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Published in: Journal of Materials Engineering and Performance 6/2022

06-01-2022 | Technical Article

Microstructure and Properties of Lightweight Al2NbTixV2Zr High Entropy Alloy

Authors: Qian Zhi, Xinrong Tan, Jilin Xie, Yang Liu, Kai Yang, Qiong Zhang, Wenhui Liu, Zhongxia Liu

Published in: Journal of Materials Engineering and Performance | Issue 6/2022

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Abstract

Lightweight Al2NbTixV2Zr (x = 1.0, 1.5, 2.0, 2.5, 3.0) high entropy alloys are fabricated through mechanical milling followed by vacuum hot pressing. The effect of Ti content on microstructure, hardness, mechanical behaviors, and corrosion property of the alloys are investigated. Microstructural studies reveal multiphase structures for this alloy, BCC solid solution matrix and α phase for Ti1.0 and for Ti1.5 alloys while β occurs in Ti2.0, Ti2.5 and Ti3.0 alloys. All sintered bulks exhibit low density in the range of 5.2-5.4 g/cm3. Hardness of Al2NbTixV2Zr alloys fluctuates between 749 to 791 HV to various Ti contents. The varying tendency of hardness is closely related with the content of the secondary phase. The alloys show high yield strength and considerable strain during compression test. Comprehensive property of Al2NbTixV2Zr system is superior to majority of other HEAs. The alloys display good anti-corrosion properties in HNO3, H2SO4, HCl, and NaCl solutions, and the corrosion property of Al2NbTixV2Zr improves with the increasing of Ti content.

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Literature
1.
go back to reference H.C. Liu and C.W. Tsai, Effect of Ge Addition on the Microstructure, Mechanical Properties, and Corrosion Behavior of CoCrFeNi High-Entropy Alloys, Intermetallics, 2021, 132, p 107167.CrossRef H.C. Liu and C.W. Tsai, Effect of Ge Addition on the Microstructure, Mechanical Properties, and Corrosion Behavior of CoCrFeNi High-Entropy Alloys, Intermetallics, 2021, 132, p 107167.CrossRef
2.
go back to reference V. Bhardwaj, Q. Zhou, F. Zhang, W.C. Han, Y. Du, K. Hua and H.F. Wang, Effect of Al Addition on the Microstructure, Mechanical and Wear Properties of TiZrNbHf Refractory High Entropy Alloys, Tribol. Int., 2021, 160, p 107031.CrossRef V. Bhardwaj, Q. Zhou, F. Zhang, W.C. Han, Y. Du, K. Hua and H.F. Wang, Effect of Al Addition on the Microstructure, Mechanical and Wear Properties of TiZrNbHf Refractory High Entropy Alloys, Tribol. Int., 2021, 160, p 107031.CrossRef
3.
go back to reference Z.Y. Zhou, L. Wang, X.H. Zhao, J.L. Wu, F. Zhang and J.H. Pi, Effects of W Addition on the Corrosion Behaviors of FeCoNiCrMn High Entropy Alloy Composites in the 3.5 wt.% NaCl Solution, Surf. Interfaces, 2021, 23, p 100956.CrossRef Z.Y. Zhou, L. Wang, X.H. Zhao, J.L. Wu, F. Zhang and J.H. Pi, Effects of W Addition on the Corrosion Behaviors of FeCoNiCrMn High Entropy Alloy Composites in the 3.5 wt.% NaCl Solution, Surf. Interfaces, 2021, 23, p 100956.CrossRef
4.
go back to reference W.H. Kao, Y.L. Su, J.H. Horng and C.M. Wu, Structure, Mechanical Properties and Thermal Stability of Nitrogen-Doped TaNbSiZrCr High Entropy Alloy Coatings and Their Application to Glass Moulding and Micro-drills, Surf. Coat. Technol., 2021, 405, p 126539.CrossRef W.H. Kao, Y.L. Su, J.H. Horng and C.M. Wu, Structure, Mechanical Properties and Thermal Stability of Nitrogen-Doped TaNbSiZrCr High Entropy Alloy Coatings and Their Application to Glass Moulding and Micro-drills, Surf. Coat. Technol., 2021, 405, p 126539.CrossRef
5.
