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Computational Methods in Spectroscopy Read chapter Read first chapter

2019 | OriginalPaper | Chapter

4. Material Analysis Using Raman Spectroscopy

A Comparative Study of Graphite, Single- and Multi-walled Carbon Nanotubes

Authors : Animesh K. Ojha, H. Michael Heise

Published in: Molecular Spectroscopy—Experiment and Theory

Publisher: Springer International Publishing

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Abstract

A comparative Raman spectroscopic study of single-walled carbon nanotubes (SWCNT), special multi-walled carbon nanotube (MWCNT) material, and graphite is presented. Their Raman spectra have been recorded using different excitation wavelengths, 532, 785, and 1064 nm, in the region of 1800–1200 cm−1. The G-bands of SWCNTs observed at all excitation wavelengths were fitted taking bands into account with Breit-Wigner-Fano (BWF) and Lorentzian line shape functions. The contribution of both BWF and Lorentzian line shapes to the asymmetric G-band shows a mixture of semiconducting as well as metallic CNTs in the SWCNTs. For graphite and MWCNTs, only Lorentzian line shape functions were used for band deconvolution. The variation in wavenumber position of component bands of G-band with laser lines may be due to the resonance Raman effect, where the energy of laser lines matches with the electronic transition energy of CNTs with different diameters and chirality. The apparent Young’s modulus of SWCNT and MWCNT materials was determined using the integrated band intensity ratio of G- and D-bands, ID/IG, and it was found that the SWCNTs have a larger value of the apparent Young’s modulus compared to that of the highly aligned MWCNT material.

