) Microstructural and optical properties of Ga-doped ZnO semiconductor thin films prepared by sol-gel process. Thin Solid Films 519:1516–1520CrossRef
5.
go back to reference Cheong KY, Muti N, Ramanan SR (2002) Electrical and optical studies of ZnO:Ga thin films fabricated via the sol-gel technique. Thin Solid Films 410:142–146CrossRef Cheong KY, Muti N, Ramanan SR (2002) Electrical and optical studies of ZnO:Ga thin films fabricated via the sol-gel technique. Thin Solid Films 410:142–146CrossRef
6.
go back to reference Goncalve AS, Lima SAM, Davolos MR, Antonio SG, Paiva-Santos CO (2006) The effects of ZnGa2O4 formation on structural and optical properties of ZnO:Ga powders. J Solid State Chem 179:1330–1334CrossRef Goncalve AS, Lima SAM, Davolos MR, Antonio SG, Paiva-Santos CO (2006) The effects of ZnGa2O4 formation on structural and optical properties of ZnO:Ga powders. J Solid State Chem 179:1330–1334CrossRef
7.
go back to reference Chaitra U, Kekuda D, Rao KM (2017) Effect of annealing temperature on the evolution of structural, microstructural, and optical properties of spin coated ZnO thin films. Ceram Inter 43:7115–7122CrossRef Chaitra U, Kekuda D, Rao KM (2017) Effect of annealing temperature on the evolution of structural, microstructural, and optical properties of spin coated ZnO thin films. Ceram Inter 43:7115–7122CrossRef
8.
go back to reference Yildiz A, Cansizoglu H, Turkoz M, Abdulrahman R, Al-Hilo A, Cansizoglu MF, Demirkan TM, Karabacak T (2015) Glancing angle deposited Al-doped ZnO nanostructures with different structural and optical properties. Thin Solid Films 589:764–769CrossRef Yildiz A, Cansizoglu H, Turkoz M, Abdulrahman R, Al-Hilo A, Cansizoglu MF, Demirkan TM, Karabacak T (2015) Glancing angle deposited Al-doped ZnO nanostructures with different structural and optical properties. Thin Solid Films 589:764–769CrossRef
9.
go back to reference Wang F-H, Chang C-L (2016) Effect of substrate temperature on transparent conducting Al and F co-doped ZnO thin films prepared by rf magnetron sputtering. Appl Surf Sci 370:83–91CrossRef Wang F-H, Chang C-L (2016) Effect of substrate temperature on transparent conducting Al and F co-doped ZnO thin films prepared by rf magnetron sputtering. Appl Surf Sci 370:83–91CrossRef
10.
go back to reference Edalati K, Shakiba A, V-Khaki J, Zebarjad SM (2016) Low-temperature hydrothermal synthesis of ZnO nanorods: Effects of zinc salt concentration, various solvents and alkaline mineralizers. Mater Res Bull 74:374–379CrossRef Edalati K, Shakiba A, V-Khaki J, Zebarjad SM (2016) Low-temperature hydrothermal synthesis of ZnO nanorods: Effects of zinc salt concentration, various solvents and alkaline mineralizers. Mater Res Bull 74:374–379CrossRef
11.
go back to reference Patil SL, Chougule MA, Pawar SG, Raut BT, Sen S, Patil VB (2011) New process for synthesis of ZnO thin films: Microstructural, optical and electrical characterization. J Alloy Compd 509:10055–10061CrossRef Patil SL, Chougule MA, Pawar SG, Raut BT, Sen S, Patil VB (2011) New process for synthesis of ZnO thin films: Microstructural, optical and electrical characterization. J Alloy Compd 509:10055–10061CrossRef
12.
go back to reference Yildiz A, Cansizoglu H, Abdulrahman R, Karabacak T (2015) Effect of grain size and strain on the bandgap of glancing angle deposited AZO nanostructures. J Mater Sci Mater Electron 26:5952–5957CrossRef Yildiz A, Cansizoglu H, Abdulrahman R, Karabacak T (2015) Effect of grain size and strain on the bandgap of glancing angle deposited AZO nanostructures. J Mater Sci Mater Electron 26:5952–5957CrossRef
13.
go back to reference Tsay CY, Fan KS, Lei CM (2012) Synthesis and characterization of sol-gel derived gallium-doped zinc oxide thin films. J Alloy Compd 512:216–222CrossRef Tsay CY, Fan KS, Lei CM (2012) Synthesis and characterization of sol-gel derived gallium-doped zinc oxide thin films. J Alloy Compd 512:216–222CrossRef
14.
go back to reference Bandyopadhyay S, Paul GK, Roy R, Sen SK, Sen S (2002) Study of structural and electrical properties of grain-boundary modified ZnO films prepared by sol-gel technique. Mater Chem Phys 74:83–91CrossRef Bandyopadhyay S, Paul GK, Roy R, Sen SK, Sen S (2002) Study of structural and electrical properties of grain-boundary modified ZnO films prepared by sol-gel technique. Mater Chem Phys 74:83–91CrossRef
15.
go back to reference Farrag AA-G, Balboul MR (2017) Nano ZnO thin films synthesis by sol-gel spin coating method as a transparent layer for solar cell applications. J Sol-Gel Sci Technol 82:269–279CrossRef Farrag AA-G, Balboul MR (2017) Nano ZnO thin films synthesis by sol-gel spin coating method as a transparent layer for solar cell applications. J Sol-Gel Sci Technol 82:269–279CrossRef
16.
go back to reference Kaur G, Mitra A, Yadav KL (2015) Pulsed laser deposited Al-doped ZnO thin films for optical applications. Prog Nat Sci Mater Int 25:12–21CrossRef Kaur G, Mitra A, Yadav KL (2015) Pulsed laser deposited Al-doped ZnO thin films for optical applications. Prog Nat Sci Mater Int 25:12–21CrossRef
17.
