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Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 1/2018

19-06-2017 | Original Paper: Sol-gel, hybrids and solution chemistries

Interaction of cellulose nanocrystals with titanium dioxide and peculiarities of hybrid structures formation

Authors: I. S. Martakov, M. A. Torlopov, V. I. Mikhaylov, E. F. Krivoshapkina, V. E. Silant’ev, P. V. Krivoshapkin

Published in: Journal of Sol-Gel Science and Technology | Issue 1/2018

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Abstract

In this work we prepared hybrid particles based on cellulose nanocrystals and titanium dioxide nanoparticles and studied their aggregate stability for a wide range of the components ratios. Electrosurface properties of cellulose nanocrystals and TiO2 greatly influence on morphology and properties of the hybrid particles. Sufficient amount of TiO2 nanoparticles in the hybrid dispersions make it possible to completely cover cellulose nanocrystals surface and form a core-shell structure. Derjaguin–Landau–Verwey–Overbeek theory calculations confirmed experimental data and possibility of TiO2 monolayer covering of cellulose nanocrystals surface. Summarizing the findings, we conclude about the mechanism of interaction between cellulose nanocrystals and titanium dioxide—at the first stage particles are attracted to one another due to long-range electrostatic forces; at the second stage hydrogen bonds are formed. It is found that control of the surface potential allows to obtain stable colloidal hybrid dispersions (having negative-charged or positive-charged particles), or hybrid systems with a neutral surface charge.

