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Clean Technologies and Environmental Policy

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01-10-2015 | Original Paper

Magnetically separable Fe₃O₄@DOPA–Pd: a heterogeneous catalyst for aqueous Heck reaction

Authors: R. B. Nasir Baig, John Leazer, Rajender S. Varma

Published in: Clean Technologies and Environmental Policy | Issue 7/2015

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Abstract

Magnetically separable Fe₃O₄@DOPA–Pd catalyst has been synthesized via anchoring of palladium over dopamine-coated magnetite via co-ordinate interaction and the catalyst is utilized for expeditious Heck coupling in aqueous media.

Graphical Abstract

Magnetically separable Fe₃O₄@DOPA-Pd catalyst has been synthesized via anchoring of palladium over dopamine-coated magnetite and the catalyst is utilized for expeditious Heck coupling in aqueous media.

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Anastas PT, Kirchhoff MM (2002) Origins, current status, and future challenges of green chemistry. Acc Chem Res 35:686–694CrossRef

Anastas PT, Warner JC (1998) Green chemistry, theory and practice. Oxford University Press, Oxford

Cartney DM, Guiry PJ (2011) The asymmetric Heck and related reactions. Chem Soc Rev 40:5122–5150CrossRef

Corma A, Garcia H (2003) Lewis acids: from conventional homogeneous to green homogeneous and heterogeneous catalysis. Chem Rev 103:4307–4366CrossRef

Dounay AB, Overman LE (2003) The asymmetric intramolecular Heck reaction in natural product total synthesis. Chem Rev 103:2945–2964CrossRef

Garrett CE, Prasad K (2004) The art of meeting palladium specifications in active pharmaceutical ingredients produced by Pd-catalyzed reactions. Adv Synth Catal 346:889–900CrossRef

Gawande MB, Branco PS, Varma RS (2013) Nano-magnetite (Fe₃O₄) as a support for recyclable catalysts in the development of sustainable methodologies. Chem Soc Rev 42:3371–3393CrossRef

Glasnov TN, Findenig S, Kappe CO (2009) Heterogeneous versus homogeneous palladium catalysts for ligandless Mizoroki–Heck reactions: a comparison of batch/microwave and continuous-flow processing chemistry. Eur J 15:1001–1010CrossRef

Kainz QM, Reiser O (2014) Polymer- and dendrimer-coated magnetic nanoparticles as versatile supports for catalysts, scavengers, and reagents. Acc Chem Res 47:667–677CrossRef

Li CJ, Anastas PT (2012) Green chemistry: present and future. Chem Soc Rev 41:1413–1414CrossRef

Nasir Baig RB, Varma RS (2012a) A facile one-pot synthesis of ruthenium hydroxide nanoparticles on magnetic silica: aqueous hydration of nitriles to amides. Chem Commun 48:6220–6222CrossRef

Nasir Baig RB, Varma RS (2012b) A highly active and magnetically retrievable nanoferrite–DOPA–copper catalyst for the coupling of thiophenols with aryl halides. Chem Commun 48:2582–2584CrossRef

Nasir Baig RB, Varma RS (2013) Magnetically retrievable catalysts for organic synthesis. Chem Commun 49:752–770CrossRef

Nasir Baig RB, Varma RS (2014) Magnetic silica supported copper: a modular approach to aqueous Ullmann-type amination of aryl halides. RSC Adv 4:6568–6572CrossRef

Nasir Baig RB, Chandrakala RN, Sai Sudhir V, Chandrasekaran S (2010) Synthesis of unnatural selenocystines and β-aminodiselenides via regioselective ring-opening of sulfamidates using a sequential, one-pot, multistep strategy. J Org Chem 75:910–2921

Nasir Baig RB, Nadagouda MN, Varma RS (2014a) Carbon-coated magnetic palladium: applications in partial oxidation of alcohols and coupling reactions. Green Chem 16:4333–4338CrossRef

Nasir Baig RB, Vaddula BR, Gonzalez MA, Varma RS (2014b) N-Allylation of amines with allyl acetates using chitosan-immobilized palladium. RSC Adv 4:9103–9106CrossRef

Nasir Baig RB, Nadagouda MN, Varma RS (2014c) Ruthenium on chitosan: a recyclable heterogeneous catalyst for aqueous hydration of nitriles to amides. Green Chem 16:2122–2127CrossRef

Nasir Baig RB, Nadagouda MN, Varma RS (2015) Magnetic retrievable catalysts for asymmetric synthesis. Coord Chem Rev 49(8):750–770. doi:10.1016/j.ccr.2014.12.017

Polshettiwar V, Varma RS (2009) Nanoparticle-supported and magnetically recoverable palladium (Pd) catalyst: a selective and sustainable oxidation protocol with high turnover number. Org Biomol Chem 7:37–40CrossRef

Polshettiwar V, Nadagouda MN, Varma RS (2009) The synthesis and applications of a micro-pine-structured nanocatalyst. Chem Commun 47:6318–6320

Polshettiwar V, Luque R, Fihri A, Zhu H, Bouhrara M, Basset JM (2011) Magnetically recoverable nanocatalysts. Chem Rev 111:3036–3075CrossRef

Saha A, Leazer J, Varma RS (2012) O-Allylation of phenols with allylic acetates in aqueous media using a magnetically separable catalytic system. Green Chem 14:67–71CrossRef

Varma RS (2014) Journey on greener pathways: from the use of alternate energy inputs and benign reaction media to sustainable applications of nano-catalysts in synthesis and environmental remediation. Green Chem 16:2027–2041CrossRef

Link: http://www2.epa.gov/science-and-technology/land-waste-and-cleanup-science

Zhao M, Sha OU, Wu CD (2014) Porous metal-organic frameworks for heterogeneous biomimetic catalysis. Acc Chem Res 47:1199–1207CrossRef

Title: Magnetically separable Fe3O4@DOPA–Pd: a heterogeneous catalyst for aqueous Heck reaction
Authors: R. B. Nasir Baig
John Leazer
Rajender S. Varma
Publication date: 01-10-2015
Publisher: Springer Berlin Heidelberg
Published in: Clean Technologies and Environmental Policy / Issue 7/2015
Print ISSN: 1618-954X
Electronic ISSN: 1618-9558
DOI: https://doi.org/10.1007/s10098-015-0914-0

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