go back to reference V. Shivam, J. Basu, V.K. Pandey, Y. Shadangi and N.K. Mukhopadhyay, Alloying Behaviour, Thermal Stability and Phase Evolution in Quinary AlCoCrFeNi High Entropy Alloy, Adv. Powder Technol., 2018, 29, p 2221–2230.CrossRef V. Shivam, J. Basu, V.K. Pandey, Y. Shadangi and N.K. Mukhopadhyay, Alloying Behaviour, Thermal Stability and Phase Evolution in Quinary AlCoCrFeNi High Entropy Alloy, Adv. Powder Technol., 2018, 29, p 2221–2230.CrossRef
6.
go back to reference Y.G. Tong, L.H. Bai, X.B. Liang, Y.X. Chen, Z.B. Zhang, J. Liu, Y.J. Li and Y.L. Hu, Influence of Alloying Elements on Mechanical and Electronic Properties of NbMoTaWX (X=Cr, Zr, V, Hf and Re) Refractory High Entropy Alloys, Intermetallics, 2020, 126, p 159740.CrossRef Y.G. Tong, L.H. Bai, X.B. Liang, Y.X. Chen, Z.B. Zhang, J. Liu, Y.J. Li and Y.L. Hu, Influence of Alloying Elements on Mechanical and Electronic Properties of NbMoTaWX (X=Cr, Zr, V, Hf and Re) Refractory High Entropy Alloys, Intermetallics, 2020, 126, p 159740.CrossRef
7.
go back to reference L. Wang, S.S. Chen, B.L. Li, T.Q. Cao, B.P. Wang, L. Wang, Y. Ren, J. Liang and Y.F. Xue, Lightweight Zr1.2V0.8NbTixAly High-Entropy Alloys with High Tensile Strength and Ductility, Mater. Sci. Eng. A, 2021, 814, p 141234.CrossRef L. Wang, S.S. Chen, B.L. Li, T.Q. Cao, B.P. Wang, L. Wang, Y. Ren, J. Liang and Y.F. Xue, Lightweight Zr1.2V0.8NbTixAly High-Entropy Alloys with High Tensile Strength and Ductility, Mater. Sci. Eng. A, 2021, 814, p 141234.CrossRef
8.
go back to reference Q. Zhi, X.R. Tan, Z.X. Liu, Y. Liu, Q. Zhang, Y.Q. Chen and M.H. Li, Effect of Zr Content on Microstructure and Mechanical Properties of Lightweight Al2NbTi3V2Zrx High Entropy Alloy, Micron, 2021, 144, p 103031.CrossRef Q. Zhi, X.R. Tan, Z.X. Liu, Y. Liu, Q. Zhang, Y.Q. Chen and M.H. Li, Effect of Zr Content on Microstructure and Mechanical Properties of Lightweight Al2NbTi3V2Zrx High Entropy Alloy, Micron, 2021, 144, p 103031.CrossRef
9.
go back to reference A. Sharma, M.C. Oh and B. Ahn, Microstructural Evolution and Mechanical Properties of Non-Cantor AlCuSiZnFe Lightweight High Entropy Alloy Processed by Advanced Powder Metallurgy, Mater. Sci. Eng. A, 2020, 797, p 140066.CrossRef A. Sharma, M.C. Oh and B. Ahn, Microstructural Evolution and Mechanical Properties of Non-Cantor AlCuSiZnFe Lightweight High Entropy Alloy Processed by Advanced Powder Metallurgy, Mater. Sci. Eng. A, 2020, 797, p 140066.CrossRef
10.
go back to reference R.X. Li, X. Li, J. Ma and Y. Zhang, Sub-grain Formation in Al–Li–Mg–Zn–Cu Lightweight Entropic Alloy by Ultrasonic Hammering, Intermetallics, 2020, 121, p 106780.CrossRef R.X. Li, X. Li, J. Ma and Y. Zhang, Sub-grain Formation in Al–Li–Mg–Zn–Cu Lightweight Entropic Alloy by Ultrasonic Hammering, Intermetallics, 2020, 121, p 106780.CrossRef
11.
go back to reference J.Y. Jiang, F. Jiang, H.F. Huang, M.H. Zhang, Z.Q. Tang and M.M. Tong, Hot Deformation Analysis and Microstructure Evolution of Al–Mg–Mn-Sc-Zr Alloy by Isothermal Compression, J. Alloys Compd., 2021, 858, p 157655.CrossRef J.Y. Jiang, F. Jiang, H.F. Huang, M.H. Zhang, Z.Q. Tang and M.M. Tong, Hot Deformation Analysis and Microstructure Evolution of Al–Mg–Mn-Sc-Zr Alloy by Isothermal Compression, J. Alloys Compd., 2021, 858, p 157655.CrossRef
12.
