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Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 1/2018

14-09-2018 | Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

Molecularly imprinted photocatalyst for glyceraldehyde production

Authors: Cícero Coelho de Escobar, Marla Azário Lansarin, João Henrique Zimnoch dos Santos, Milena Duarte Brandestini

Published in: Journal of Sol-Gel Science and Technology | Issue 1/2018

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Abstract

In this work, a ZnO-based molecularly imprinted photocatalyst (MIP) bearing acid Lewis sites (Al) was evaluated for photocatalytic oxidation of glycerol. The MIP was characterized by porosimetry using nitrogen adsorption/desorption, Fourier transform infrared spectroscopy and X-ray diffraction. Characterization provided evidence of the presence of zincide crystalline phase and Al–O–Si bonds. Experiments were carried out in a batch reactor (slurry) under UV radiation. The oxidation products were analysed by HPLC. Until 1 h of reaction under UV-light, the molar fraction of glyceraldehyde (GAD) was 4.5% with formation of minor subproducts (carboxylic acid). Compared to the control samples (NIP), the presence of imprinted sites has enhanced the GAD production. The MIP was shown to be highly selective for glyceraldehyde until 1 h of reaction, since no other degradation products, such as glycolaldehyde and 1,3-dihydroxyacetone, were produced.
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Metadata
Title
Molecularly imprinted photocatalyst for glyceraldehyde production
Authors
Cícero Coelho de Escobar
Marla Azário Lansarin
João Henrique Zimnoch dos Santos
Milena Duarte Brandestini
Publication date
14-09-2018
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 1/2018
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-018-4812-x

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