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Published in: Polymer Science, Series B 6/2019

01-11-2019 | MODIFICATION OF POLYMERS

Modification of Low Density Polyethylene Films by Blending with Natural Polymers and Curing by Gamma Radiation

Authors: Ashraf M. Abdel Ghaffar, Hussein E. Ali, Nabila A. Maziad

Published in: Polymer Science, Series B | Issue 6/2019

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Abstract

The aim of the study is to improve the properties of low density polyethylene (LDPE) films by blending with different natural polymers such as rubber, starch, and lactic acid. The properties of the different synthesized bioblends which composed of LDPE/PVA/starch, LDPE/natural rubber/PVA/starch/glycerol blend and LDPE/PVA/polylactic acid/starch/glycerol blend were studied by using FTIR, mechanical, TGA, XRD and SEM techniques. Also the properties of the different bioblends were compared with synthetic polymers such as commercial LDPE, blank LDPE and LDPE/glycerol. The results show that the blend composed of LDPE/natural rubber/PVA/starch/glycerol has improved the properties than the other blends and synthetic polymers. Also further modification to the selected blend by irradiation with gamma rays at different doses has been occurred. The selected irradiated LDPE/natural rubber/PVA/starch/glycerol blend-shows good thermal stability than other blend films and further improvement occurs up to dose of 15 kGy. Moreover, the observed mechanical results show improvement in both tensile strength and elongation up to 30 kGy. The presence of PVA and glycerol as compatibilizer and plasticizer agents respectively, increases the interfacial adhesion properties between the low density polyethylene, natural rubber, and starch within the selected blend film.

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Metadata
Title
Modification of Low Density Polyethylene Films by Blending with Natural Polymers and Curing by Gamma Radiation
Authors
Ashraf M. Abdel Ghaffar
Hussein E. Ali
Nabila A. Maziad
Publication date
01-11-2019
Publisher
Pleiades Publishing
Published in
Polymer Science, Series B / Issue 6/2019
Print ISSN: 1560-0904
Electronic ISSN: 1555-6123
DOI
https://doi.org/10.1134/S1560090420010017

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