go back to reference Y.F. Jia, Y.D. Jia, S.W. Wu, X.D. Ma and G. Wang, Novel Ultralight-Weight Complex Concentrated Alloys with High Strength, Materials, 2019, 12, p 1136.CrossRef Y.F. Jia, Y.D. Jia, S.W. Wu, X.D. Ma and G. Wang, Novel Ultralight-Weight Complex Concentrated Alloys with High Strength, Materials, 2019, 12, p 1136.CrossRef
13.
go back to reference R. Li, C. Gao and K. Fan, Study to Microstructure and Mechanical Properties of mg Containing High Entropy Alloys, Mater. Sci. Forum, 2010, 650, p 265–271.CrossRef R. Li, C. Gao and K. Fan, Study to Microstructure and Mechanical Properties of mg Containing High Entropy Alloys, Mater. Sci. Forum, 2010, 650, p 265–271.CrossRef
14.
go back to reference X. Yang, S.Y. Chen, J.D. Cotton and Y. Zhang, Phase Stability of Low-Density, Multiprincipal Component Alloys Containing Aluminum, Magnesium, and Lithium, JOM, 2014, 66, p 2009–2020.CrossRef X. Yang, S.Y. Chen, J.D. Cotton and Y. Zhang, Phase Stability of Low-Density, Multiprincipal Component Alloys Containing Aluminum, Magnesium, and Lithium, JOM, 2014, 66, p 2009–2020.CrossRef
15.
go back to reference R.X. Li, Z. Ren, Y. Wu, Z.B. He, P.K. Liaw, J.L. Ren and Y. Zhang, Mechanical Behaviors and Precipitation Transformation of the Lightweight High-Zn-Content Al–Zn–Li–Mg–Cu Alloy, Mater. Sci. Eng. A, 2021, 802, p 140637.CrossRef R.X. Li, Z. Ren, Y. Wu, Z.B. He, P.K. Liaw, J.L. Ren and Y. Zhang, Mechanical Behaviors and Precipitation Transformation of the Lightweight High-Zn-Content Al–Zn–Li–Mg–Cu Alloy, Mater. Sci. Eng. A, 2021, 802, p 140637.CrossRef
16.
go back to reference J.Y. He, H. Wang, H.L. Huang, X.D. Xu, M.W. Chen, Y. Wu, X.J. Liu, T.G. Nieh, K. An and Z.P. Lu, A Precipitation-Hardened High-Entropy Alloy with Outstanding Tensile Properties, Acta Mater., 2016, 102, p 187–196.CrossRef J.Y. He, H. Wang, H.L. Huang, X.D. Xu, M.W. Chen, Y. Wu, X.J. Liu, T.G. Nieh, K. An and Z.P. Lu, A Precipitation-Hardened High-Entropy Alloy with Outstanding Tensile Properties, Acta Mater., 2016, 102, p 187–196.CrossRef
17.
go back to reference X.R. Tan, G.P. Zhang, Q. Zhi and Z.X. Liu, Effects Of milling on the Microstructure and Hardness of Al2NbTi3V2Zr High-Entropy Alloy, Mater. Des., 2016, 109, p 27–36.CrossRef X.R. Tan, G.P. Zhang, Q. Zhi and Z.X. Liu, Effects Of milling on the Microstructure and Hardness of Al2NbTi3V2Zr High-Entropy Alloy, Mater. Des., 2016, 109, p 27–36.CrossRef
18.
go back to reference X.R. Tan, Q. Zhi, R.B. Yang, F.Z. Wang, J.R. Yang and Z.X. Liu, Effects of Milling on the Corrosion Behavior of Al2NbTi3V2Zr High-Entropy Alloy System in 10% Nitric Acid Solution, Mater. Corros., 2017, 68, p 1080–1089.CrossRef X.R. Tan, Q. Zhi, R.B. Yang, F.Z. Wang, J.R. Yang and Z.X. Liu, Effects of Milling on the Corrosion Behavior of Al2NbTi3V2Zr High-Entropy Alloy System in 10% Nitric Acid Solution, Mater. Corros., 2017, 68, p 1080–1089.CrossRef
19.
