Skip to main content
Top
Published in: Journal of Nanoparticle Research 11/2014

01-11-2014 | Research Paper

Iron(III) phthalocyanine/BiPO4 heterostructured nanofibers: controllable fabrication and visible photocatalytic properties investigation

Authors: Guoshuai Liu, Suwen Liu, Qifang Lu, Haiyan Sun, Zhiliang Xiu

Published in: Journal of Nanoparticle Research | Issue 11/2014

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Iron(III) Phthalocyanine/BiPO4 (FePc/BiPO4) heterostructures were successfully synthesized by electrospinning combined solvothermal routes. The prepared samples were characterized by scanning electron microscopy, X-ray diffraction, UV–Vis diffuse reflectance spectroscopy, high-resolution transmission electron microscopy, photoluminescence spectroscopy, and electrochemical measurement. The samples are well-defined hierarchical nanostructures, and its absorption was extended to the near-infrared region. The photocatalytic activities of the FePc/BiPO4 photocatalysts were evaluated by the decomposition of methylene blue under visible light irradiation (λ ≥ 400 nm). The FePc/BiPO4 heterostructures showed excellent visible light photocatalytic performances. The electrochemical measurement was also performed and the effect of the hierarchical nanostructures on the photocatalytic activities was also discussed.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Appendix
Available only for authorised users
Literature
go back to reference Arunkumar P, Jayajothi C, Jeyakumar D, Lakshminarasimhan N (2012) Structure–property relations in hexagonal and monoclinic BiPO4:Eu3+ nanoparticles synthesized by polyol-mediated method. RSC Adv 2:1477–1485. doi:10.1039/C1RA00389E CrossRef Arunkumar P, Jayajothi C, Jeyakumar D, Lakshminarasimhan N (2012) Structure–property relations in hexagonal and monoclinic BiPO4:Eu3+ nanoparticles synthesized by polyol-mediated method. RSC Adv 2:1477–1485. doi:10.​1039/​C1RA00389E CrossRef
go back to reference Carey JH, Lawrence J, Tosine HM (1976) Photodechlorination of PCB’s in the presence of titanium dioxide in aqueous suspensions. Bull Environ Contam Toxicol 16:697–701. doi:10.1007/BF01685575 CrossRef Carey JH, Lawrence J, Tosine HM (1976) Photodechlorination of PCB’s in the presence of titanium dioxide in aqueous suspensions. Bull Environ Contam Toxicol 16:697–701. doi:10.​1007/​BF01685575 CrossRef
go back to reference Chen W, Lu W, Yao Y, Xu M (2007) Highly efficient decomposition of organic dyes by aqueous-fiber phase transfer and in situ catalytic oxidation using fiber-supported cobalt phthalocyanine. Environ Sci Technol 41:6240–6245. doi:10.1021/es070002k CrossRef Chen W, Lu W, Yao Y, Xu M (2007) Highly efficient decomposition of organic dyes by aqueous-fiber phase transfer and in situ catalytic oxidation using fiber-supported cobalt phthalocyanine. Environ Sci Technol 41:6240–6245. doi:10.​1021/​es070002k CrossRef
go back to reference Cheng P, Zhu Y (2010) New type of BiPO4 oxy-acid salt photocatalyst with high photocatalytic activity on degradation of dye. Environ Sci Technol 44:5570–5574. doi:10.1021/es101223n CrossRef Cheng P, Zhu Y (2010) New type of BiPO4 oxy-acid salt photocatalyst with high photocatalytic activity on degradation of dye. Environ Sci Technol 44:5570–5574. doi:10.​1021/​es101223n CrossRef
go back to reference Geng J, Hou WH, Lv YN, Zhu JJ, Chen HY (2005) One-dimensional BiPO4 nanorods and two-dimensional BiOCl lamellae: fast low-temperature sonochemical synthesis, characterization, and growth mechanism. Inorg Chem 44:8503–8509. doi:10.1021/ic050674g CrossRef Geng J, Hou WH, Lv YN, Zhu JJ, Chen HY (2005) One-dimensional BiPO4 nanorods and two-dimensional BiOCl lamellae: fast low-temperature sonochemical synthesis, characterization, and growth mechanism. Inorg Chem 44:8503–8509. doi:10.​1021/​ic050674g CrossRef
