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Journal of Materials Science

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24-10-2017 | Polymers

Photochromic behavior of a new polyoxomolybdate/alkylamine composite in solid state

Published in: Journal of Materials Science | Issue 4/2018

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Abstract

A new polyoxomolybdate/alkylamine composite (C₃N₂H₅)₆[As₄Mo₈O₃₃]·4H₂O [1] was successfully synthesized by controlling the reaction parameters in the conventional aqueous solution. Compound 1 was well characterized by single-crystal X-ray diffraction, FTIR, XPRD analysis, TGA and elemental analyses. It was found that compound 1 exhibited intriguing photochromic behavior along with interesting thermochromic property as the color of 1 turns from white to blue-mazarine with rise in temperature. Furthermore, compound 1 features distinct photochromic behavior in the solid state. This new arsenomolybdate/alkylamine composite can change color from white to pale blue upon irradiation by a xenon lamp (full wave-band, P = 300 W). The photochromism of 1 involves the reduction of Mo⁶⁺ to Mo⁵⁺, indicating crucial role in proton transfer from the imidazole cations toward the polyanion.

previous article Understanding reaction sequences and mechanisms during synthesis of nanocrystalline Ti2N and TiN via magnetically controlled ball milling of Ti in nitrogen

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Title: Photochromic behavior of a new polyoxomolybdate/alkylamine composite in solid state
Publication date: 24-10-2017
Published in: Journal of Materials Science / Issue 4/2018
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-017-1736-8

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