go back to reference Y.L. Chen, Y.H. Hu, C.A. Hsieh, J.W. Yeh and S.K. Chen, Competition Between Elements during Mechanical Alloying in an Octonary Multi-principal-element Alloy System, J. Alloys Compd., 2009, 481, p 768–775.CrossRef Y.L. Chen, Y.H. Hu, C.A. Hsieh, J.W. Yeh and S.K. Chen, Competition Between Elements during Mechanical Alloying in an Octonary Multi-principal-element Alloy System, J. Alloys Compd., 2009, 481, p 768–775.CrossRef
20.
go back to reference A. Takeuchi and A. Inoue, Calculations of Mixing Enthalpy and Mismatch Entropy for Ternary Amorphous Alloys, Mater. Trans. JIM, 2000, 41, p 1372–1378.CrossRef A. Takeuchi and A. Inoue, Calculations of Mixing Enthalpy and Mismatch Entropy for Ternary Amorphous Alloys, Mater. Trans. JIM, 2000, 41, p 1372–1378.CrossRef
21.
go back to reference X. Yang and Y. Zhang, Prediction of High-Entropy Stabilized Solid-Solution in Multi-component Alloys, Mater. Chem. Phys., 2012, 132, p 233–238.CrossRef X. Yang and Y. Zhang, Prediction of High-Entropy Stabilized Solid-Solution in Multi-component Alloys, Mater. Chem. Phys., 2012, 132, p 233–238.CrossRef
22.
go back to reference B. Kang, T. Kong, H.J. Ryu and S.H. Hong, Superior Mechanical Properties and Strengthening Mechanisms of Lightweight AlxCrNbVMo Refractory High-Entropy Alloys (x = 0, 0.5, 1.0) Fabricated by the Powder Metallurgy Process, J. Mater. Sci. Technol., 2021, 69, p 32–41.CrossRef B. Kang, T. Kong, H.J. Ryu and S.H. Hong, Superior Mechanical Properties and Strengthening Mechanisms of Lightweight AlxCrNbVMo Refractory High-Entropy Alloys (x = 0, 0.5, 1.0) Fabricated by the Powder Metallurgy Process, J. Mater. Sci. Technol., 2021, 69, p 32–41.CrossRef
23.
go back to reference N.D. Stepanov, D.G. Shaysultanov, G.A. Salishchev and M.A. Tikhonovsky, Structure and Mechanical Properties of a Light-Weight AlNbTiV High Entropy Alloy, Mater. Lett., 2015, 142, p 153–155.CrossRef N.D. Stepanov, D.G. Shaysultanov, G.A. Salishchev and M.A. Tikhonovsky, Structure and Mechanical Properties of a Light-Weight AlNbTiV High Entropy Alloy, Mater. Lett., 2015, 142, p 153–155.CrossRef
24.
go back to reference O.N. Senkov, S.V. Senkova, D.B. Miracle and C.F. Woodward, Mechanical Properties of Low-Density, Refractory Multi-principal Element Alloys of the Cr–Nb–Ti–V–Zr System, Mater. Sci. Eng. A, 2013, 565, p 51–62.CrossRef O.N. Senkov, S.V. Senkova, D.B. Miracle and C.F. Woodward, Mechanical Properties of Low-Density, Refractory Multi-principal Element Alloys of the Cr–Nb–Ti–V–Zr System, Mater. Sci. Eng. A, 2013, 565, p 51–62.CrossRef
25.
go back to reference O.N. Senkov, J.M. Scott, S.V. Senkova, D.B. Miracle and C.F. Woodward, Microstructure and Room Temperature Properties of a High-Entropy TaNbHfZrTi Alloy, J. Alloys Compd., 2011, 509, p 6043–6048.CrossRef O.N. Senkov, J.M. Scott, S.V. Senkova, D.B. Miracle and C.F. Woodward, Microstructure and Room Temperature Properties of a High-Entropy TaNbHfZrTi Alloy, J. Alloys Compd., 2011, 509, p 6043–6048.CrossRef
26.
go back to reference Q.C. Fan, B.S. Li and Y. Zhang, The Microstructure and Properties of (FeCrNiCo)AlxCuy High-Entropy Alloys and Their TiC-Reinforced Composites, Mater. Sci. Eng. A, 2014, 598, p 244–250.CrossRef Q.C. Fan, B.S. Li and Y. Zhang, The Microstructure and Properties of (FeCrNiCo)AlxCuy High-Entropy Alloys and Their TiC-Reinforced Composites, Mater. Sci. Eng. A, 2014, 598, p 244–250.CrossRef
27.
