Top

Rheologica Acta

Published in:

01-09-2012 | Original Contribution

Linear viscoelasticity of ZrO₂ nanoparticle dispersions with associative polymers

Authors: Rose S. Ndong, William B. Russel

Published in: Rheologica Acta | Issue 9/2012

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

ZrO₂ nanoparticle dispersions containing associative polymers exhibit two relaxation modes: Maxwellian behavior at high frequency imparted by the associating polymers and a power law spectrum at low frequency generated by the particle dynamics. The timescales and volume fraction dependence of the dispersions reflect weak attractions between particles with adsorbed polymer layers dispersed in a percolated network of associative polymer. The Baxter stickiness parameter extracted from the high frequency viscosity data indicates strong attractions, whereas the high frequency modulus reveals three sources of elasticity: micelle–micelle associations in the solution, rigidity of the particles and adsorbed layer, and adsorbed layer–adsorbed layer interactions. The sol-gel transition of the dispersions occurs around 12–14% particle loading. Comparison with latex dispersions suggests a slower relaxation mode and greater rigidity with the ZrO₂ particles.

next article On the viscoelastic characterization of the Jeffreys–Lomnitz law of creep

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Agrawal SK, Sanabria-DeLong N, Tew GN, Bhatia SR (2008) Nanoparticle-reinforced associative network hydrogels. Langmuir 24:13,148–13,154

Alami E, Almgren M, Brown W, Francois J (1996) Aggregation of hydrophobically end-capped poly(ethylene oxide) in aqueous solutions. Fluorescence and light-scattering studies. Macromolecules 29:2229–2243

Annable T, Buscall R, Ettelaie R, Whittlestone D (1993) The rheology of solutions of associating polymers: comparison of experimental behavior with transient network theory. J Rheol 37:695–726CrossRef

Aubry T, Bossard F, Moan M (2002) Laponite dispersions in the presence of an associative polymer. Langmuir 18:155–159CrossRef

Batchelor G, Green J (1972) The determination of the bulk stress in a suspension of spherical particles to order c ². J Fluid Mech 56:401–427CrossRef

Baumgaertel M, A Schausberger A, Winter H (1990) The relaxation of polymers with linear flexible chains of uniform length. Rheol Acta 29:400–408CrossRef

Baxter RJ (1968) Percus-Yevick equation for hard spheres with surface adhesion. J Chem Phys 63:2770–2774CrossRef

Bergenholtz J, Brady J, Vicic M (2002) The non-newtonian rheology of dilute colloidal suspensions. J Fluid Mech 456:239–275CrossRef

Bergstrom L (1997) Hamaker constants of inorganic materials. Adv Colloid Interface Sci 70:125–169CrossRef

Buscall R, McGowan JI, Morton-Jones AJ (1993) The rheology of concentrated dispersions of weakly attracting colloidal particles with and without wall slip. J Rheol 37:621–641CrossRef

Cicchocki B, Felderhof B (1990) Diffusion coefficients and effective viscosity of suspensions of sticky hard spheres with hydrodynamic interactions. J Chem Phys 93(6):4427CrossRef

Einstein A (1905) On the motion of small particles suspended in a stationary liquid, as required by the molecular kinetic theory of heat. Ann Phys 17:549–560CrossRef

English RJ, Gulati HS, Jenkins RD, Khan S (1997) Solution rheology of a hydrophobically modified alkali-soluble associative polymer. J Rheol 41:427–444CrossRef

Fonnum G, Bakke J, Hansen FK (1993) Associative thickeners. part i: synthesis, rheology and aggregation behavior. Colloid and Polymer Science 271:380–389CrossRef

Glass J (1989) Polymers in aqueous media: performance through association. American Chemical Society, Washington, DC, USACrossRef

Green MS, Tobolsky AV (1946) A new approach to the theory of relaxing polymeric media. J Chem Phys 14:80–92CrossRef

Huang Y, Santore MM (2002) Dynamics in adsorbed layers of associative polymers in the limit of strong backbone-surface attractions. Langmuir 18:2158–2165CrossRef

