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Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 2/2018

09-04-2018 | Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

Investigation of electrocatalytic activity of nanostructure Ce-doped MnO x sol–gel coating deposited on porous Ti membrane electrode

Authors: Di Zhang, Xiaoping Liang, Shanmin Yang, Zishang Chen, Huan Wang, Yu Feng, Hong Wang, Jianxin Li

Published in: Journal of Sol-Gel Science and Technology | Issue 2/2018

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Abstract

Ce-doped MnOx/Ti electrocatalytic membrane electrodes were prepared by doping rare earth element Ce into manganese oxide (MnOx) via sol–gel method, and coated on the porous Ti substrate membrane electrode. In order to evaluate electrocatalytic activity of the Ce–MnOx/Ti electrode, a functional electrocatalytic membrane reactor (ECMR), which assembled a Ce–MnOx/Ti electrode as an anode and a stainless steel mesh as a cathode, has been employed for phenolic wastewater treatment. The results revealed that a new crystal form Ce2O3 appeared after doping Ce into the system, and the urchinlike morphology and smaller grain size of Ce–MnOx led the catalytic activity of the composite membrane electrode to improve. Moreover, the 25 mol% Ce–MnOx/Ti (C25MT) composite membrane electrode represented the best activity in the degradation of phenolic wastewater. During ECMR with C25MT operation under the conditions of 450 mg/L phenolic wastewater (500 mL), residence time of 5 min, pH of 1–13 and current density of 0.3–1.2 mA/cm2, the highest degradation efficiency of phenolic wastewater achieved in current density of 0.9 mA/cm2 and pH of 7, that is, the achieved remove rate of phenol, COD and TOC were 99.61, 93.12, and 84.23%, respectively. Finally, the effective reusability of C25MT composite membrane electrode was assessed, and a proposed reaction mechanism has been analyzed in the ECMR operation.
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Metadata
Title
Investigation of electrocatalytic activity of nanostructure Ce-doped MnO x sol–gel coating deposited on porous Ti membrane electrode
Authors
Di Zhang
Xiaoping Liang
Shanmin Yang
Zishang Chen
Huan Wang
Yu Feng
Hong Wang
Jianxin Li
Publication date
09-04-2018
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 2/2018
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-018-4620-3

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