go back to reference O.N. Senkov and C.F. Woodward, Microstructure and Properties of a Refractory NbCrMo0.5Ta0.5TiZr Alloy, Mater. Sci. Eng. A, 2011, 529, p 311–320.CrossRef O.N. Senkov and C.F. Woodward, Microstructure and Properties of a Refractory NbCrMo0.5Ta0.5TiZr Alloy, Mater. Sci. Eng. A, 2011, 529, p 311–320.CrossRef
28.
go back to reference Y.D. Wu, Y.H. Cai, X.H. Chen, T. Wang, J.J. Si, L. Wang, Y.D. Wang and X.D. Hui, Phase Composition and Solid Solution Strengthening Effect in TiZrNbMoV High-Entropy Alloys, Mater. Des., 2015, 83, p 651–660.CrossRef Y.D. Wu, Y.H. Cai, X.H. Chen, T. Wang, J.J. Si, L. Wang, Y.D. Wang and X.D. Hui, Phase Composition and Solid Solution Strengthening Effect in TiZrNbMoV High-Entropy Alloys, Mater. Des., 2015, 83, p 651–660.CrossRef
29.
go back to reference M.Y. Seok, Y.K. Zhao, J.A. Lee, R.M. Mohamed, L.M. Al-Harbi, M.S. Al-Ghamdi, G. Singh, U. Ramamurty and J. Jang, On the Contributions of Different Micromechanisms for Enhancement in the Strength of TI-6Al-4V Alloy Upon B Addition: A Nanomechanical Analysis, Mater. Sci. Eng. A, 2016, 649, p 123–127.CrossRef M.Y. Seok, Y.K. Zhao, J.A. Lee, R.M. Mohamed, L.M. Al-Harbi, M.S. Al-Ghamdi, G. Singh, U. Ramamurty and J. Jang, On the Contributions of Different Micromechanisms for Enhancement in the Strength of TI-6Al-4V Alloy Upon B Addition: A Nanomechanical Analysis, Mater. Sci. Eng. A, 2016, 649, p 123–127.CrossRef
30.
go back to reference B.S. Li, Y.P. Wang, M.X. Ren, C. Yang and H.Z. Fu, Effects of Mn, Ti and V on the Microstructure and Properties of AlCrFeCoNiCu High Entropy Alloy, Mater. Sci. Eng. A, 2008, 498, p 482–486.CrossRef B.S. Li, Y.P. Wang, M.X. Ren, C. Yang and H.Z. Fu, Effects of Mn, Ti and V on the Microstructure and Properties of AlCrFeCoNiCu High Entropy Alloy, Mater. Sci. Eng. A, 2008, 498, p 482–486.CrossRef
31.
go back to reference J.M. Zhu, H.M. Fu, H.F. Zhang, A.M. Wang, H. Li and Z.Q. Hu, Synthesis and properties of multiprincipal component AlCoCrFeNiSix alloys, Mater. Sci. Eng. A, 2010, 527, p 7210–7214.CrossRef J.M. Zhu, H.M. Fu, H.F. Zhang, A.M. Wang, H. Li and Z.Q. Hu, Synthesis and properties of multiprincipal component AlCoCrFeNiSix alloys, Mater. Sci. Eng. A, 2010, 527, p 7210–7214.CrossRef
32.
go back to reference Y.J. Hsu, W.C. Chiang and J.K. Wu, Corrosion Behavior of FeCoNiCrCux High-Entropy Alloys in 3.5% Sodium Chloride Solution, Mater. Chem. Phys., 2005, 92, p 112–117.CrossRef Y.J. Hsu, W.C. Chiang and J.K. Wu, Corrosion Behavior of FeCoNiCrCux High-Entropy Alloys in 3.5% Sodium Chloride Solution, Mater. Chem. Phys., 2005, 92, p 112–117.CrossRef
Metadata
Title
Microstructure and Properties of Lightweight Al2NbTixV2Zr High Entropy Alloy
Authors
Qian Zhi
Xinrong Tan
Jilin Xie
Yang Liu
Kai Yang
Qiong Zhang
Wenhui Liu
Zhongxia Liu
Publication date
06-01-2022
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 6/2022
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-021-06571-w

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