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Polymer Bulletin
Published in: Polymer Bulletin 2/2012

01-01-2012 | Original Paper

Kinetic study of 2-acrylamido-2-methylpropanesulfonic acid in free-radical polymerization method by differential scanning calorimetry

Authors: E. Nadim, H. Bouhendi, F. Ziaee, R. Bazhrang

Published in: Polymer Bulletin | Issue 2/2012

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Abstract

Aqueous free-radical polymerization of 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS) in the presence of potassium persulfate (KPS) as thermal initiator was studied by differential scanning calorimetry (DSC). Effect of temperature, monomer, and initiator concentration on polymerization rate was studied. Obtained recorded data represented order of reaction with respect to monomer greater than unity (1.56). Among the theories presented order of reaction more than one, the gage effect theory in the range of monomer concentration (0.966–2.410 mol/L) had a good agreement with mechanism of AMPS polymerization. The order with respect to KPS was 0.52 which was consistent with classical kinetic theory. Calculated amount of activation energy in overall rate of reaction was 83 kJ/mol K.
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Literature
1.
Mahdavian AR, Abdollahi M, Bijanzadeh HR (2004) Kinetic study of radical polymerization. III. Solution polymerization of acrylamide by 1H-NMR. J Appl Polym Sci 93:2007–2013CrossRef
2.
Williams PA (2007) In: Handbook of industrial water soluble polymers. Blackwell, Oxford
3.
Rintoul I, Wandrey C (2005) Polymerization of ionic monomers in polar solvents: kinetics and mechanism of free radical copolymerization of acrylamide/acrylic acid. Polymer 46:4525–4532CrossRef
4.
Cutie SS, Smith PB, Henton DE, Staples TL, Powell C (1997) Acrylic acid polymerization kinetics. J Polym Sci Part B Polym Phys 35:2029–2047CrossRef
5.
Gor Alberda, Ekenstein V, Tan Yy (1981) A differential scanning calorimetric study of the radical polymerization of N-vinylpyrolidone in dimethyl formamide. Eur Polym J 17:839–843CrossRef
6.
Verneker VRP, Vasanthakumari R (1983) Solid-state thermal polymerization of sodium acrylate. J Poly Sci Part A Polym Chem 21:1657–1664
7.
Adler G, Ballantine D, Baysal B (1960) The mechanism of free radical polymerization in solid state. J Poly Sci 48:195–206CrossRef
8.
Kishore K, Santhanalakshmi KN (1981) Thermal polymerization of acrylamide by differential scanning calorimetry. J Poly Sci Part A Polym Chem 19:2367
9.
Mahdavian A-R, Zandi M (2003) Kinetic study of radical polymerization. II Solid-state bulk polymerization of sodium methacrylate by differential scanning calorimetry. J Appl Polym Sci 90:1648CrossRef
10.
Kolthoff IM, Medalia AI, Raeen HP (1951) The reaction between Ferrous Iron and Peroxides. IV. Reaction with Potassium persulfate. J Am Chem Soc 73:1733CrossRef
11.
12.
Odian G (ed) (2004) Principles of polymerization, 4th edn. Academic Press, New York
Metadata
Title
Kinetic study of 2-acrylamido-2-methylpropanesulfonic acid in free-radical polymerization method by differential scanning calorimetry
Authors
E. Nadim
H. Bouhendi
F. Ziaee
R. Bazhrang
Publication date
01-01-2012
Publisher
Springer-Verlag
Published in
Polymer Bulletin / Issue 2/2012
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-011-0552-6

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