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Polymer Science, Series B
Published in: Polymer Science, Series B 1/2019

01-01-2019 | SYNTHESIS

Microwave Synthesis of Polyfluorenes and Copolyfluorenes and Their Optical Properties

Authors: G. I. Nosova, L. S. Litvinova, I. A. Berezin, E. V. Zhukova, R. Yu. Smyslov, A. V. Yakimansky

Published in: Polymer Science, Series B | Issue 1/2019

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Abstract

The synthesis of copolyfluorenes by the Suzuki method under microwave heating carried out under conditions that were previously used for convection heating in an open system is studied. Using size-exclusion liquid chromatography, the stages of polycondensation, namely, oligomer formation, chain growth, and end group termination, are examined. The influence of temperature, solvent, and catalyst type Pd(PPh3)4, PdCl2(dppf), polymer-bound Pd(PPh3)4, and SiliaCatDPP-Pd on the molecular-mass characteristics of the polymers is analyzed. The optical properties of new copolyfluorenes obtained by different methods are compared.
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Metadata
Title
Microwave Synthesis of Polyfluorenes and Copolyfluorenes and Their Optical Properties
Authors
G. I. Nosova
L. S. Litvinova
I. A. Berezin
E. V. Zhukova
R. Yu. Smyslov
A. V. Yakimansky
Publication date
01-01-2019
Publisher
Pleiades Publishing
Published in
Polymer Science, Series B / Issue 1/2019
Print ISSN: 1560-0904
Electronic ISSN: 1555-6123
DOI
https://doi.org/10.1134/S1560090419010081

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