Skip to main content
Top
Published in: Rare Metals 5/2021

27-04-2020

Microstructure and hot ductility behavior of Ni-based superalloy U720Li with boron addition

Authors: Guang-Di Zhao, Fang Liu, Xi-Min Zang, Wen-Ru Sun

Published in: Rare Metals | Issue 5/2021

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

High-alloyed superalloy U720Li is difficult to be processed through the conventional cast and wrought route. Boron is an important strengthening element for superalloys, but the role of boron in the hot ductility of U720Li alloy is not clear. This study is focused on the effect of boron addition, in the range of < 0.0005 wt%–0.0240 wt%, on the microstructure and hot ductility behavior of superalloy U720Li. It is found that boron addition significantly increases the content of eutectic (γ + γ′) and greatly affects the degree of continuity of the grain boundary eutectic (γ + γ′) precipitation. Boron addition dramatically worsens the 1100 °C tensile ductility of conventional cast U720Li alloy and causes a change in tensile fracture mode from transgranular to intergranular. The eutectic (γ + γ′) represents the most effective site for crack initiation. Boron deteriorates the hot ductility mainly by promoting the continuous precipitation of eutectic (γ + γ′) along the grain boundary.

Graphic abstract

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
[1]
go back to reference Keefe PW, Mancuso SO, Maurer GE. Effects of heat treatment and chemistry on the long-term phase stability of a high strength nickel-based superalloy. In: Proceedings of Superalloys 1992. Warrendale; 1992. 487. Keefe PW, Mancuso SO, Maurer GE. Effects of heat treatment and chemistry on the long-term phase stability of a high strength nickel-based superalloy. In: Proceedings of Superalloys 1992. Warrendale; 1992. 487.
[2]
go back to reference Helm D, Roder O. Influence of long term exposure in air on microstructure, surface stability and mechanical properties of Udimet 720Li. In: Proceedings of Superalloys 2000. Champion; 2000. 487. Helm D, Roder O. Influence of long term exposure in air on microstructure, surface stability and mechanical properties of Udimet 720Li. In: Proceedings of Superalloys 2000. Champion; 2000. 487.
[3]
go back to reference Screrzenie FE, Maurer GE. Development of Udimet720 for high strength disk application. In: Proceedings of Superalloys 1984. Warrendale; 1984. 573. Screrzenie FE, Maurer GE. Development of Udimet720 for high strength disk application. In: Proceedings of Superalloys 1984. Warrendale; 1984. 573.
[4]
go back to reference Zhao GD, Yu LX, Qi F, Liu F, Sun WR, Hu ZQ. The minor precipitation at the final stage of U720Li solidification. Acta Metall Sin (Engl Lett). 2016;29(6):518.CrossRef Zhao GD, Yu LX, Qi F, Liu F, Sun WR, Hu ZQ. The minor precipitation at the final stage of U720Li solidification. Acta Metall Sin (Engl Lett). 2016;29(6):518.CrossRef
[5]
go back to reference Chang L, Jin H, Sun W. Solidification behavior of Ni-base superalloy Udimet 720Li. J Alloys Compd. 2015;653:266.CrossRef Chang L, Jin H, Sun W. Solidification behavior of Ni-base superalloy Udimet 720Li. J Alloys Compd. 2015;653:266.CrossRef
[6]
go back to reference Fahrmann M, Suzuki A. Effect of cooling rate on Gleeble hot ductility of UDIMET alloy 720 billet. In: Proceedings of Superalloys 2008. Warrendale; 2008. 311. Fahrmann M, Suzuki A. Effect of cooling rate on Gleeble hot ductility of UDIMET alloy 720 billet. In: Proceedings of Superalloys 2008. Warrendale; 2008. 311.
[7]
go back to reference Holt RT, Wallace W. Impurities and trace elements in nickel-base superalloys. Int Mater Rev. 1976;21(1):1.CrossRef Holt RT, Wallace W. Impurities and trace elements in nickel-base superalloys. Int Mater Rev. 1976;21(1):1.CrossRef
[8]
go back to reference Wang RD, Hu Q, Zhang SM, Zhang FW, Lu CT, Wang ZG. Properties of (Fe–B)-doped Sn–1.0Ag–0.5Cu solders prepared by mechanical alloying. Rare Met. 2019;38(7):665.CrossRef Wang RD, Hu Q, Zhang SM, Zhang FW, Lu CT, Wang ZG. Properties of (Fe–B)-doped Sn–1.0Ag–0.5Cu solders prepared by mechanical alloying. Rare Met. 2019;38(7):665.CrossRef
