Top

Journal of Materials Science

Published in:

20-02-2024 | Electronic materials

Optimizing dielectric energy storage properties of BNT-based relaxor ferroelectric ceramics modified via Ba_0.4Sr_0.6TiO₃

Authors: Wen Zhu, Zong-Yang Shen

Published in: Journal of Materials Science | Issue 7/2024

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Low-voltage driven ceramic capacitor applications call for relaxor ferroelectric ceramics with superior dielectric energy storage capabilities. Here, the (Bi_0.5Na_0.5)_0.65(Ba_0.3Sr_0.7)_0.35(Ti_0.98Ce_0.02)O₃ + x wt% Ba_0.4Sr_0.6TiO₃ (BNBSTC + xBST, x = 0, 2, 4, 6, 8, 10) ceramics were prepared to systematically investigate the effect of BST content on the phase structure, microscopic morphology and dielectric energy storage properties. A single perovskite structure with a dense and homogenous microstructure is presented in all BNBSTC + xBST ceramics. A recoverable energy storage density W_rec = 1.39 J/cm³ with efficiency η = 81.5% is achieved only under a low electric field of 94 kV/cm in the optimal composition of x = 6, accompanied by an enhanced dielectric temperature stability meeting the requirement of wider working window. In addition to good frequency, anti-fatigue and temperature stability, the BNBSTC + 6BST ceramics exhibit tremendous potential for designing low-voltage driven energy storage ceramic capacitors.

previous article Effect of oxygen vacancy concentration on the resistive random access memory characteristics of NiOx (x = 1, 0.97, 0.94) thin films

next article Zn doping for enhanced sodium-ion conductivity and air stability in Na3SbS4 solid electrolyte

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Simon P, Gogotsi Y (2020) Perspectives for electrochemical capacitors and related devices. Nat Mater 19(11):1151–1163. https://doi.org/10.1038/s41563-020-0747-zADSCrossRefPubMed

Xu J, Cai X, Cai S, Shao Y, Hu C, Lu S, Ding S (2023) High-energy lithium-ion batteries: recent progress and a promising future in applications. Energy Environ Mater 6(5):e12450. https://doi.org/10.1002/eem2.12450CrossRef

Ji X, Zhang Y, Cao M, Gu Q, Wang H, Yu J, Guo Z, Zhou X (2022) Advanced inorganic/polymer hybrid electrolytes for all-solid-state lithium batteries. J Adv Ceram 11(6):835–861. https://doi.org/10.1007/s40145-022-0580-8CrossRef

Aznam I, Muchtar A, Somalu MR, Baharuddin NA, Rosli NAH (2023) Advanced materials for heterogeneous catalysis: a comprehensive review of spinel materials for direct internal reforming of methane in solid oxide fuel cell. Chem Eng J 471:144751. https://doi.org/10.1016/j.cej.2023.144751CrossRef

Li D, Zeng X, Li Z, Shen Z-Y, Hao H, Luo W, Wang X, Song F et al (2021) Progress and perspectives in dielectric energy storage ceramics. J Adv Ceram 10(4):675–703. https://doi.org/10.1007/s40145-021-0500-3CrossRef

Zhao W, Xu D, Li D, Avdeev M, Jing H, Xu M, Guo Y, Shi D et al (2023) Broad-high operating temperature range and enhanced energy storage performances in lead-free ferroelectrics. Nat Commun 14(1):5725. https://doi.org/10.1038/s41467-023-41494-1ADSCrossRefPubMedPubMedCentral

Zhu W, Shen Z-Y, Deng W, Li K, Luo W, Song F, Zeng X, Wang Z et al (2023) A review: (Bi, Na)Ti_O3 (BNT)-based energy storage ceramics. J Materiomics 10(1):86–123. https://doi.org/10.1016/j.jmat.2023.05.002CrossRef

Li D, Xu D, Zhao W, Avdeev M, Jing H, Guo Y, Zhou T, Liu W et al (2023) A high-temperature performing and near-zero energy loss lead-free ceramic capacitor. Energ Environ Sci 16(10):4511–4521. https://doi.org/10.1039/D3EE01545ACrossRef

Zhang S (2023) High entropy design: a new pathway to promote the piezoelectricity and dielectric energy storage in perovskite oxides. Microstructures 3(1):2023003. https://doi.org/10.20517/microstructures.2022.38ADSCrossRef

10.

Hong K, Lee TH, Suh JM, Yoon S-H, Jong HW (2019) Perspectives and challenges in multilayer ceramic capacitors for next generation electronics. J Mater Chem C 7(32):9782–9802. https://doi.org/10.1039/C9TC02921DCrossRef

11.

