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Journal of Polymer Research

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01-04-2016 | Original Paper

Microstructure study of poly(isobutyl acrylate) and poly(sec-butyl acrylate) by incremental analysis of ¹³C NMR spectra

Authors: Maria Siołek, Norbert Henzel, Marek Matlengiewicz

Published in: Journal of Polymer Research | Issue 4/2016

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Abstract

Microstructure of poly(isobutyl acrylate) (PiBuA) and poly(sec-butyl acrylate) (PsBuA), prepared by free radical and anionic polymerization, was investigated by ¹³C NMR spectroscopy. The carbonyl signal in the 100 MHz ¹³C NMR spectra of both homopolymers provided sufficient resolution to perform detailed analysis of distribution of configurational sequences at the pentad/heptad level. Application of Bernoulli and first order Markov statistics to determine probabilities of configurational sequences and incremental calculation to estimate chemical shifts of the individual sequences allowed for positive simulation of carbonyl signals.

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Title: Microstructure study of poly(isobutyl acrylate) and poly(sec-butyl acrylate) by incremental analysis of 13C NMR spectra
Authors: Maria Siołek
Norbert Henzel
Marek Matlengiewicz
Publication date: 01-04-2016
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 4/2016
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-016-0960-2

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