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30-04-2022 | Original Research

Inspired by sodium alginate: Amino acids cooperating with sodium ions to prepare phosphorus-free flame retardant lyocell fabric

Authors: Yansong Liu, Wenjing Zhao, Jiayue Zhang, Yuanlin Ren, Xiaohui Liu, Hongqiang Qu

Published in: Cellulose | Issue 9/2022

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Abstract

Inspired by the intrinsically flame-retardant alginate fiber, a novel eco-friendly, biomass-based flame retardant was developed to endow lyocell fabrics with excellent flame-retardant properties by using bio-material glycine, aspartic acid as raw materials. Furthermore, glycine and aspartic acid were converted into sodium carboxylate (glycine-Na and aspartate-Na), respectively. Then, lyocell fabric was respectively modified by glycine-Na and aspartic acid-Na to prepare flame retardant lyocell fabric (G-lyocell-Na and A-lyocell-Na). The combustion test result showed that the modified fabrics exhibited self-extinguishing characteristics and high char-forming ability. In addition, compared to the control sample, the peak of heat release rate (PHRR) of G-lyocell-Na and A-lyocell-Na reduced by 36.5% and 49.9%. TG-IR and Raman spectra results indicated that both the condensed and gas phase played the flame retardant role. The electron withdrawing effect of the Na⁺ reduced the activation energy, promoted the pyran ring-opening reaction and reduced the decomposition temperature. Therefore, the flame retardant lyocell fabric decomposed and formed more char residue containing Na₂CO₃. The expanded char layer formed during combustion could effectively block the release of heat and the overflow of combustible gases, so that the modified lyocell fabric showed highly flame-retardant efficiency. In this work, a novel preparation strategy that can endow lyocell fabric with good flame retardant properties without traditional flame retardant elements such as P, Cl and Br was proposed, which was green, environment-friendly and in line with sustainable development.

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Title: Inspired by sodium alginate: Amino acids cooperating with sodium ions to prepare phosphorus-free flame retardant lyocell fabric
Authors: Yansong Liu
Wenjing Zhao
Jiayue Zhang
Yuanlin Ren
Xiaohui Liu
Hongqiang Qu
Publication date: 30-04-2022
Publisher: Springer Netherlands
Published in: Cellulose / Issue 9/2022
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-022-04596-5

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