[9]
go back to reference Sabol GP, Stickler R. Microstructure of nickel-based superalloys. Phys Status Solidi. 1969;35(1):11.CrossRef Sabol GP, Stickler R. Microstructure of nickel-based superalloys. Phys Status Solidi. 1969;35(1):11.CrossRef
[10]
go back to reference Garosshen TJ, Tillman TD, McCarthy GP. Effects of B, C, and Zr on the structure and properties of a P/M nickel base superalloy. Metall Trans A. 1987;18(1):69.CrossRef Garosshen TJ, Tillman TD, McCarthy GP. Effects of B, C, and Zr on the structure and properties of a P/M nickel base superalloy. Metall Trans A. 1987;18(1):69.CrossRef
[11]
go back to reference Stiller K. Investigations of grain boundary microchemistry in nickel base superalloys. Surf Sci. 1991;246(1–3):225.CrossRef Stiller K. Investigations of grain boundary microchemistry in nickel base superalloys. Surf Sci. 1991;246(1–3):225.CrossRef
[12]
go back to reference Huang X, Chaturvedi MC, Richards NL, Jackman J. The effect of grain boundary segregation of boron in cast alloy 718 on HAZ microfissuring—a SIMS analysis. Acta Mater. 1997;45(8):3095.CrossRef Huang X, Chaturvedi MC, Richards NL, Jackman J. The effect of grain boundary segregation of boron in cast alloy 718 on HAZ microfissuring—a SIMS analysis. Acta Mater. 1997;45(8):3095.CrossRef
[13]
go back to reference Chen W, Chaturvedi MC, Richards NL, McMahon G. Grain boundary segregation of boron in INCONEL 718. Metall Mater Trans A. 1998;29(7):1947.CrossRef Chen W, Chaturvedi MC, Richards NL, McMahon G. Grain boundary segregation of boron in INCONEL 718. Metall Mater Trans A. 1998;29(7):1947.CrossRef
[14]
go back to reference Cadel E, Lemarchand D, Chambreland S, Blavette D. Atom probe tomography investigation of the microstructure of superalloys N18. Acta Mater. 2002;50(5):957.CrossRef Cadel E, Lemarchand D, Chambreland S, Blavette D. Atom probe tomography investigation of the microstructure of superalloys N18. Acta Mater. 2002;50(5):957.CrossRef
[15]
go back to reference Blavette D, Duval P, Letellier L, Guttmann M. Atomic-scale APFIM and TEM investigation of grain boundary microchemistry in Astroloy nickel base superalloys. Acta Mater. 1996;44(12):4995.CrossRef Blavette D, Duval P, Letellier L, Guttmann M. Atomic-scale APFIM and TEM investigation of grain boundary microchemistry in Astroloy nickel base superalloys. Acta Mater. 1996;44(12):4995.CrossRef
[16]
go back to reference Zhou PJ, Yu JJ, Sun XF, Guan HR, Hu ZQ. The role of boron on a conventional nickel-based superalloy. Mater Sci Eng A. 2008;491(1–2):159.CrossRef Zhou PJ, Yu JJ, Sun XF, Guan HR, Hu ZQ. The role of boron on a conventional nickel-based superalloy. Mater Sci Eng A. 2008;491(1–2):159.CrossRef
[17]
go back to reference Ladna B, Birnbaum HK. Surface and grain boundary segregation of sulfur and boron in nickel. Acta Met. 1988;36(3):745.CrossRef Ladna B, Birnbaum HK. Surface and grain boundary segregation of sulfur and boron in nickel. Acta Met. 1988;36(3):745.CrossRef
[18]
go back to reference Liu CT, White CL, Horton JA. Effect of boron on grain-boundaries in Ni3Al. Acta Met. 1985;33(2):213.CrossRef Liu CT, White CL, Horton JA. Effect of boron on grain-boundaries in Ni3Al. Acta Met. 1985;33(2):213.CrossRef
[19]
go back to reference Cheng XY, Wan XJ, Liu CT, Guo JT. Effect of Zr and B on environmental embrittlement in Ni3Al alloys. Scr Mater. 1998;38(6):959.CrossRef Cheng XY, Wan XJ, Liu CT, Guo JT. Effect of Zr and B on environmental embrittlement in Ni3Al alloys. Scr Mater. 1998;38(6):959.CrossRef
[20]
go back to reference Lee CS, Han GW, Smallman RE, Feng D, Lai JKL. The influence of boron-doping on the effectiveness of grain boundary hardening in Ni3Al. Acta Mater. 1999;47(6):1823.CrossRef Lee CS, Han GW, Smallman RE, Feng D, Lai JKL. The influence of boron-doping on the effectiveness of grain boundary hardening in Ni3Al. Acta Mater. 1999;47(6):1823.CrossRef
[21]
go back to reference Khadkikar PS, Vedula K, Shabel BS. The role of boron in ductilizing Ni3Al. Metall Trans A. 1987;18(3):425.CrossRef Khadkikar PS, Vedula K, Shabel BS. The role of boron in ductilizing Ni3Al. Metall Trans A. 1987;18(3):425.CrossRef