go back to reference He J, Hagfeldt A, Lindquist SE, Grennberg H, Korodi F, Sun L, Åkermark B (2001) Phthalocyanine-sensitized nanostructured TiO2 electrodes prepared by a novel anchoring method. Langmuir 17:2743–2747. doi:10.1021/la001651b CrossRef He J, Hagfeldt A, Lindquist SE, Grennberg H, Korodi F, Sun L, Åkermark B (2001) Phthalocyanine-sensitized nanostructured TiO2 electrodes prepared by a novel anchoring method. Langmuir 17:2743–2747. doi:10.​1021/​la001651b CrossRef
go back to reference Li J, Zhang X, Ai Z, Jia F, Zhang L, Lin J (2007) Efficient visible light degradation of rhodamine B by a photo-electrochemical process based on a Bi2WO6 nanoplate film electrode. J Phys Chem C 111:6832–6836. doi:10.1021/jp070694z CrossRef Li J, Zhang X, Ai Z, Jia F, Zhang L, Lin J (2007) Efficient visible light degradation of rhodamine B by a photo-electrochemical process based on a Bi2WO6 nanoplate film electrode. J Phys Chem C 111:6832–6836. doi:10.​1021/​jp070694z CrossRef
go back to reference Liu G, Liu S, Lu Q, Sun H, Xiu Z (2014) Synthesis of mesoporous BiPO4 nanofibers by electrospinning with enhanced photocatalytic performances. Ind Eng Chem Res 53:13023–13029. doi:10.1021/ie4044357 CrossRef Liu G, Liu S, Lu Q, Sun H, Xiu Z (2014) Synthesis of mesoporous BiPO4 nanofibers by electrospinning with enhanced photocatalytic performances. Ind Eng Chem Res 53:13023–13029. doi:10.​1021/​ie4044357 CrossRef
go back to reference Mills G, Hoffmann MR (1993) Photocatalytic degradation of pentachlorophenol on titanium dioxide particles: identification of intermediates and mechanism of reaction. Environ Sci Technol 27:1681–1689. doi:10.1021/es00045a027 CrossRef Mills G, Hoffmann MR (1993) Photocatalytic degradation of pentachlorophenol on titanium dioxide particles: identification of intermediates and mechanism of reaction. Environ Sci Technol 27:1681–1689. doi:10.​1021/​es00045a027 CrossRef
go back to reference Nimlos MR, Jacoby WA, Blake DM (1993) Direct mass spectrometric studies of the destruction of hazardous wastes. 2. Gas-phase photocatalytic oxidation of trichloroethylene over titanium oxide: products and mechanisms. Environ Sci Technol 27:732–740. doi:10.1021/es00041a018 CrossRef Nimlos MR, Jacoby WA, Blake DM (1993) Direct mass spectrometric studies of the destruction of hazardous wastes. 2. Gas-phase photocatalytic oxidation of trichloroethylene over titanium oxide: products and mechanisms. Environ Sci Technol 27:732–740. doi:10.​1021/​es00041a018 CrossRef
go back to reference Nykong T, Gasyna Z, Stillman MJ (1987) Analysis of the absorption and magnetic circular dichroism spectra of zinc phthalocyanine and the.pi.-cation-radical species [ZnPc(1−)].cntdot.+. Inorg Chem 26:1087–1095. doi:10.1021/ic00254a025 CrossRef Nykong T, Gasyna Z, Stillman MJ (1987) Analysis of the absorption and magnetic circular dichroism spectra of zinc phthalocyanine and the.pi.-cation-radical species [ZnPc(1−)].cntdot.+. Inorg Chem 26:1087–1095. doi:10.​1021/​ic00254a025 CrossRef
go back to reference Ogisu K, Ishikawa A, Shimodaira Y, Takata T, Kobayashi H, Domen K (2008) Electronic band structures and photochemical properties of La-Ga-based oxysulfides. J Phys Chem C 112:11978–11984. doi:10.1021/jp802153t CrossRef Ogisu K, Ishikawa A, Shimodaira Y, Takata T, Kobayashi H, Domen K (2008) Electronic band structures and photochemical properties of La-Ga-based oxysulfides. J Phys Chem C 112:11978–11984. doi:10.​1021/​jp802153t CrossRef
go back to reference Park HS, Kweon KE, Ye H, Paek E, Hwang GS, Bard AJ (2011) Factors in the metal doping of BiVO4 for improved photoelectrocatalytic activity as studied by scanning electrochemical microscopy and first-principles density-functional calculation. J Phys Chem C 115:17870–17879. doi:10.1021/jp204492r CrossRef Park HS, Kweon KE, Ye H, Paek E, Hwang GS, Bard AJ (2011) Factors in the metal doping of BiVO4 for improved photoelectrocatalytic activity as studied by scanning electrochemical microscopy and first-principles density-functional calculation. J Phys Chem C 115:17870–17879. doi:10.​1021/​jp204492r CrossRef