Hulden M (1994) Hydrophobically modified urethane–ethoxylate (heur) associative thickeners 2. interaction with latex. Colloids and Surfaces A: Physicochemical and Engineering Aspects 88:207–221CrossRef

Isa L, Besseling R, Poon WCK (2007) Shear zones and wall slip in the capillary flow of concentrated colloidal suspensions. Phys Rev Lett 98:1983–1905CrossRef

Jenkins R (1990) The fundamental thickening mechanism of associative polymers in latex systems: a rheological study. PhD thesis, Lehigh University

Jenkins RD, Silebi CA, El-Aasser MS (1989) Steady shear and linear viscoelastic material properties of associative thickener solutions. Polymeric Materials Science and Engineering 61:629–633

Kamibayashi M, Ogura H, Otsubo Y (2006) Rheological behavior of suspensions of silica nanoparticles in associating polymer solutions. Ind Eng Chem Res 45:6899–6905CrossRef

Koleske JV (1995) Paint and coating testing manual. 14 Sub edition. ASTM Intl, PA, USACrossRef

Kramers H (1927) La diffusion de la lumiere par les atomes. Atti Cong Intern Fisica, (Transactions of Volta Centenary Congress) Como 2:545–557

Kronig R (1926) On the theory of the dispersion of x-rays. Opt Soc Am 12:547–557CrossRef

Langmuir I (1916) The constitution and fundamental properties of solids and liquids. part i. solids. J Am Chem Soc 38:2221–2295CrossRef

Larson R (1999) The structure and rheology of complex fluids. Oxford University Press, USA

Lionberger RA, Russel WB (1994) High frequency modulus of hard sphere colloids. J Rheol 38:1885–1907CrossRef

Liptak B (1995) Instrument engineers’ handbook, third edition: process measurement and analysis. Butterworth-Heinemann, USA

Lochhead R (1998) A review of recent advances in the polymeric delivery of attributes in cosmetics and personal care products. ACS Symp Ser 1053:3–22CrossRef

van Maanen G, Seeley S, Capracotta M, White S, Bukovnik R, Hartmann J, Martin J, Spontak R (2005) Property and morphology development in nanocomposite thermoplastic elastomer gels. Langmuir 29:3106–3115CrossRef

Mortimer R (2000) Physical chemistry, 2nd edition. Academic Press, USA

Olesen K, Bassett D, Wilkerson C (1999) Surfactant co-thickening in model associative polymers. Prog Org Coat 35:161–170CrossRef

Patton T (1979) Paint flow and pigment dispersion a rheological approach to coating and ink technology (2nd ed). Wiley, NY

Pham QT, Russel WB, Lau W (1998) The effects of adsorbed layers and solution polymers on the viscosity of dispersions containing associative polymers. J Rheol 42:159–176CrossRef

Pham QT, Russel WB, Thibeault JC, Lau W (1999) Micellar solutions of associative triblock copolymers: the relationship between structure and rheology. Macromolecules 32(15):5139–5146CrossRef

Pham QT, Russel WB, Thibeault JC, Lau W (1999) Polymeric and colloidal modes of relaxation in latex dispersions containing associative triblock copolymers. J Rheol 43(6):1599–1615CrossRef

Pham QT, Thibeault JC, Lau W, Russel WB (2000) Dispersions containing PEO with C₁₆ hydrophobes: adsorption and rheology. Associative Polymers in Aqueous Media pp 221–238

Pham QT, Thibeault JC, Russel WB (2000) Linear viscoelasticity of polymer latices containing PEO with terminal hydrophobes. Macromol Symp pp 557–566

Russel W (1984) Huggins coefficient as a means of characterizing suspended particles. Trans. Faraday Soc J Chem Soc, Faraday Trans 1(80):31–41CrossRef

Sanguandekul S, El-Aasser MS, Silebi CA (1998) Absorbed layer thicknesses of associative polymers on TiO₂ particles. ACS Symp Ser 693:148–160CrossRef

Saito Y, Ogura H, Otsubo Y (2008) Rheological behavior of silica suspensions in aqueous solutions of associating polymer. Colloid Polym Sci 286:1537–1544CrossRef

