Skip to main content
Top
Published in: Journal of Coatings Technology and Research 4/2011

01-07-2011

Investigating the antigraffiti properties of a polyurethane clearcoat containing a silicone polyacrylate additive

Authors: A. Mohammad Rabea, M. Mohseni, S. M. Mirabedini

Published in: Journal of Coatings Technology and Research | Issue 4/2011

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

In this study, a polyurethane clearcoat was modified using a silicone polyacrylate antigraffiti additive and its surface free energy and mechanical properties were evaluated by various analytical techniques. The results showed that surface free energy decreased by replacing the polyol resin with the additive up to 10 mol%. Dynamic mechanical thermal analysis (DMTA) showed that the presence of the additive increased the storage modulus of the samples at ambient temperature. Evaluation of stainability of the coatings containing the additive revealed that a spray paint would be repelled from the surface showing a proper antigraffiti behavior. The additive did not affect the surface roughness of the films, indicating that the antigraffiti properties resulted from changes in surface chemistry due to migration of the additive to the surface.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Maty, J, “Anti-Grafitti Coatings: Taking Aim Against Tagging.” J. Arch. Coat., 4 18–26 (2007) Maty, J, “Anti-Grafitti Coatings: Taking Aim Against Tagging.” J. Arch. Coat., 4 18–26 (2007)
2.
go back to reference Zielink, A, “Durability: Rules of the Grafitti Game.” J. Arch. Coat., 4 29–34 (2007) Zielink, A, “Durability: Rules of the Grafitti Game.” J. Arch. Coat., 4 29–34 (2007)
3.
go back to reference Scheerder, J, Visscher, N, Nabuurs, T, Overbeek, A, “Novel, Water-Based Fluorinated Polymers With Excellent Antigraffiti Properties.” JCT Res., 2 617–625 (2005) Scheerder, J, Visscher, N, Nabuurs, T, Overbeek, A, “Novel, Water-Based Fluorinated Polymers With Excellent Antigraffiti Properties.” JCT Res., 2 617–625 (2005)
4.
go back to reference Tarnowski, A, Zhang, X, McNamara, C, Martin, ST, Mitchell, R, “Biodeterioration and Performance of Anti-Graffiti Coatings on Sandstone and Marble.” J. ACCR, 32 3–16 (2007) Tarnowski, A, Zhang, X, McNamara, C, Martin, ST, Mitchell, R, “Biodeterioration and Performance of Anti-Graffiti Coatings on Sandstone and Marble.” J. ACCR, 32 3–16 (2007)
5.
go back to reference Wu, X, Rosen, RP, “Development of Low-VOC 2K Waterborne Polyurethane Anti-Graffit Coatings.” JCT Coatings Tech., 5 66–72 (2008) Wu, X, Rosen, RP, “Development of Low-VOC 2K Waterborne Polyurethane Anti-Graffit Coatings.” JCT Coatings Tech., 5 66–72 (2008)
6.
go back to reference Graiver, D, Farminer, KW, Narayan, R, “A Review of the Fate and Effects of Silicones in the Environment.” J. Polym. Environ., 11 129–136 (2003)CrossRef Graiver, D, Farminer, KW, Narayan, R, “A Review of the Fate and Effects of Silicones in the Environment.” J. Polym. Environ., 11 129–136 (2003)CrossRef
7.
go back to reference Feng, L, Zhang, X, Dai, J, Ge, Z, Chao, J, Bai, C, “Synthesis and Surface Properties of Polyurethane Modified by Polysiloxane.” Front. Chem. China, 3 1–5 (2008)CrossRef Feng, L, Zhang, X, Dai, J, Ge, Z, Chao, J, Bai, C, “Synthesis and Surface Properties of Polyurethane Modified by Polysiloxane.” Front. Chem. China, 3 1–5 (2008)CrossRef