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Literature
1.
Kroto HW, Heath JR, O’Brien SC, Curl RF, Smalley RE (1985) C60: Buckminsterfullerene. Nature 318:162–163CrossRef
2.
3.
Kruss S, Hilmer AJ, Zhang J, Reuel NF, Mu B, Strano MS (2013) Carbon nanotubes as biomedical sensors. Adv Drug Deliv Rev 65:1933–1950CrossRefPubMedCentral
4.
Zaporotskova IV, Boroznina NP, Parkhomenko YN, Kozhito LV (2016) Carbon nanotubes: sensor properties. A review. Mod Electron Mater 2:95–105CrossRef
5.
Iannazzo D, Piperno A, Pistone A, Grassi G, Galvagno S (2013) Recent advances in carbon nanotubes as delivery systems for anticancer drugs. Curr Med Chem 20:1333–1354CrossRefPubMedCentral
6.
Dalton AB, Collins S, Munoz E, Razal JM, Ebron VH, Ferraris JP, Coleman JN, Kim BG, Baughman RH (2003) Super-tough carbon-nanotube fibres. Nature 423:703–703CrossRefPubMedCentral
7.
Bokobza L (2012) A Raman investigation of carbon nanotubes embedded in a soft polymeric matrix. J Inorg Organometallic Polym 22(3):629–635CrossRef
8.
Baibarac M, Baltog I, Lefrant S (2011) Recent progress in synthesis, vibrational characterization and applications trend of conjugated polymers/Carbon nanotubes composites. Curr Org Chem 15:1160–1196CrossRef
9.
Bose S, Khare RA, Moldenaers P (2010) Assessing the strengths and weaknesses of various types of pre-treatments of carbon nanotubes on the properties of polymer/carbon nanotubes composites: a critical review. Polymer 51:975–993CrossRef
10.
Dillon AC, Jones KM, Bekkedahl TA, Kiang CH, Heben MJ (1997) Storage of hydrogen in single-walled carbon nanotubes. Nature 386:377–379CrossRef
11.
Britto PJ, Santhanam KSV, Ajayan PM (1996) Carbon nanotube electrode for oxidation of dopamine. Bioelectrochem Bioenerg 41:121–125CrossRef
12.
Che GL, Lakshmi BB, Fisher ER, Martin CR (1998) Carbon nanotubule membranes for electrochemical energy storage and production. Nature 393:346–349CrossRef
13.
Lu W, Baek JB, Dai L (eds) (2015) Carbon nanomaterials for advanced energy systems: advances in materials synthesis and device applications. Wiley, Hoboken, NJ
14.
Herrero-Latorre C, Álvarez-Méndez J, Barciela-García J, García-Martín S, Peña-Crecente RM (2015) Characterization of carbon nanotubes and analytical methods for their determination in environmental and biological samples: a review. Anal Chim Acta 853:77–94CrossRefPubMedCentral
15.
Braun EI, Huang A, Tusa CA, Yukica MA, Pantano P (2016) Use of Raman spectroscopy to identify carbon nanotube contamination at an analytical balance workstation. J Occup Environ Hyg 13:915–923CrossRefPubMedCentral
16.
Rogers-Nieman GM, Dinu CZ (2014) Therapeutic applications of carbon nanotubes: opportunities and challenges. Wiley Interdiscip Rev Nanomed Nanobiotechnol 6:327–337CrossRefPubMedCentral
17.
Herrera-Herrera AV, Gonzalez-Curbelo MA, Hernández-Borges J (2012) Carbon nanotubes applications in separation science: a review. Anal Chim Acta 734:1–30CrossRefPubMedCentral
18.
Socas-Rodríguez B, Herrera-Herrera AV, Asensio-Ramos M, Hernández-Borges J (2014) Recent applications of carbon nanotube sorbents in analytical chemistry. J Chromatogr A 1357:110–146CrossRefPubMedCentral
19.
Srivastava A, Srivastava ON, Talapatra S, Vajtai R, Ajayan PM (2004) Carbon nanotube filters. Nat Mat 3:610–614CrossRef
20.
Ebbesen TW, Lezec HJ, Hiura H, Bennett JW, Ghaemi HF, Thio T (1996) Electrical conductivity of individual carbon nanotubes. Nature 382:54–56CrossRef
21.
Bockrath M, Cobden DH, McEuen PL, Chopra NG, Zettle A, Thess A, Smalley RE (1997) Single-electron transport in ropes of carbon nanotubes. Science 275:1922–1925CrossRefPubMedCentral
22.
Krauss TD, Wise FW, Tanner DB (1996) Observation of coupled vibrational modes of a semiconductor nanocrystal. Phys Rev Lett 76:1376–1379CrossRefPubMedCentral
23.
Bischof T, Lermann G, Schreder B, Materny A, Kiefer W, Ivanda M (1997) Intensity-dependent micro-Raman and photoluminescence investigations of CdSxSe1−x nanocrystallites. J Opt Soc Am B 14:3334–3338CrossRef
24.
Schreder B, Materny A, Kiefer W, Kümmell T, Bacher G, Forchel A, Landwehr G (2000) Raman investigation of CdxZn1−xSe/ZnSe quantum wires: Strain relaxation and excitation profile. J Appl Phys 88:764–771CrossRef
25.
Jorio A, Dresselhaus G, Dresselhaus MS, Souza M, Dantas MSS, Pimenta MA, Rao AM, Saito R, Liu C, Cheng HM (2000) Polarized Raman study of single-wall semiconducting carbon nanotubes. Phys Rev Lett 85:2617–2620CrossRefPubMedCentral
26.
Kasuya A, Sasaki Y, Saito Y, Tohji K, Nishina Y (1997) Evidence for size-dependent discrete dispersions in single-wall nanotubes. Phys Rev Lett 78:4434–4441CrossRef
27.