Saito Y, Ogura H, Otsubo Y (2009) Effect of associating polymer on the viscosity behavior of suspensions consisting of particles with different surface properties. Colloid Polym Sci 287:1229–1235CrossRef

Semenov A, Joanny J, Khokhlov A (1995) Associating polymers: equilibrium and linear viscoelasticity. Macromolecules 28:1066–1075CrossRef

Sperry P, Hopfenberg H, Thomas N (1981) Flocculation of latex by water-soluble polymers: experimental confirmation of a nonbridging, nonadsorptive, volume-restriction mechanism. J Colloid Interface Sci 82:62–7CrossRef

Sperry PR, Thibeault J, Kastanek E (1987) Flocculation and rheological characteristics of mixtures of latices and water-soluble polymeric thickeners. Adv Org Coat Sci Technol 9:1–11

Tanaka F, Edwards SF (1992) Viscoelastic properties of physically crosslinked networks, parts 1 to 3. J Non-Newtonian Fluid Mech 43:247–309CrossRef

Tanaka R, Williams P, Meadows J, Phillips G (1992) The adsorption of hydroxyethyl cellulose and hydrophobically modified hydroxyethyl cellulose onto polystyrene latex. Colloids Surf 66(1):63–72CrossRef

Tanner R (1985) Engineering rheology. Oxford University Press, USA

Taylor K, Nasr-El-Din H (1998) Water-soluble hydrophobically associating polymers for improved oil recovery: a literature review. J Petrol Science Eng 19(3-4):265–280CrossRef

Wang Y, Winnik M (1990) Onset of aggregation for water soluble polymeric associative thickeners: a fluorescence study. Langmuir 6:1437–1439CrossRef

Winnik M, Yekta A (1997) Associative polymers in aqueous solution. Curr Opin Colloid Interface Sci 2(4):424– 436CrossRef

Winter H (1987) Can the gel point of a cross-linking polymer be detected by the G ^′-G ^″ crossover? Polym Eng Sci 27(22):1698–1702CrossRef

Winter H (1994) The occurrence of self-similar relaxation in polymers. J Non-Cryst Solids 172-174:1158–1167CrossRef

Winter H, Mours M (1997) Rheology of polymers near their liquid-solid transitions. Adv Polym Sci 134:165–234CrossRef

Xu B, Yekta A, Li L, Masoumi Z, Winnik MA (1996) The functionality of associative polymer networks: the association behavior of hydrophobically modified urethane-ethoxylate (HEUR) associative polymers in aqueous solution. Colloids and Surfaces A: Physicochemical and Engineering Aspects 112(2–3):239–250CrossRef

Yekta A, Xu B, Duhamel J, Adiwidjaja H, Winnik M (1995) Fluorescence studies of associating polymers in water: determination of the chain end aggregation number and a model for the association process. Macromolecules 28:956–966CrossRef

Yoshimura A, Prud’homme RK (1988) Wall slip corrections for couette and parallel disk viscometers. J Rheol 32:53–67CrossRef

Zhu B, Gu T (1989) General isotherm equation for adsorption of surfactants at solid/liquid interfaces. Trans Faraday Soc J Chem Soc, Faraday Trans 1 85:3813–3817CrossRef

Title: Linear viscoelasticity of ZrO 2 nanoparticle dispersions with associative polymers
Authors: Rose S. Ndong
William B. Russel
Publication date: 01-09-2012
Publisher: Springer-Verlag
Published in: Rheologica Acta / Issue 9/2012
Print ISSN: 0035-4511
Electronic ISSN: 1435-1528
DOI: https://doi.org/10.1007/s00397-012-0633-y

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Other articles of this Issue 9/2012

Axial laminar flow of viscoplastic fluids in a concentric annulus subject to wall slip

On the viscoelastic characterization of the Jeffreys–Lomnitz law of creep

Detecting very low levels of long-chain branching in metallocene-catalyzed polyethylenes

Wall slip phenomena in concentrated ionic liquid-based magnetorheological fluids

Systems analysis of hybrid, multi-scale complex flow simulations using Newton-GMRES

Variable viscosity and slip velocity effects on the flow and heat transfer of a power-law fluid over a non-linearly stretching surface with heat flux and thermal radiation

Premium Partners