[22]
go back to reference Yan BC, Zhang J, Lou LH. Effect of boron additions on the microstructure and transverse properties of a directionally solidified superalloy. Mater Sci Eng A. 2008;474(1–2):39.CrossRef Yan BC, Zhang J, Lou LH. Effect of boron additions on the microstructure and transverse properties of a directionally solidified superalloy. Mater Sci Eng A. 2008;474(1–2):39.CrossRef
[23]
go back to reference Burke MA, Greggi J, Whitlow GA. The effect of boron and carbon on the microstructural chemistries of two wrought nickel base superalloys. Scr Metall. 1984;18(1):91.CrossRef Burke MA, Greggi J, Whitlow GA. The effect of boron and carbon on the microstructural chemistries of two wrought nickel base superalloys. Scr Metall. 1984;18(1):91.CrossRef
[24]
go back to reference Franzoni U, Marchetti F, Sturlese S. Effects of grain boundary segregation and precipitation on the creep behaviour of a 20Cr, Al–Ti, Ni-base superalloy. Scr Metall. 1985;19(4):511.CrossRef Franzoni U, Marchetti F, Sturlese S. Effects of grain boundary segregation and precipitation on the creep behaviour of a 20Cr, Al–Ti, Ni-base superalloy. Scr Metall. 1985;19(4):511.CrossRef
[25]
go back to reference Zhao G, Yu L, Yang G, Zhang W, Sun W. The role of boron in modifying the solidification and microstructure of nickel-base alloy U720Li. J Alloys Compd. 2016;686:194.CrossRef Zhao G, Yu L, Yang G, Zhang W, Sun W. The role of boron in modifying the solidification and microstructure of nickel-base alloy U720Li. J Alloys Compd. 2016;686:194.CrossRef
[26]
go back to reference Liu L, Jin T, Zhao N, Sun X, Guan H, Hu Z. Formation of carbides and their effects on stress rupture of a Ni-base single crystal superalloy. Mater Sci Eng A. 2003;361(1–2):191.CrossRef Liu L, Jin T, Zhao N, Sun X, Guan H, Hu Z. Formation of carbides and their effects on stress rupture of a Ni-base single crystal superalloy. Mater Sci Eng A. 2003;361(1–2):191.CrossRef
[27]
go back to reference Voort GFV. Metallography, Principles and Practice. New York: ASM International; 1984. 45. Voort GFV. Metallography, Principles and Practice. New York: ASM International; 1984. 45.
[28]
go back to reference Hobbs R, Tin S, Rae C. A castability model based on elemental solid–liquid partitioning in advanced nickel-base single-crystal superalloys. Metall Mater Trans A. 2005;36(10):2761.CrossRef Hobbs R, Tin S, Rae C. A castability model based on elemental solid–liquid partitioning in advanced nickel-base single-crystal superalloys. Metall Mater Trans A. 2005;36(10):2761.CrossRef
[29]
go back to reference Monajati H, Taheri AK, Jahazi M, Yue S. Deformation characteristics of isothermally forged UDIMET 720 nickel-base superalloy. Metall Mater Trans A. 2005;36(4):895.CrossRef Monajati H, Taheri AK, Jahazi M, Yue S. Deformation characteristics of isothermally forged UDIMET 720 nickel-base superalloy. Metall Mater Trans A. 2005;36(4):895.CrossRef
[30]
go back to reference Wei CN, Bor HY, Chang L. The effects of carbon content on the microstructure and elevated temperature tensile strength of a nickel-base superalloy. Mater Sci Eng A. 2010;527(16–17):3741.CrossRef Wei CN, Bor HY, Chang L. The effects of carbon content on the microstructure and elevated temperature tensile strength of a nickel-base superalloy. Mater Sci Eng A. 2010;527(16–17):3741.CrossRef
[31]
go back to reference Motejadded H, Soltanieh M, Rastegari S. An investigation about the effect of annealing conditions on microstructure in a Ni3Al base alloy. J Alloys Compd. 2009;486(1–2):881.CrossRef Motejadded H, Soltanieh M, Rastegari S. An investigation about the effect of annealing conditions on microstructure in a Ni3Al base alloy. J Alloys Compd. 2009;486(1–2):881.CrossRef
[32]
go back to reference Zhang J, Singer RF. Effect of Zr and B on castability of Ni-based superalloy IN792. Metall Mater Trans A. 2004;35(4):1337.CrossRef Zhang J, Singer RF. Effect of Zr and B on castability of Ni-based superalloy IN792. Metall Mater Trans A. 2004;35(4):1337.CrossRef
[33]