Dresselhaus MS, Jorio A, Hofmann M, Dresselhaus G, Saito R (2010) Perspectives on carbon nanotubes and graphene Raman spectroscopy. Nano Lett 10:751–758CrossRefPubMedCentral
28.
Jorio A, Kauppinen E, Hassanien A (2008) Carbon-nanotube metrology. In: Jorio A, Dresselhaus G, Dresselhaus MS (eds) Carbon nanotubes. Topics applied in physics, vol 111. Springer, Berlin, pp 63–100
29.
Thomsen C, Reich S (2007) Raman scattering in carbon nanotubes. In: Cardona M, Merlin R (eds) Light scattering in solid IX. Topics applied in physics, vol 108. Springer, Berlin, pp 115–232
30.
Saito R, Grüneis A, Samsonidze GG, Brar VW, Dresselhaus G, Dresselhaus MS, Jario A, Canҫado LG, Fantini C, Pimenta MA, Filho AGS (2003) Double resonance Raman spectroscopy of single-wall carbon nanotubes. New J Phys 5:157CrossRef
31.
Saito R, Dresselhaus G, Dresselhaus MS (1998) Physical properties of carbon nanotube. Imperial College Press, LondonCrossRef
32.
Dresselhaus MS, Endo M (2001) Carbon nanotubes: synthesis, structure, properties and applications. In: Dresselhaus MS, Dresselhaus G, Avouris P (eds) Topics Applied in Physics, vol 80. Springer, Berlin, pp 11–28
33.
Sadezky A, Muckenhuber H, Grothe H, Niessner R, Poeschl U (2005) Raman microspectroscopy of soot and related carbonaceous materials: spectral analysis and structural information. Carbon 43:1731–1742CrossRef
34.
Dresselhaus MS, Dresselhaus G, Jorio A (2007) Raman Spectroscopy of Carbon Nanotubes in 1997 and 2007. J Phys Chem C 111:17887–17893CrossRef
35.
Jorio A, Pimenta MA, Souza Filho AG, Saito R, Dresselhaus G, Dresselhaus MS (2003) Characterizing carbon nanotube samples with resonance Raman scattering. New J Phys 5:139CrossRef
36.
Enomoto K, Kitakata S, Yasuhara T, Ohtake N (2006) Measurement of Young’s modulus of carbon nanotubes by nanoprobe manipulation in a transmission electron microscope. Appl Phys Lett 88:153115–153117CrossRef
37.
Heise HM, Kuckuk R, Ojha AK, Srivastava A, Srivastava V, Asthana BP (2009) Characterisation of carbonaceous materials using Raman spectroscopy: a comparison of carbon nanotube filters, single- and multi-walled nanotubes, graphitised porous carbon and graphite. J Raman Spectrosc 40:344–353CrossRef
38.
Heise HM, Kuckuk R, Srivastava A, Asthana BP (2011) Characterization of carbon nanotube filters and other carbonaceous materials by Raman spectroscopy—II: study on dispersion and disorder parameters. J Raman Spectrosc 42:294–302CrossRef
39.
Fantini C, Jorio A, Souza M, Strano MS, Dresselhaus MS, Pimenta MA (2004) Optical transition energies for carbon nanotubes from resonant Raman spectroscopy: environment and temperature effects. Phys Rev Lett 93:147406–147410CrossRefPubMedCentral
40.
Kataura H, Kumazawa Y, Maniwa Y, Umezu I, Suzuki S, Ohtsuka Y, Achiba Y (1999) Diameter control of single-walled carbon nanotubes. Synth Met 103:2555–2558CrossRef
41.
Brown SDM, Jorio A, Corio P, Dresselhaus MS, Dresselhaus G, Saito R, Kneipp K (2001) Origin of the Breit-Wigner-Fano lineshape of the tangential G-band feature of metallic carbon nanotubes. Phys Rev B 63:155414–155421CrossRef
42.
Puretzky AA, Schittenhelm H, Fan X, Lance JM Jr, Allard LF, Geohegan DB (2002) Investigations of single-wall carbon nanotube growth by time-restricted laser vaporization. Phys Rev B 65:245425–245433CrossRef
43.
Tuinstra F, Foenig J (1970) Raman spectrum of graphite. J Chem Phys 53:1126–1130CrossRef
44.
Brown SDM, Corio P, Marucci A, Dresselhaus MS, Pimenta MA, Kneipp K (2000) Anti-Stokes Raman spectra of single-walled carbon nanotubes. Phys Rev B 64:R5137CrossRef
45.
Dresselhaus MS, Dresselhaus G, Hofmann M (2007) The big picture of Raman scattering in carbon nanotubes. Vib Spectrosc 45:71–81CrossRef
46.
Miyata Y, Yanagi K, Maniwa Y, Kataura H (2008) Optical evaluation of the metal-to-semiconductor ratio of single-wall carbon nanotubes. J Phys Chem 112:13187–13191
47.
Yakobson BI, Brabec CJ, Bernholc J (1996) Nanomechanics of carbon tubes: instabilities beyond linear response. Phys Rev Lett 76:2511–2514CrossRefPubMedCentral
48.
Miyata Y, Mizuno K, Kataura H (2011) Purity and defect characterization of single-wall carbon nanotubes using raman spectroscopy. J Nanomater 786763
49.
DiLeo RA, Landi BJ, Raffaelle RP (2007) Purity assessment of multiwalled carbon nanotubes by Raman spectroscopy. J Appl Phys 101:064307–64311CrossRef
Metadata
Title
Material Analysis Using Raman Spectroscopy
Authors
Animesh K. Ojha
H. Michael Heise
Copyright Year
2019
Book
Molecular Spectroscopy—Experiment and Theory

Print ISBN: 978-3-030-01354-7

Electronic ISBN: 978-3-030-01355-4

Copyright Year: 2019

DOI
https://doi.org/10.1007/978-3-030-01355-4_4