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Colloid and Polymer Science
Published in: Colloid and Polymer Science 1/2017

16-12-2016 | Original Contribution

Mesoporous diatomite-filled PMMA by in situ reverse atom transfer radical polymerization

Authors: Yousef Fazli, Khezrollah Khezri

Published in: Colloid and Polymer Science | Issue 1/2017

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Abstract

Mesoporous diatomite was employed to synthesize different poly (methyl methacrylate)/diatomite composites. Diatomite platelets were used for in situ polymerization of methyl methacrylate by RATRP to synthesize tailor-made poly (methyl methacrylate) nanocomposites. FTIR spectroscopy, TGA, nitrogen adsorption/desorption isotherm, SEM, and TEM were employed for evaluating some inherent properties of pristine diatomite platelets. Conversion and molecular weight determinations were carried out using GC and SEC, respectively. Addition of 3 wt% pristine mesoporous diatomite leads to increase of conversion from 84 to 95%. Molecular weight of poly (methyl methacrylate) chains increases from 8600 to 9400 g mol−1 by addition of 3 wt% pristine mesoporous diatomite; however, polydispersity index values increase from 1.34 to 1.54. Increasing thermal stability of the nanocomposites is demonstrated by TGA. Differential scanning calorimetry shows an increase in glass transition temperature from 75.8 to 81.1 °C by adding 3 wt% of mesoporous diatomite platelets.
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Metadata
Title
Mesoporous diatomite-filled PMMA by in situ reverse atom transfer radical polymerization
Authors
Yousef Fazli
Khezrollah Khezri
Publication date
16-12-2016
Publisher
Springer Berlin Heidelberg
Published in
Colloid and Polymer Science / Issue 1/2017
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-016-3997-1

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