Graphical Abstract

https://static-content.springer.com/image/art%3A10.1007%2Fs10971-017-4447-3/MediaObjects/10971_2017_4447_Figa_HTML.gif
previous article Heteroaggregation of cellulose nanocrystals with Fe2O3 nanoparticles
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Literature
1.
Pomogailo AD, Dzhardimalieva GI (2014) Nanostructured materials preparation via condensation ways. Springer, Dodrecht—Heidelberg—New York—LondonCrossRef
2.
Shchipunov YA, Karpenko TY (2004) Hybrid polysaccharide-silica nanocomposites prepared by the sol-gel technique. Langmuir 20:3882–3887CrossRef
3.
Gubanova GN, Kononova SV, Cristea M, Timpu D, Romashkova KA, Korytkova EN, Saprikina NN, Maslennikova TP (2015) Morphology and mechanical properties of polymer-inorganic nanocomposite containing triple chain fibrous Na-Mg hydrosilicate. Russ J Gen Chem 85:1496–1505CrossRef
4.
Kononova SV, Korytkova EN, Maslennikova TP, Romashkova KA, Kruchinina EV, Potokin IL, Gusarov VV (2010) Polymer-inorganic nanocomposites based on aromatic polyamidoimides effective in the processes of liquids separation. Russ J Gen Chem 80:1136–1142CrossRef
5.
Wei H, Rodriguez K, Renneckar S, Vikesland PJ (2014) Environmental science and engineering applications of nanocellulose-based nanocomposites. Environ Sci: Nano 1:302–316
6.
Han J, Zhou C, Wu Y, Liu F, Wu Q (2013) Self-assembling behavior of cellulose nanoparticles during freeze-drying: effect of suspension concentration, particle size, crystal structure, and surface charge. Biomacromolecules 14:1529–1540CrossRef
7.
Shi Z, Phillips GO, Yang G (2013) Nanocellulose electroconductive composites. Nanoscale 5:3194–3201CrossRef
8.
Mautner A, Lee KY, Tammelin T, Mathew AP, Nedoma AJ, Li K, Bismarck A (2015) Cellulose nanopapers as tight aqueous ultra-filtration membranes. React FunctPolym 86:209–214CrossRef
9.
Sitnikov PA, Belykh AG, Fedoseev MS, Vaseneva IN, Kuchin AV (2008) Modification of epoxyanhydride polymers with aluminum oxide. Russ J Appl Chem 81:826–829CrossRef
10.
De Salvi DT, Barud HS, Caiut JMA, Messaddeq Y, Ribeiro SJ (2012) Self-supported bacterial cellulose/boehmite organic–inorganic hybrid films. J Sol-Gel Sci Technol 63:211–218CrossRef
11.
Shopsowitz KE, Qi H, Hamad WY, MacLachlan MJ (2010) Free-standing mesoporous silica films with tunable chiral nematic structures. Nature 468:422–425CrossRef
12.
Ivanova A, Fattakhova-Rohlfing D, Kayaalp BE, Rathouský J, Bein T (2014) Tailoring the morphology of mesoporous titania thin films through biotemplating with nanocrystalline cellulose. J Am Chem Soc 136:5930–5937CrossRef
13.
Yoldas BE (1986) Hydrolysis of titanium alkoxide and effects of hydrolytic polycondensation parameters. J Mater Sci 21:1087–1092CrossRef
14.
Torlopov MA, Udoratina EV, Martakov IS, Sitnikov PA (2017) Cellulose nanocrystals prepared in H3PW12O40-acetic acid system. Cellulose 24:2153–2162CrossRef
15.
Martakov IS, Krivoshapkin PV, Torlopov MA, Mikhailov VI, Krivoshapkina EF (2016) Study on the stability of hybrid dispersions of cellulose nanocrystals and aluminum oxide. Glass Phys Chem 42:590–596CrossRef
16.
Hogg R, Healy TW, Furstenau DW (1966) Mutual coagulation of colloidal dispersions. Trans Faraday Soc 62:1638–1651CrossRef
17.
Golikova EV, Burdina NM, Vysokovskaya NA (2002) Aggregation stability of SiO2, FeOOH, ZrO2, CeO2, and natural diamond sols and their binary mixtures: 2. The photometric study of heterocoagulation of SiO2–FeOOH, SiO2–ZrO2, SiO2–CeO2, and CeO2–natural diamond binary systems in KCl solutions. Colloid J 64:142–148CrossRef
18.
Elimelech M, Gregory J, Jia X, Williams RA (1995) Particle Deposition and Aggregation Measurement, Modelling and Simulation. Elsevier, Butterworth-Heinemann, Woburn
19.
Lu S, Pugh RJ, Forssberg E (2005) Interfacial Separation of Particles. Elsevier, Amsterdam
20.
Baturenko DYU, Chernoberezhskii YUM, Lorentsson AV, Zhukov AN (2003) Effect of pH on the aggregation stability of microcrystalline cellulose dispersions in aqueous 0.1 M NaCl solutions. Colloid J 65:666–671CrossRef
21.
Mahmoud KA, Mena JA, Male KB, Hrapovic S, Kamen A, Luong JH (2010) Effect of surface charge on the cellular uptake and cytotoxicity of fluorescent labeled cellulose nanocrystals. ACS Appl Mater Interfaces 2:2924–2932CrossRef
22.
Fu G, He A, Jin Y, Cheng Q, Song J (2012) Fabrication of hollow silica nanorods using nanocrystalline cellulose as templates. BioResources 7:2319–2329
23.
Mashkour M, Kimura T, Kimura F, Mashkour M, Tajvidi M (2014) One-dimensional core–shell cellulose-akaganeite hybrid nanocrystals: synthesis, characterization, and magnetic field induced self-assembly. RSC Adv 4:52542–52549CrossRef
24.
Cerbelaud M, Videcoq A, Abelard P, Pagnoux C, Rossignol F, Ferrando R (2008) Heteroaggregation between Al2O3 submicrometer particles and SiO2 nanoparticles: experiment and simulation. Langmuir 24:3001–3008CrossRef
25.
Zhbankov RG (1992) Hydrogen bonds and structure of carbohydrates. J Mol Struct 270:523–539CrossRef
26.
Levdik IY, Nikitin VN, Petropavlovskii GA, Vasil’eva GS (1965) IR study of analytical and structural characteristics of low-substituted methylcellulose films. J Appl Spectrosc 3:269–272CrossRef
27.
Klemm D, Philipp B, Heinze T, Heinze U, Wagenknecht W (1998) Comprehensive Cellulose Chemistry; Volume 1: Fundamentals and Analytical Methods. Wiley‐VCH Verlag GmbH, Weinheim
28.
Salas C, Nypelö T, Rodriguez-Abreu C, Carrillo C, Rojas OJ (2014) Nanocellulose properties and applications in colloids and interfaces. Curr Opin Colloid Interface Sci 19:383–396CrossRef
29.
Khoshkava V, Kamal MR (2014) Effect of drying conditions on cellulose nanocrystal (CNC) agglomerate porosity and dispersibility in polymer nanocomposites. Powder Technol 261:288–298CrossRef
30.
De Salvi DT (2012) Self-supported bacterial cellulose/boehmite organic–inorganic hybrid films. J Sol-Gel Sci Technol 63:211–218CrossRef
31.
He M, Duan B, Xu D, Zhang L (2015) Moisture and solvent responsive cellulose/SiO2 nanocomposite materials. Cellulose 22:553–563CrossRef
32.
Khan R, Dhayal M (2008) Nanocrystalline bioactive TiO2-chitosan impedimetric immunosensor for ochratoxin-A. Electrochem Commun 10:492–495CrossRef
33.
Zhou Z, Lu C, Wu X, Zhang X (2013) Cellulose nanocrystals as a novel support for CuO nanoparticles catalysts: facile synthesis and their application to 4-nitrophenol reduction. RSC Adv 3:26066–26073CrossRef
34.
Lin N, Dufresne A (2014) Nanocellulose in biomedicine: current status and future prospect. Eur Polym J 59:302–325CrossRef
35.
Romanov DP, Baklagina YuG, Gubanova GN, Ugolkov VL, Lavrent’ev VK, Tkachenko AA, Sinyaev VA, Sukhanova TE, Khripunov AK (2010) Formation of organic-inorganic composite materials based on cellulose Acetobacter xylinum and calcium phosphates for medical applications. Glass Phys Chem 36:484–493CrossRef
36.
Liu S, Tao D, Bai H, Liu X (2012) Cellulose-nanowhisker-templated synthesis of titanium dioxide/cellulose nanomaterials with promising photocatalytic abilities. J Appl Polym Sci 126:E282–E290CrossRef
Metadata
Title
Interaction of cellulose nanocrystals with titanium dioxide and peculiarities of hybrid structures formation
Authors
I. S. Martakov
M. A. Torlopov
V. I. Mikhaylov
E. F. Krivoshapkina
V. E. Silant’ev
P. V. Krivoshapkin
Publication date
19-06-2017
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 1/2018
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-017-4447-3

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