go back to reference Ranjit KT, Willner I, Bossmann SH, Braun AM (2001) Lanthanide oxide-doped titanium dioxide photocatalysts: novel photocatalysts for the enhanced degradation of p-chlorophenoxyacetic acid. Environ Sci Technol 35:1544–1549. doi:10.1021/es001613e CrossRef Ranjit KT, Willner I, Bossmann SH, Braun AM (2001) Lanthanide oxide-doped titanium dioxide photocatalysts: novel photocatalysts for the enhanced degradation of p-chlorophenoxyacetic acid. Environ Sci Technol 35:1544–1549. doi:10.​1021/​es001613e CrossRef
go back to reference Sayama K, Nomura A, Zou ZG, Abe R, Abe Y, Arakawa H (2003) Photoelectrochemical decomposition of water on nanocrystalline BiVO4 film electrodes under visible light. Chem Commun 23:2908–2909. doi:10.1039/B310428A CrossRef Sayama K, Nomura A, Zou ZG, Abe R, Abe Y, Arakawa H (2003) Photoelectrochemical decomposition of water on nanocrystalline BiVO4 film electrodes under visible light. Chem Commun 23:2908–2909. doi:10.​1039/​B310428A CrossRef
go back to reference Tokunaga S, Kato H, Kudo A (2001) Selective preparation of monoclinic and tetragonal BiVO4 with scheelite structure and their photocatalytic properties. Chem Mater 13:4624–4628. doi:10.1021/cm0103390 CrossRef Tokunaga S, Kato H, Kudo A (2001) Selective preparation of monoclinic and tetragonal BiVO4 with scheelite structure and their photocatalytic properties. Chem Mater 13:4624–4628. doi:10.​1021/​cm0103390 CrossRef
go back to reference VanCott TC, Rose JL, Misener GC, Williamson BE, Schrimpf AE, Boyle ME, Schatz PN (1989) Magnetic circular dichroism and absorption spectrum of zinc phthalocyanine in an argon matrix between 14,700 and 74,000 cm−1. J Phys Chem 93:2999–3011. doi:10.1021/j100345a028 CrossRef VanCott TC, Rose JL, Misener GC, Williamson BE, Schrimpf AE, Boyle ME, Schatz PN (1989) Magnetic circular dichroism and absorption spectrum of zinc phthalocyanine in an argon matrix between 14,700 and 74,000 cm−1. J Phys Chem 93:2999–3011. doi:10.​1021/​j100345a028 CrossRef
go back to reference Xu H, Xu Y, Li H, Xia J, Xiong J, Yin S, Huang C, Wan H (2012) Synthesis, characterization and photocatalytic property of AgBr/BiPO4 heterojunction photocatalyst. Dalton Trans 41:3387–3394. doi:10.1039/C2DT11969B CrossRef Xu H, Xu Y, Li H, Xia J, Xiong J, Yin S, Huang C, Wan H (2012) Synthesis, characterization and photocatalytic property of AgBr/BiPO4 heterojunction photocatalyst. Dalton Trans 41:3387–3394. doi:10.​1039/​C2DT11969B CrossRef
go back to reference Xue F, Li HB, Zhu YC, Xiong SL, Zhang XW, Wang TT, Liang X, Qian YT (2009) Solvothermal synthesis and photoluminescence properties of BiPO4 nano-cocoons and nanorods with different phases. J Solid State Chem 182:1396–1400. doi:10.1016/j.jssc.2009.02.031 CrossRef Xue F, Li HB, Zhu YC, Xiong SL, Zhang XW, Wang TT, Liang X, Qian YT (2009) Solvothermal synthesis and photoluminescence properties of BiPO4 nano-cocoons and nanorods with different phases. J Solid State Chem 182:1396–1400. doi:10.​1016/​j.​jssc.​2009.​02.​031 CrossRef
go back to reference Zhang M, Shao C, Guo Z, Zhang Z, Mu J, Cao T, Liu Y (2011) Hierarchical nanostructures of copper(II) phthalocyanine on electrospun TiO2 nanofibers: controllable solvothermal-fabrication and enhanced visible photocatalytic properties. ACS Appl Mater Interfaces 3:369–377. doi:10.1021/am100989a CrossRef Zhang M, Shao C, Guo Z, Zhang Z, Mu J, Cao T, Liu Y (2011) Hierarchical nanostructures of copper(II) phthalocyanine on electrospun TiO2 nanofibers: controllable solvothermal-fabrication and enhanced visible photocatalytic properties. ACS Appl Mater Interfaces 3:369–377. doi:10.​1021/​am100989a CrossRef
Metadata
Title
Iron(III) phthalocyanine/BiPO4 heterostructured nanofibers: controllable fabrication and visible photocatalytic properties investigation
Authors
Guoshuai Liu
Suwen Liu
Qifang Lu
Haiyan Sun
Zhiliang Xiu
Publication date
01-11-2014
Publisher
Springer Netherlands
Published in
Journal of Nanoparticle Research / Issue 11/2014
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-014-2685-7

Other articles of this Issue 11/2014

Journal of Nanoparticle Research 11/2014 Go to the issue

Premium Partners