go back to reference Keene BJ. Review of data for the surface tension of pure metals. Int Mater Rev. 1993;38(4):157.CrossRef Keene BJ. Review of data for the surface tension of pure metals. Int Mater Rev. 1993;38(4):157.CrossRef
[34]
go back to reference Busby PE, Warga ME, Wells C. Diffusion and solubility of boron in iron and steel. JOM. 1953;5(11):1463.CrossRef Busby PE, Warga ME, Wells C. Diffusion and solubility of boron in iron and steel. JOM. 1953;5(11):1463.CrossRef
[35]
go back to reference Lomaev IL, Novikov DL, Okatov SV, Gornostyrev YN, Burlatsky SF. First-principles study of 4d solute diffusion in nickel. J Mater Sci. 2014;49(11):4038.CrossRef Lomaev IL, Novikov DL, Okatov SV, Gornostyrev YN, Burlatsky SF. First-principles study of 4d solute diffusion in nickel. J Mater Sci. 2014;49(11):4038.CrossRef
[36]
go back to reference Miller MK. Contributions of atom probe tomography to the understanding of nickel-based superalloys. Micron. 2001;32(8):757.CrossRef Miller MK. Contributions of atom probe tomography to the understanding of nickel-based superalloys. Micron. 2001;32(8):757.CrossRef
[37]
go back to reference Chuang TH. The mutual effects of boron, zirconium and aluminium on grain boundary segregation in Ni3Al intermetallic compounds. Mater Sci Eng A. 1991;141(2):169.CrossRef Chuang TH. The mutual effects of boron, zirconium and aluminium on grain boundary segregation in Ni3Al intermetallic compounds. Mater Sci Eng A. 1991;141(2):169.CrossRef
[38]
go back to reference Momeni A, Abbasi SM, Morakabati M, Badri H, Wang X. Dynamic recrystallization behavior and constitutive analysis of Incoloy 901 under hot working condition. Mater Sci Eng A. 2014;615:51.CrossRef Momeni A, Abbasi SM, Morakabati M, Badri H, Wang X. Dynamic recrystallization behavior and constitutive analysis of Incoloy 901 under hot working condition. Mater Sci Eng A. 2014;615:51.CrossRef
[39]
go back to reference Rollett A, Humphreys FJ, Rohrer GS, Hatherly M. Recrystallization and Related Annealing Phenomena. Oxford: Elsevier; 2012. 113. Rollett A, Humphreys FJ, Rohrer GS, Hatherly M. Recrystallization and Related Annealing Phenomena. Oxford: Elsevier; 2012. 113.
[40]
go back to reference Gao B, Wang L, Liang T, Liu Y, Song X, Qu J. Plastic deformation behavior of directionally solidified U720Li alloy at elevated temperature. Acta Metall Sin. 2016;52(4):437. Gao B, Wang L, Liang T, Liu Y, Song X, Qu J. Plastic deformation behavior of directionally solidified U720Li alloy at elevated temperature. Acta Metall Sin. 2016;52(4):437.
[41]
go back to reference Wang L, Pyczak F, Zhang J, Lou LH, Singer RF. Effect of eutectics on plastic deformation and subsequent recrystallization in the single crystal nickel base superalloy CMSX-4. Mater Sci Eng A. 2012;532:487.CrossRef Wang L, Pyczak F, Zhang J, Lou LH, Singer RF. Effect of eutectics on plastic deformation and subsequent recrystallization in the single crystal nickel base superalloy CMSX-4. Mater Sci Eng A. 2012;532:487.CrossRef
[42]
go back to reference Chen X, Qi YG, Shi XN, Xie BC, Ning YQ. Behaviors and model of dynamic recrystallization of nickel-based superalloy IN718Plus. Chin J Rare Met. 2019;43(12):1260. Chen X, Qi YG, Shi XN, Xie BC, Ning YQ. Behaviors and model of dynamic recrystallization of nickel-based superalloy IN718Plus. Chin J Rare Met. 2019;43(12):1260.
[43]
go back to reference Zhu SQ, Yan HG, Chen JH, Wu YZ, Liu JZ, Tian J. Effect of twinning and dynamic recrystallization on the high strain rate rolling process. Scr Mater. 2010;63(10):985.CrossRef Zhu SQ, Yan HG, Chen JH, Wu YZ, Liu JZ, Tian J. Effect of twinning and dynamic recrystallization on the high strain rate rolling process. Scr Mater. 2010;63(10):985.CrossRef
Metadata
Title
Microstructure and hot ductility behavior of Ni-based superalloy U720Li with boron addition
Authors
Guang-Di Zhao
Fang Liu
Xi-Min Zang
Wen-Ru Sun
Publication date
27-04-2020
Publisher
Nonferrous Metals Society of China
Published in
Rare Metals / Issue 5/2021
Print ISSN: 1001-0521
Electronic ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-020-01395-4

Other articles of this Issue 5/2021

Rare Metals 5/2021 Go to the issue

Premium Partners