go back to reference Swanepoel R (1983) Determination of the thickness and optical constants of amorphous silicon. J Phys E Sci Instrum 16:1214–1222CrossRef Swanepoel R (1983) Determination of the thickness and optical constants of amorphous silicon. J Phys E Sci Instrum 16:1214–1222CrossRef
18.
go back to reference Ramirez-Malo JB, Marquez E, Villares P, Jimenez-Garay R (1993) Refractive-index dispersion and optical-absorption edge of physically vapor-deposited films of the As35S65 chalcogenide glass. Mater Lett 17:327–332CrossRef Ramirez-Malo JB, Marquez E, Villares P, Jimenez-Garay R (1993) Refractive-index dispersion and optical-absorption edge of physically vapor-deposited films of the As35S65 chalcogenide glass. Mater Lett 17:327–332CrossRef
19.
go back to reference Atthi N, Nimittrakoolchai O, Jeamsaksiri W, Supothina S, Hruanun C, Poyai A (2009) Study of optimization condition for spin coating of the photoresist film on rectangular substrate by taguchi design of an experiment. J Sci Technol 31:331–335 Atthi N, Nimittrakoolchai O, Jeamsaksiri W, Supothina S, Hruanun C, Poyai A (2009) Study of optimization condition for spin coating of the photoresist film on rectangular substrate by taguchi design of an experiment. J Sci Technol 31:331–335
20.
go back to reference Kara I, Atilgan A, Serin T, Yildiz A (2017) Effects of Co and Cu dopants on the structural, optical, and electrical properties of ZnO nanocrystals. J Mater Sci Mater Electron 28:6088–6092CrossRef Kara I, Atilgan A, Serin T, Yildiz A (2017) Effects of Co and Cu dopants on the structural, optical, and electrical properties of ZnO nanocrystals. J Mater Sci Mater Electron 28:6088–6092CrossRef
21.
go back to reference Yildiz A, Ozturk E, Atilgan A, Sbeta M, Atli A, Serin T (2017) An understanding of the band gap shrinkage in Sn-doped ZnO for dye-sensitized solar cells. J Electron Mater 46(12):6739–6744CrossRef Yildiz A, Ozturk E, Atilgan A, Sbeta M, Atli A, Serin T (2017) An understanding of the band gap shrinkage in Sn-doped ZnO for dye-sensitized solar cells. J Electron Mater 46(12):6739–6744CrossRef
22.
go back to reference Smits FM (1958) Measurement of sheet resistivities with the four‐point probe. Bell Syst Tech J 37:711–718CrossRef Smits FM (1958) Measurement of sheet resistivities with the four‐point probe. Bell Syst Tech J 37:711–718CrossRef
23.
go back to reference Gordon RG (2000) Criteria for choosing transparent conductors. MRS Bull 25:52–57CrossRef Gordon RG (2000) Criteria for choosing transparent conductors. MRS Bull 25:52–57CrossRef
24.
go back to reference Ghosh R, Basak D, Fujihar S (2004) Effect of substrate-induced strain on the structural, electrical, and optical properties of polycrystalline ZnO thin films. J Appl Phys 96(5):2689–2692CrossRef Ghosh R, Basak D, Fujihar S (2004) Effect of substrate-induced strain on the structural, electrical, and optical properties of polycrystalline ZnO thin films. J Appl Phys 96(5):2689–2692CrossRef
25.
go back to reference Valle GG, Hammer P, Pulcinelli SH, Santilli CV (2004) Transparent and conductive ZnO:Al thin films prepared by sol-gel dip-coating. J Eur Ceram Soc 24:1009–1013CrossRef Valle GG, Hammer P, Pulcinelli SH, Santilli CV (2004) Transparent and conductive ZnO:Al thin films prepared by sol-gel dip-coating. J Eur Ceram Soc 24:1009–1013CrossRef
26.
go back to reference Ko H, Tai WP, Kim KC, Kim SH, Suh SJ, Y. Kim S (2005) Growth of Al-doped ZnO thin films by pulsed DC magnetron sputtering. J Cryst Growth 277:352–358CrossRef Ko H, Tai WP, Kim KC, Kim SH, Suh SJ, Y. Kim S (2005) Growth of Al-doped ZnO thin films by pulsed DC magnetron sputtering. J Cryst Growth 277:352–358CrossRef
Metadata
Title
Influence of the spin acceleration time on the properties of ZnO:Ga thin films deposited by sol–gel method
Authors
M. Sbeta
A. Atilgan
A. Atli
A. Yildiz
Publication date
09-04-2018
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 2/2018
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-018-4652-8

Other articles of this Issue 2/2018

Journal of Sol-Gel Science and Technology 2/2018 Go to the issue

Original Paper: Industrial and technological applications of sol-gel and hybrid materials

Processing and properties of sintered submicron IR transparent alumina derived through sol–gel method

Original Paper: Sol-gel and hybrid materials for energy, environment and building applications

Optical, mechanical and electrical properties of LSCF–SDC composite cathode prepared by sol–gel assisted rotary evaporation technique

Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

Investigation of electrocatalytic activity of nanostructure Ce-doped MnO x sol–gel coating deposited on porous Ti membrane electrode

Invited Paper: Nano- and macroporous materials (aerogels, xerogels, cryogels, etc.)

Rapid fabrication of hybrid aerogels and 3D printed porous materials

Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

Preparation of mesoporous crack-free Sb-SnO2 xerogels through ambient-pressure drying and its application as three-dimensional electrode

Premium Partners