Adediji YB, Adeyinka AM, Yahya DI, Mbelu OV (2023) A review of energy storage applications of lead-free BaTiO₃-based dielectric ceramic capacitors. Energy Ecol Environ 8:401–419. https://doi.org/10.1007/s40974-023-00286-5CrossRef

12.

Zhao P, Cai Z, Wu L, Zhu C, Li L, Wang X (2021) Perspectives and challenges for lead-free energy-storage multilayer ceramic capacitors. J Adv Ceram 10(6):1153–1193. https://doi.org/10.1007/s40145-021-0516-8CrossRef

13.

Zhu W, Meng Y, Song F, Li Z, Shen Z (2023) Enhanced dielectric temperature stability and energy storage characteristics of BNBST relaxor ferroelectric ceramics through B-site rare earth Y³⁺ doping. J Ceram 44(3):525–533. https://doi.org/10.13957/j.cnki.tcxb.2023.03.013CrossRef

14.

Qi H, Xie A, Zuo R (2022) Local structure engineered lead-free ferroic dielectrics for superior energy-storage capacitors: a review. Energy Storage Mater 45:541–567. https://doi.org/10.1016/j.ensm.2021.11.043CrossRef

15.

Li Z, Li D-X, Shen Z-Y, Zeng X, Song F, Luo W, Wang X, Wang Z et al (2022) Remarkably enhanced dielectric stability and energy storage properties in BNT-BST relaxor ceramics by A-site defect engineering for pulsed power applications. J Adv Ceram 11(2):283–294. https://doi.org/10.1007/s40145-021-0532-8CrossRef

16.

Lee JK, Kang SG, Kim H (1998) Dielectric properties of Pb(Zn_1/3, N_b2/3)_O3 ceramics modified by Ba(Z_n1/3, _Nb2/3₎O3 and BaT_iO3. J Mater Sci 33(3):693–698. https://doi.org/10.1023/A:1004337728221ADSCrossRef

17.

Kahoul F, Hamzioui L, Guemache A, Aillerie M, Boutarfaia A (2021) Phase structure, microstructure, and dielectric properties of (1–x)Pb(Zr_0.50Ti_0.50)O₃-xBa(W_2/3Mn_1/3)O₃ ceramics. Ferroelectrics 572(1):229–237. https://doi.org/10.1080/00150193.2020.1868885ADSCrossRef

18.

Peddigari M, Palneedi H, Hwang GT, Ryu J (2019) Linear and nonlinear dielectric ceramics for high-power energy storage capacitor applications. J Korean Ceram Soc 56(1):1–23. https://doi.org/10.4191/kcers.2019.56.1.02CrossRef

19.

Lu Y, Zhang J, Zhou K, He L (2023) Capacitive energy storage performance of lead-free sodium niobate-based antiferroelectric ceramics. J Mater Sci 58(29):11886–11893. https://doi.org/10.1007/s10853-023-08769-wADSCrossRef

20.

Zhang H, Wei T, Zhang Q, Ma W, Fang P, Salamon D, Zhang S-T, Nan B et al (2020) A review on the development of lead-free ferroelectric energy-storage ceramics and multilayer capacitors. J Mater Chem C 8(47):16648–16667. https://doi.org/10.1039/D0TC04381HCrossRef

21.

Zhao P, Li L, Wang X (2023) BaTiO₃-NaNbO₃ energy storage ceramics with an ultrafast charge-discharge rate and temperature-stable power density. Microstructures 3:2023002. https://doi.org/10.20517/microstructures.2022.21CrossRef

22.

Li Z, Li D, Shen Z, Luo WQ, Song F, Wang Z, Li Y (2021) Effect of (Zn_1/3/Nb_2/3)⁴⁺ complex on energy storage characteristics of BNBST ceramics. J Ceram 42(3):414–422. https://doi.org/10.13957/j.cnki.tcxb.2021.03.007CrossRef

23.

Suchanicz J, Kluczewska-Chmielarz K, Sitko D, Jagło G (2021) Electrical transport in lead-free Na_0.5Bi_0.5TiO₃ ceramics. J Adv Ceram 10(1):152–165. https://doi.org/10.1007/s40145-020-0430-5CrossRef

24.

Wang H, Li Q, Jia Y, Yadav AK, Yan B, Shen Q, Li M, Quan Q et al (2021) Enhanced dielectric temperature stability and energy-storage properties of (Y_0.5Nb_0.5)⁴⁺ co-doped (Bi_0.5Na_0.5)_0.94Ba_0.06TiO₃ lead-free relaxor ceramics. J Mater Sci 56(26):14672–14683. https://doi.org/10.1007/s10853-021-06193-6ADSCrossRef

25.

