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Journal of Sol-Gel Science and Technology

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07-04-2017 | Original Paper: Sol-gel, hybrids and solution chemistries

Heteroaggregation of cellulose nanocrystals with Fe₂O₃ nanoparticles

Authors: Vasily Igorevich Mikhaylov, Mikhail Anatolievich Torlopov, Elena Fedorovna Krivoshapkina, Ilia Sergeevich Martakov, Pavel Vasilievich Krivoshapkin

Published in: Journal of Sol-Gel Science and Technology | Issue 1/2018

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Abstract

Hybrid dispersion systems based on cellulose nanocrystals (CNC) and ferric oxide nanoparticles have been prepared, and heteroaggregation process for a wide range of the concentration ratio of the components have been studied. It is established that one can obtain stable colloidal dispersions with both negatively and positively charged particles or hybrid systems with a neutralized surface charge by controlling the CNC/Fe₂O₃ concentration ratio. It is shown that the heteroaggregation of cellulose nanocrystals-Fe₂O₃ hybrid dispersions occurs by the “charge neutralization–charge reversal” mechanism. The hybrid systems are stable outside the range of the ζ-potential values between −30 and +30 mV.

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Title: Heteroaggregation of cellulose nanocrystals with Fe2O3 nanoparticles
Authors: Vasily Igorevich Mikhaylov
Mikhail Anatolievich Torlopov
Elena Fedorovna Krivoshapkina
Ilia Sergeevich Martakov
Pavel Vasilievich Krivoshapkin
Publication date: 07-04-2017
Publisher: Springer US
Published in: Journal of Sol-Gel Science and Technology / Issue 1/2018
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-017-4374-3

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