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Journal of Materials Science
Published in: Journal of Materials Science 4/2018

19-10-2017 | Chemical routes to materials

Microwave synthesis and voltammetric simultaneous determination of paracetamol and caffeine using an MOF-199-based electrode

Authors: Tran Thanh Minh, Nguyen Hai Phong, Hoang Van Duc, Dinh Quang Khieu

Published in: Journal of Materials Science | Issue 4/2018

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Abstract

In the present paper, the microwave synthesis of MOF-199 and its application as an electrode modifier for the simultaneous voltammetric determination of paracetamol (PAR) and caffeine (CAF) were demonstrated. The obtained materials were characterised by X-ray diffraction, a scanning electron microscope (SEM), nitrogen adsorption/desorption isotherms and thermal gravity. The microwave (MW) synthesis of MOF-199 has been compared to its conventional hydrothermal synthesis. It is found that by using the MW synthesis, MOF-199 can be obtained in a much shorter synthesis time with improved yield and textural properties. The electrode modified by MOF-199 was used in order to develop an electroanalytical method that can be used to simultaneously quantify PAR and CAF. The kinetic parameters of the electrode reaction process were also investigated. This proposed method was successfully employed for the simultaneous detection of PAR and CAF in pharmaceutical formulations using the standard addition method and the obtained results compared with the results determined by means of HPLC were found to be statistically similar.
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Metadata
Title
Microwave synthesis and voltammetric simultaneous determination of paracetamol and caffeine using an MOF-199-based electrode
Authors
Tran Thanh Minh
Nguyen Hai Phong
Hoang Van Duc
Dinh Quang Khieu
Publication date
19-10-2017
Publisher
Springer US
Published in
Journal of Materials Science / Issue 4/2018
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1715-0

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