Liu Y, Ji Y, Yang Y (2021) Growth, properties and applications of Bi_0.5Na_0.5TiO₃ ferroelectric nanomaterials. Nanomaterials 11(7):1724. https://doi.org/10.3390/nano11071724CrossRefPubMedPubMedCentral

26.

Wu Y, Fan Y, Liu N, Peng P, Zhou M, Yan S, Cao F, Dong X et al (2019) Enhanced energy storage properties in sodium bismuth titanate-based ceramics for dielectric capacitor applications. J Mater Chem C 7(21):6222–6230. https://doi.org/10.1039/C9TC01239GCrossRef

27.

Li Z, Yang Q, Wang C, Zhang J, Wang Z, Gao B, Li Z, Wang Z et al (2023) A brief review of sodium bismuth titanate-based lead-free materials for energy storage: solid solution modification, metal/metallic oxide doping, defect engineering and process optimizing. Crystals 13(2):295. https://doi.org/10.3390/cryst13020295CrossRef

28.

Li D, Shen Z-Y, Li Z, Luo W, Wang X, Wang Z, Song F, Li Y (2020) P–E hysteresis loop going slim in Ba_0.3Sr_0.7TiO₃-modified Bi_0.5Na_0.5TiO₃ ceramics for energy storage applications. J Adv Ceram 9(2):183–192. https://doi.org/10.1007/s40145-020-0358-9CrossRef

29.

Li D, Shen Z-Y, Li Z, Wang X, Luo W-Q, Song F, Wang Z, Li Y (2019) Structural evolution, dielectric and ferroelectric properties of (1–x) Bi_0.5Na_0.5TiO₃-xBa_0.3Sr_0.7TiO₃ ceramics. J Mater Sci Mater Electron 30(6):5917–5922. https://doi.org/10.1007/s10854-019-00890-4CrossRef

30.

Zhu W, Deng W, Li Z, Shen Z-Y, Shi X, Song F, Luo W, Wang Z et al (2022) Broadening the dielectric stability temperature range of BNBST relaxor ferroelectric ceramics by rare earth Ce doping for energy storage. J Mater Sci: Mater Electron 33(36):26861–26869. https://doi.org/10.1007/s10854-022-09351-xCrossRef

31.

Wang Y, Shen Z-Y, Li Y-M, Wang Z-M, Luo W-Q, Hong Y (2015) Optimization of energy storage density and efficiency in Ba_xSr_1-xTiO₃ (x≤0.4) paraelectric ceramics. Ceram Int 41(6):8252–8256. https://doi.org/10.1016/j.ceramint.2015.02.156

32.

Luo W-Q, Li D-X, Li Z-P, Shen Z-Y (2023) Structure and dielectric energy storage properties of secondary phase CaCu₃Ti₄O₁₂ modified BSBNT relaxor ferroelectric ceramics. Adv Ceram 44 (3) 218–225. https://doi.org/10.16253/j.cnki.37-1226/tq.2023.03.007

33.

Luo W-Q, Li Z-P, Yuan L-H, Li D-X, Shen Z-Y (2022) Effect of Sn⁴⁺ ion modification on electrical energy storage properties of BSBNT ceramics. Adv Ceram 43(1) 57–64. https://doi.org/10.16253/j.cnki.37-1226/tq.2022.01.006

34.

Zan P, Long Y, Pu L, Huang X, Liu J (2024) Dielectric temperature stability and energy storage performance of BST-based lead-free ceramics for X8R capacitors. J Mater Sci: Mater El 35(1):23. https://doi.org/10.1007/s10854-023-11762-3CrossRef

35.

Zhang K, Zheng P, Zhang H, Niu Z, Luo C, Bai W, Zhang J, Zheng L et al (2022) Excellent energy storage performance of paraelectric Ba_0.4Sr_0.6TiO₃ based ceramics through induction of polar nano-regions. Ceram Int 48(14):19864–19873. https://doi.org/10.1016/j.ceramint.2022.03.261

36.

Li L, Xie B, Liu Z, Cheng X, Zhang L, Ma W, Fang P, Zhang H (2021) Improved energy storage performance of Ba_0.4Sr_0.6TiO₃ by doping high polarization BiFeO₃. Ceram Int 47(10):14647–14654. https://doi.org/10.1016/j.ceramint.2021.02.053

37.