8.
go back to reference Adamson, AW, Physical Chemistry of Surfaces. Wiley, New York (1990) Adamson, AW, Physical Chemistry of Surfaces. Wiley, New York (1990)
9.
go back to reference Hikita, M, Tanaka, K, Nakamura, T, Kajiyama, T, Takahara, A, “Super-Liquid-Repellent Surfaces Prepared by Colloidal Silica Nanoparticles Covered With Fluoroalkyl Groups.” Langmuir, 21 7299–7302 (2005)CrossRef Hikita, M, Tanaka, K, Nakamura, T, Kajiyama, T, Takahara, A, “Super-Liquid-Repellent Surfaces Prepared by Colloidal Silica Nanoparticles Covered With Fluoroalkyl Groups.” Langmuir, 21 7299–7302 (2005)CrossRef
10.
go back to reference Wu, W, Nancollas, GH, “Determination of Interfacial Tension from Crystallization and Dissolution Data: A Comparison with Other Methods.” Adv. Colloid Interface Sci., 79 229–279 (1999)CrossRef Wu, W, Nancollas, GH, “Determination of Interfacial Tension from Crystallization and Dissolution Data: A Comparison with Other Methods.” Adv. Colloid Interface Sci., 79 229–279 (1999)CrossRef
11.
go back to reference Tyagi, D, Yilgor, I, McGrath, JE, Wilkes, GL, “Segmented Organosiloxane Copolymers: 2 Thermal and Mechanical Properties of Siloxane–Urea Copolymers.” Polymer, 25 1807–1816 (1984)CrossRef Tyagi, D, Yilgor, I, McGrath, JE, Wilkes, GL, “Segmented Organosiloxane Copolymers: 2 Thermal and Mechanical Properties of Siloxane–Urea Copolymers.” Polymer, 25 1807–1816 (1984)CrossRef
12.
go back to reference Majumdar, P, Webster, DC, “Surface Microtopography in Siloxaneepolyurethane Thermosets: The Influence of Siloxane and Extent of Reaction.” Polymer, 48 7499–7509 (2007)CrossRef Majumdar, P, Webster, DC, “Surface Microtopography in Siloxaneepolyurethane Thermosets: The Influence of Siloxane and Extent of Reaction.” Polymer, 48 7499–7509 (2007)CrossRef
13.
go back to reference Majumdar, P, Webster, DC, “Preparation of Siloxane-Urethane Coatings Having Spontaneously Formed Stable Biphasic Microtopograpical Surfaces.” Macromolecules, 38 5857–5859 (2005)CrossRef Majumdar, P, Webster, DC, “Preparation of Siloxane-Urethane Coatings Having Spontaneously Formed Stable Biphasic Microtopograpical Surfaces.” Macromolecules, 38 5857–5859 (2005)CrossRef
14.
go back to reference Pu, Z, Mark, JE, Li, Z, Zhu, J, “Some Block Copolymers Illustrating the Effects of Siloxane and Silane Units on the Properties of Terephthalate–Glycol Thermoplastics.” Polymer, 40 4695–4701 (1999)CrossRef Pu, Z, Mark, JE, Li, Z, Zhu, J, “Some Block Copolymers Illustrating the Effects of Siloxane and Silane Units on the Properties of Terephthalate–Glycol Thermoplastics.” Polymer, 40 4695–4701 (1999)CrossRef
15.
go back to reference Wenzel, RN, “Resistance of Solid Surfaces to Wetting by Water.” Ind. Eng. Chem., 28 988–994 (1936)CrossRef Wenzel, RN, “Resistance of Solid Surfaces to Wetting by Water.” Ind. Eng. Chem., 28 988–994 (1936)CrossRef
Metadata
Title
Investigating the antigraffiti properties of a polyurethane clearcoat containing a silicone polyacrylate additive
Authors
A. Mohammad Rabea
M. Mohseni
S. M. Mirabedini
Publication date
01-07-2011
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 4/2011
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-011-9324-3

Other articles of this Issue 4/2011

Journal of Coatings Technology and Research 4/2011 Go to the issue

Premium Partners