Wang Q, Wang T, Zhang L, Liu Z, Guo K, Liu J, Xie B (2022) High energy-storage performance of lead-free Ba_0.4Sr_0.6TiO₃-Sr_0.7Bi_0.2TiO₃ relaxor-ferroelectric ceramics with ultrafine grain size. Ceram Int 48(2):2068–2074. https://doi.org/10.1016/j.ceramint.2021.09.292

38.

Shi X, Li K, Shen Z-Y, Liu J, Chen C, Zeng X, Zhang B, Song F et al (2023) BS_0.5BNT-based relaxor ferroelectric ceramic/glass-ceramic composites for energy storage. J Adv Ceram 12(4):695–710. https://doi.org/10.26599/JAC.2023.9220713

39.

Liu G, Dong J, Zhang L, Yan Y, Jing R, Jin L (2020) Phase evolution in (1-x)(Na_0.5Bi_0.5)TiO₃-xSrTiO₃ solid solutions: a study focusing on dielectric and ferroelectric characteristics. J Materiomics 6(4):677–691. https://doi.org/10.1016/j.jmat.2020.05.005

40.

Kang R, Wang Z, Liu W, He L, Zhu X, Shi P, Zhang X, Zhang L et al (2021) Domain engineered lead-free ceramics with large energy storage density and ultra-high efficiency under low electric fields. ACS Appl Mater Interfaces 13(21):25143–25152. https://doi.org/10.1021/acsami.1c05824CrossRefPubMed

41.

Zhu W, Guo H, Shen Z-Y, Song F, Luo W, Wang Z, Li Y (2023) Boosting dielectric temperature stability in BNBST based energy storage ceramics by Nb₂O₅ modification. J Am Ceram Soc 106(6):3633–3642. https://doi.org/10.1111/jace.19050CrossRef

42.

Li D, Shen Z-Y, Li Z, Luo W, Song F, Wang Z, Li Y et al (2020) Optimization of polarization behavior in (1–x)BSBNT-xNN ceramics for pulsed power capacitors. J Mater Chem C 8(23):7650–7657. https://doi.org/10.1039/D0TC01699CCrossRef

43.

Zhu W, Song F, Shen Z-Y, Luo W, Wang Z, Li Y (2023) KNN+Nb₂O₅ co-modified BNBST-based relaxor ferroelectric ceramics for X8R energy storage capacitors. Ceram Int 49(23):38196–38203. https://doi.org/10.1016/j.ceramint.2023.09.150CrossRef

44.

Zhang K, Zheng P, Zhang H, Niu Z, Luo C, Bai W, Zhang J, Zhang L et al (2022) Excellent energy storage performance of paraelectric Ba_0.4Sr_0.6TiO₃ based ceramics through induction of polar nano-regions. Ceram Int 48(14):19864–19873. https://doi.org/10.1016/j.ceramint.2022.03.261

45.

Yadav AK, Yoo IR, Choi SH, Park J-Y, Song H-C, Cho K-H (2022) Enhanced energy storage properties and excellent fatigue resistance of Pb-free Bi_0.47Na_0.376K_0.094Ba_0.06Nb_0.024Ti_0.97-x(Ta_0.24Sn_0.7)_xO₃ relaxor ceramics. J Alloys Compd 923:166324. https://doi.org/10.1016/j.jallcom.2022.166324

46.

He Z, Li H, Qing Z, Zeng M, Li J, Zhou L, Zhong X, Liu J (2021) Temperature stability of lead-free BST-BZN relaxor ferroelectric ceramics for energy storage capacitors. J Mater Sci Mater Electron 32:752–763. https://doi.org/10.1007/s10854-020-04854-xCrossRef

Title: Optimizing dielectric energy storage properties of BNT-based relaxor ferroelectric ceramics modified via Ba0.4Sr0.6TiO3
Authors: Wen Zhu
Zong-Yang Shen
Publication date: 20-02-2024
Publisher: Springer US
Published in: Journal of Materials Science / Issue 7/2024
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-024-09444-4

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 7/2024

Sn incorporation boosts reversible conversion reaction of FeOOH nanocomposite for high-performance lithium storage

Developing a multiscale approach for damage analysis of functionalized-GNP/PET nanocomposite

Molecular dynamics simulations of solid-state sintering in Fe35Ni alloy: understanding the process at the atomic scale

Effect of microcrystalline cellulose on the mechanical properties of flax reinforced methylmethacrylate and urethane acrylate composites

A model transfer strategy based on screening stable wavelength for quantitative analysis of holocellulose and lignin content distribution in pulpwood

Mechanical behavior of cavity and dislocation evolution induced by interfacial debonding of Cu/SiC composites

Premium Partners